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    PROCESS FOR THE PRODUCTION OF A FUEL BASE FROM AN ETHYLENE FEEDSTOCK IMPLEMENTING AT LEAST ONE OLIGOMERIZATION STAGE IN THE PRESENCE OF A HOMOGENEOUS CATALYTIC SYSTEM
    1.
    发明申请
    PROCESS FOR THE PRODUCTION OF A FUEL BASE FROM AN ETHYLENE FEEDSTOCK IMPLEMENTING AT LEAST ONE OLIGOMERIZATION STAGE IN THE PRESENCE OF A HOMOGENEOUS CATALYTIC SYSTEM 有权
    在均质催化体系存在下，在至少一个低级化阶段实施乙烯进料的燃料基料的生产方法

    公开(公告)号：US20110282119A1

    公开(公告)日：2011-11-17

    申请号：US13102593

    申请日：2011-05-06

    申请人： Sandrine BERARD ,  Stephane Harry ,  Natacha Touchais ,  Lionel Magna ,  Helene Olivier-Bourbigou ,  Cedrik Popelin ,  David Proriol ,  Lucien Saussine

    发明人： Sandrine BERARD ,  Stephane Harry ,  Natacha Touchais ,  Lionel Magna ,  Helene Olivier-Bourbigou ,  Cedrik Popelin ,  David Proriol ,  Lucien Saussine

    IPC分类号： C07C2/04

    CPC分类号： C10G50/00 ,  C10G2300/1011 ,  C10G2300/703 ,  C10G2400/04 ,  C10G2400/08 ,  Y02P30/20

    摘要： This invention describes a process for the production of bases for fuels (such as diesel and/or kerosene) from a C2 ethanol feedstock, whereby said process comprises at least a first stage for oligomerization of said feedstock into at least one hydrocarbon effluent that comprises a mixture of olefins that for the most part have between 4 and 30 carbons, whereby said olefin mixture comprises a C10-C24 fraction that has a mean linearity that is greater than 60%, in the presence of a homogeneous catalytic system that comprises at least one metal precursor that is selected from among the group that is formed by titanium, zirconium, hafnium, nickel and iron, taken by themselves or in a mixture, a second stage for oligomerization of at least a portion of the effluent that is obtained from stage a), into at least one hydrocarbon effluent that comprises a mixture of olefins that for the most part have between 4 and 30 carbon atoms, with said olefin mixture comprising a C10-C24 fraction that has a mean linearity that is less than 50%, in the presence of a homogeneous catalytic system that is identical to or different from the one that is used in stage a).

    摘要翻译： 本发明描述了一种从C2乙醇原料生产燃料（例如柴油和/或煤油）的碱的方法，其中所述方法至少包括将所述原料低聚至至少一种碳氢化合物流出物的第一阶段，其包括 大部分具有4至30个碳原子的烯烃混合物，其中所述烯烃混合物包含平均线性大于60％的C10-C24级分，在均相催化体系存在下，其包含至少一种 选自由钛，锆，铪，镍和铁形成的组中的金属前体，它们本身或混合物中，第二阶段用于将至少一部分从阶段a获得的流出物 ）至少一种烃流出物，其包含大部分具有4至30个碳原子的烯烃混合物，所述烯烃混合物包含C10-C24部分，其中ha 在与a）阶段中使用的相同或不同的均相催化体系的存在下，其平均线性小于50％。

    HYDROFORMYLATION METHOD INVOLVING A COBALT-BASED CATATLYST IN A NON-AQUEOUS IONIC LIQUID
    3.
    发明申请
    HYDROFORMYLATION METHOD INVOLVING A COBALT-BASED CATATLYST IN A NON-AQUEOUS IONIC LIQUID 有权
    在非水性离子液体中涉及基于钴的催化剂的水解方法

    公开(公告)号：US20100010270A1

    公开(公告)日：2010-01-14

    申请号：US12373409

    申请日：2007-06-22

    申请人： Helene Olivier-Bourbigou ,  Lucien Saussine ,  Lionel Magna ,  David Proriol

    发明人： Helene Olivier-Bourbigou ,  Lucien Saussine ,  Lionel Magna ,  David Proriol

    IPC分类号： C07C45/00

    CPC分类号： C07C45/50 ,  Y02P20/584 ,  C07C47/02

    摘要： In a method for hydroformylating olefinically unsaturated compounds by means of a cobalt-based catalyst, used in a non-aqueous ionic liquid, liquid at a temperature below 100° C. and comprising at least one cation Q+ and at least one anion A−, said method comprising at least a stage of reaction under pressure and at least a stage of separation of the phases by decantation, recycling of the catalyst is improved: through the use of a ligand selected from among the Lewis bases, more particularly pyridine derivatives, and simultaneously through the addition of this ligand in a post-reaction stage. At the end of this process, the organic phase containing the reaction products can be recovered and the ionic liquid phase containing the catalyst can be recycled to the hydroformylation reactor.

    摘要翻译： 在用于非水离子液体中的钴基催化剂加氢甲酰化烯属不饱和化合物的方法中，在低于100℃的温度下含有至少一种阳离子Q +和至少一种阴离子A-的液体， 所述方法至少包括在压力下的反应阶段和至少通过倾析分离相的阶段，催化剂的再循环得到改善：通过使用选自路易斯碱，更特别是吡啶衍生物的配体和 同时通过在后反应阶段加入该配体。 在该方法结束时，可以回收含有反应产物的有机相，并且可以将含有催化剂的离子液相再循环至加氢甲酰化反应器。

    Hydroformylation method involving a cobalt-based catalyst in a non-aqueous ionic liquid
    4.
    发明授权
    Hydroformylation method involving a cobalt-based catalyst in a non-aqueous ionic liquid 有权
    在非水离子液体中涉及钴基催化剂的羰基化方法

    公开(公告)号：US07781621B2

    公开(公告)日：2010-08-24

    申请号：US12373409

    申请日：2007-06-22

    申请人： Helene Olivier-Bourbigou ,  Lucien Saussine ,  Lionel Magna ,  David Proriol

    发明人： Helene Olivier-Bourbigou ,  Lucien Saussine ,  Lionel Magna ,  David Proriol

    IPC分类号： C07C45/50

    CPC分类号： C07C45/50 ,  Y02P20/584 ,  C07C47/02

    摘要： In a method for hydroformylating olefinically unsaturated compounds by means of a cobalt-based catalyst, used in a non-aqueous ionic liquid, liquid at a temperature below 100° C. and comprising at least one cation Q+ and at least one anion A−, said method comprising at least a stage of reaction under pressure and at least a stage of separation of the phases by decantation, recycling of the catalyst is improved: through the use of a ligand selected from among the Lewis bases, more particularly pyridine derivatives, and simultaneously through the addition of this ligand in a post-reaction stage. At the end of this process, the organic phase containing the reaction products can be recovered and the ionic liquid phase containing the catalyst can be recycled to the hydroformylation reactor.

    摘要翻译： 在用于非水离子液体中的钴基催化剂加氢甲酰化烯属不饱和化合物的方法中，在低于100℃的温度下含有至少一种阳离子Q +和至少一种阴离子A-的液体， 所述方法至少包括在压力下的反应阶段和至少通过倾析分离相的阶段，催化剂的再循环得到改善：通过使用选自路易斯碱，更特别是吡啶衍生物的配体和 同时通过在后反应阶段加入该配体。 在该方法结束时，可以回收含有反应产物的有机相，并且可以将含有催化剂的离子液相再循环至加氢甲酰化反应器。

    FLEXIBLE PROCESS FOR TRANSFORMATION OF ETHANOL INTO MIDDLE DISTILLATES IMPLEMENTING A HOMOGENEOUS CATALYTIC SYSTEM AND A HETEROGENEOUS CATALYTIC SYSTEM
    6.
    发明申请
    FLEXIBLE PROCESS FOR TRANSFORMATION OF ETHANOL INTO MIDDLE DISTILLATES IMPLEMENTING A HOMOGENEOUS CATALYTIC SYSTEM AND A HETEROGENEOUS CATALYTIC SYSTEM 有权
    用于将乙醇转化成中等离子的柔性方法实现均相催化体系和异构催化体系

    公开(公告)号：US20110313221A1

    公开(公告)日：2011-12-22

    申请号：US13102384

    申请日：2011-05-06

    申请人： Emmanuelle Guillon ,  Nicolas Cadran ,  Natacha Touchais ,  Laurent Bournay ,  Lionel Magna ,  Helene Olivier-Bourbigou

    发明人： Emmanuelle Guillon ,  Nicolas Cadran ,  Natacha Touchais ,  Laurent Bournay ,  Lionel Magna ,  Helene Olivier-Bourbigou

    IPC分类号： C07C1/20

    CPC分类号： C10G50/00 ,  C07C1/24 ,  C10G3/49 ,  C10G3/62 ,  C10G2300/1014 ,  C10G2300/301 ,  C10G2400/04 ,  C10G2400/08 ,  Y02P20/52 ,  Y02P30/20 ,  C07C11/04

    摘要： The invention describes a process for the production of middle distillate hydrocarbon bases from an ethanol feedstock that is produced from a renewable source that is obtained from biomass, comprising a stage for purification of said feedstock, a stage for dehydration of said purified feedstock into an effluent that is for the most part ethylene and comprises water, at least one stage for separating water, a first stage for oligomerization of the effluent that is for the most part ethylene into at least one olefinic effluent that comprises at least 80% by weight of olefins that have four or more carbon atoms, in the presence of a homogeneous catalyst that comprises at least one bivalent nickel compound, whereby a second oligomerization stage produces middle distillate hydrocarbon bases in the presence of an amorphous or zeolitic catalyst that has at least pore openings that contain 10 or 12 oxygen atoms, producing middle distillate hydrocarbon bases, and a fractionation stage.

    摘要翻译： 本发明描述了从由生物质获得的可再生来源生产的乙醇原料生产中间馏分烃碱的方法，其包括用于纯化所述原料的阶段，将所述纯化原料脱水成流出物的步骤 大部分是乙烯并且包括水，至少一个用于分离水的阶段，用于将流出物低聚的第一阶段，其大部分是乙烯至少一种烯烃流出物，其包含至少80重量％的烯烃 在含有至少一种二价镍化合物的均相催化剂的存在下，其具有四个或更多个碳原子，由此第二低聚阶段在无定形或沸石催化剂存在下产生中间馏分烃基，其至少具有孔开口， 含有10或12个氧原子，产生中间馏分烃基和分馏阶段。