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公开(公告)号:US07700803B2
公开(公告)日:2010-04-20
申请号:US10498131
申请日:2002-12-06
申请人: Helge Wessel , Verena Seitz , Klaus Harth , Volker Bomm , Nicola Christiane Aust
发明人: Helge Wessel , Verena Seitz , Klaus Harth , Volker Bomm , Nicola Christiane Aust
IPC分类号: C07C51/00
CPC分类号: C07C227/02 , B01J23/70 , B01J23/72 , B01J23/745 , B01J35/0053 , B01J37/03 , B01J37/18 , C07C51/295 , C07C59/125
摘要: Catalysts for preparing carboxylic acid salts from alcohols which a) consist of copper or b) comprise from 99.9 to 10% by weight of copper and from 0.01 to 90% by weight of iron and from 0 to 50% by weight of one or more other metals, and may optionally be doped, the hydroxides being obtained by precipitation of copper salt solutions or by coprecipitation of copper and iron salt solutions optionally containing salts of other metals using a base, and being reduced by hydrogen.
摘要翻译: 用于从醇制备羧酸盐的催化剂,a)由铜或b)组成的组合物包含99.9至10重量%的铜和0.01至90重量%的铁和0至50重量%的一种或多种其它 金属,并且可以任选地被掺杂,所述氢氧化物通过沉淀铜盐溶液或通过任选地含有其它金属的盐的铜和铁盐溶液的共沉淀而获得并被氢还原。
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公开(公告)号:US20050020850A1
公开(公告)日:2005-01-27
申请号:US10498131
申请日:2002-12-06
申请人: Helge Wessel , Verena Seitz , Klaus Harth , Volker Bomm , Nicola Aust
发明人: Helge Wessel , Verena Seitz , Klaus Harth , Volker Bomm , Nicola Aust
IPC分类号: B01J23/70 , B01J23/72 , B01J23/745 , B01J35/10 , B01J37/03 , B01J37/18 , C07B61/00 , C07C51/295 , C07C227/02 , C07C229/22 , C07C51/235
CPC分类号: C07C227/02 , B01J23/70 , B01J23/72 , B01J23/745 , B01J35/0053 , B01J37/03 , B01J37/18 , C07C51/295 , C07C59/125
摘要: Catalysts for preparing carboxylic acid salts from alcohols which a) consist of copper or b) comprise from 99.9 to 10% by weight of copper and from 0.01 to 90% by weight of iron and from 0 to 50% by weight of one or more other metals, and may optionally be doped, the hydroxides being obtained by precipitation of copper salt solutions or by coprecipitation of copper and iron salt solutions optionally containing salts of other metals using a base, and being reduced by hydrogen.
摘要翻译: 用于从醇制备羧酸盐的催化剂,a)由铜或b)组成的组合物包含99.9至10重量%的铜和0.01至90重量%的铁和0至50重量%的一种或多种其它 金属,并且可以任选地被掺杂,所述氢氧化物通过沉淀铜盐溶液或通过任选地含有其它金属的盐的铜和铁盐溶液的共沉淀而获得并被氢还原。
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公开(公告)号:US20050175531A1
公开(公告)日:2005-08-11
申请号:US10514557
申请日:2003-06-06
申请人: Helge Wessel , Markus Holzle , Klaus Harth
发明人: Helge Wessel , Markus Holzle , Klaus Harth
CPC分类号: B01J23/005 , B01J23/8926 , C01B3/326 , C01B3/40 , C01B2203/0233 , C01B2203/0261 , C01B2203/1047 , C01B2203/1064 , C01B2203/1082 , Y02P20/52
摘要: Hydrogenous gases are prepared by reacting hydrocarbons with air and/or water at temperatures of from 300 to 1000° C. and a pressure of from 1 to 20 bar in the presence of a catalyst by using a spinel catalyst which comprises at least one element of transition group VIII of the periodic table.
摘要翻译: 通过使用尖晶石催化剂,通过使烃与空气和/或水在温度为300至1000℃和压力为1至20巴的催化剂存在下反应制备氢气,所述尖晶石催化剂包含至少一种元素 周期表第八组过渡。
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公开(公告)号:US07468463B2
公开(公告)日:2008-12-23
申请号:US10591925
申请日:2005-03-04
申请人: Thorsten Johann , Oliver Löber , Eike Johannes Bergner , Klaus Ebel , Klaus Harth , Christian Walsdorff
发明人: Thorsten Johann , Oliver Löber , Eike Johannes Bergner , Klaus Ebel , Klaus Harth , Christian Walsdorff
IPC分类号: C07C45/65
CPC分类号: C07C45/002 , C07B2200/07 , C07C2601/08 , C07C2601/14 , C07C2601/16 , C07C47/21 , C07C49/403 , C07C49/395 , C07C47/02 , C07C49/647
摘要: The present invention relates to a process for preparing optically active aldehydes or ketones which have from 3 to 25 carbon atoms and at least one racemizable stereocenter by catalytic dehydrogenation of the corresponding optically active primary or secondary alcohols in the gas phase in the presence of a catalyst.
摘要翻译: 本发明涉及一种制备具有3至25个碳原子的光学活性醛或酮的方法和至少一种可消化的立体中心,通过在催化剂存在下在气相中相应的光学活性伯或仲醇的催化脱氢 。
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5.
公开(公告)号:US07291761B2
公开(公告)日:2007-11-06
申请号:US10507001
申请日:2003-03-04
CPC分类号: B01J19/26 , B01J8/025 , B01J8/0278 , B01J23/002 , B01J27/199 , B01J2523/00 , C07C45/33 , C07C45/35 , Y02P20/582 , C07C47/22 , B01J2523/13 , B01J2523/15 , B01J2523/3706 , B01J2523/41 , B01J2523/43 , B01J2523/48 , B01J2523/828
摘要: A process for the continuous heterogeneously catalyzed partial dehydrogenation of a hydrocarbon in the gas phase and in the presence of molecular oxygen, in which part of the product gas is recirculated to the reaction zone, and a reactor for carrying out such a process.
摘要翻译: 在气相和分子氧存在下,烃的连续不均匀催化部分脱氢的方法,其中部分产物气体再循环到反应区,以及用于进行这种方法的反应器。
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公开(公告)号:US20070191644A1
公开(公告)日:2007-08-16
申请号:US10591925
申请日:2005-03-04
申请人: Thorsten Johann , Oliver Lober , Eike Bergner , Klaus Ebel , Klaus Harth , Christian Walsdorff
发明人: Thorsten Johann , Oliver Lober , Eike Bergner , Klaus Ebel , Klaus Harth , Christian Walsdorff
CPC分类号: C07C45/002 , C07B2200/07 , C07C2601/08 , C07C2601/14 , C07C2601/16 , C07C47/21 , C07C49/403 , C07C49/395 , C07C47/02 , C07C49/647
摘要: The present invention relates to a process for preparing optically active aldehydes or ketones which have from 3 to 25 carbon atoms and at least one racemizable stereocenter by catalytic dehydrogenation of the corresponding optically active primary or secondary alcohols in the gas phase in the presence of a catalyst.
摘要翻译: 本发明涉及一种制备具有3至25个碳原子的光学活性醛或酮的方法和至少一种可消化的立体中心,通过在催化剂存在下在气相中相应的光学活性伯或仲醇的催化脱氢 。
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公开(公告)号:US20060140849A1
公开(公告)日:2006-06-29
申请号:US10529208
申请日:2003-09-25
IPC分类号: C01B7/00
摘要: The invention relates to a catalyst for the catalytic oxidation of hydrogen chloride, comprising on a support a) from 0.001 to 30% by weight of gold, b) from 0 to 3% by weight of one or more alkaline earth metals, c) from 0 to 3% by weight of one or more alkali metals, d) from 0 to 10% by weight of one or more rare earth metals, e) from 0 to 10% by weight of one or more further metals selected from the group consisting of ruthenium, palladium, platinum, osmium, iridium, silver, copper and rhenium, in each case based on the total weight of the catalyst.
摘要翻译: 本发明涉及一种用于催化氧化氯化氢的催化剂,其包括在载体上a)0.001至30重量%的金,b)0-3重量%的一种或多种碱土金属,c) 0至3重量%的一种或多种碱金属,d)0至10重量%的一种或多种稀土金属,e)0至10重量%的一种或多种其它金属,其选自 的钌,钯,铂,锇,铱,银,铜和铼,基于催化剂的总重量。
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公开(公告)号:US20050124837A1
公开(公告)日:2005-06-09
申请号:US10501878
申请日:2003-01-20
申请人: Christian Walsdorff , Michael Baier , Klaus Harth , Susanne Weber , Wilhelm Ruppel , Gotz-Peter Schindler
发明人: Christian Walsdorff , Michael Baier , Klaus Harth , Susanne Weber , Wilhelm Ruppel , Gotz-Peter Schindler
IPC分类号: C07B35/04 , C07C2/68 , C07C5/333 , C07C15/46 , C07D233/04
CPC分类号: C07C5/3332 , B01J23/83 , B01J37/0009 , B01J2523/00 , C07C2523/02 , C07C2523/10 , C07C2523/28 , C07C2523/745 , C07C15/46 , C07C15/52 , C07C15/44 , B01J2523/13 , B01J2523/22 , B01J2523/23 , B01J2523/3712 , B01J2523/842
摘要: A process for preparing alkenylaromatic compounds by reacting alkylaromatic compounds in the presence of steam and natural gas or methane over a suitable catalyst at a temperature of from 400 to 800° C. and a pressure of from 0.01 to 10 bar, wherein the molar ratio of steam to alkylaromatic compound is from 6.9:1 to 1:1 or the molar ratio of methane to alkylaromatic compound is from 0.1:1 to 8:1.
摘要翻译: 在蒸气和天然气或甲烷的存在下,在合适的催化剂上,在400-800℃的温度和0.01至10巴的压力下使烷基芳族化合物反应制备链烯基芳族化合物的方法,其中摩尔比 蒸汽至烷基芳族化合物的摩尔比为6.9:1至1:1,或甲烷与烷基芳族化合物的摩尔比为0.1:1至8:1。
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9.
公开(公告)号:US06395936B1
公开(公告)日:2002-05-28
申请号:US09936138
申请日:2001-09-10
申请人: Heiko Arnold , Signe Unverricht , Ulrich Hammon , Hans-Peter Neumann , Klaus Harth , Andreas Tenten
发明人: Heiko Arnold , Signe Unverricht , Ulrich Hammon , Hans-Peter Neumann , Klaus Harth , Andreas Tenten
IPC分类号: C07C4500
CPC分类号: C07C45/35 , B01J23/002 , B01J23/31 , B01J23/8876 , B01J35/0006 , B01J2523/00 , C07C51/252 , C07C47/22 , C07C57/04 , B01J2523/13 , B01J2523/41 , B01J2523/54 , B01J2523/68 , B01J2523/69 , B01J2523/842 , B01J2523/845
摘要: In a process for the catalytic gas-phase oxidation of propene to acrolein, the reaction gas starting mixture is passed with a propene loading of ≧160 l(S.T.P.)/l·h over a fixed-bed catalyst which is housed in two spatially successive reaction zones A,B, the reaction zone B being kept at a higher temperature than the reaction zone A.
摘要翻译: 在将丙烯催化气相氧化成丙烯醛的方法中,反应气体起始混合物在固定床催化剂上以大于等于160l(STP)/ 1h的丙烯负载通过,所述固定床催化剂容纳在两个空间连续反应 区域A,B,反应区域B保持在比反应区域A高的温度。
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公开(公告)号:US06255534B1
公开(公告)日:2001-07-03
申请号:US09240851
申请日:1999-02-01
申请人: Dirk Demuth , Thomas Fetzer , Volker Pratsch , Thomas Wendrich , Helmuth Menig , Ludwig Wambach , Klaus Harth
发明人: Dirk Demuth , Thomas Fetzer , Volker Pratsch , Thomas Wendrich , Helmuth Menig , Ludwig Wambach , Klaus Harth
IPC分类号: C07C4529
CPC分类号: C07C45/39 , C07C45/38 , C07C47/04 , C07C47/127
摘要: Carbonyl compounds of the formula where R1 is a hydrogen atom or an alkyl radical having from 1 to 3 carbon atoms, R2 is a hydrogen atom, an unsubstituted or C1-C3-alkyl-monosubstituted to -trisubstituted C2-C4-alkenyl radical or a radical of the formula where R3 is a hydrogen atom or together with R4 is an oxygen atom, R4 is the radical OR6 or together with R3 is an oxygen atom, R5 is a hydrogen atom, an alkyl radical having from 1 to 8 carbon atoms, an unsubstituted or C1-C3-alkyl-monosubstituted to -trisubstituted C2-C4-alkenyl radical or a cyclohexyl or cyclopentyl radical and R6 is an alkyl radical having from 1 to 4 carbon atoms, a cyclohexyl or cyclopentyl radical or a radical of the formula —CH2—CHO or —CH2—CH2—O—CH2—CHO, are prepared by gas-phase oxidation of methanol or alcohols of the formula where R1 and R5 are as defined above, by means of an oxygen-containing gas in the presence of copper- and/or silver-containing catalysts, the catalyst system used comprising at least one phosphorus-containing copper- and/or silver-containing catalyst.
摘要翻译: 式R 1的羰基化合物是氢原子或具有1至3个碳原子的烷基,R 2是氢原子,未取代的或C 1 -C 3烷基单取代的至三取代的C 2 -C 4 - 烯基或基团 其中R 3是氢原子或与R 4一起是氧原子,R 4是基团OR 6或与R 3一起是氧原子,R 5是氢原子,具有1至8个碳原子的烷基,未取代的 或C 1 -C 3烷基单取代至三取代的C 2 -C 4 - 烯基或环己基或环戊基,R 6是具有1至4个碳原子的烷基,环己基或环戊基或式-CH 2 -CHO或-CH2-CH2-O-CH2-CHO,通过在含铜的气体存在下,通过含氧气体,通过气相氧化甲醇或式(I)的化合物,其中R 1和R 5如上定义, 和/或含银催化剂,所用的催化剂体系包含至少一个p 含胡磷铜和/或含银催化剂。
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