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1.发明授权
公开(公告)号：US5064870A
公开(公告)日：1991-11-12
申请号：US595677
申请日：1990-10-10
申请人： Hans-Joachim Kollmeier , Georg Burkhart , Rolf-Dieter Langenhagen , Helmut Lammerting , Bernd-Jurgen Klietsch
发明人： Hans-Joachim Kollmeier , Georg Burkhart , Rolf-Dieter Langenhagen , Helmut Lammerting , Bernd-Jurgen Klietsch
IPC分类号： C08J9/00
CPC分类号： C08J9/0061 , C08J2375/04 , C08J2483/00 , Y10S521/904
摘要： In a method for the preparation of highly elastic, cold curing polyurethane foams, equilibrated organofunctional polysiloxanes of the average general formula ##STR1## wherein R.sup.1 is methyl or R.sup.2,R.sup.2 is chloropropyl,n has a value of 0 to 12,m has a value of 1 to 8 when R.sup.1 is methyl and a value of 0 to 6 when R.sup.1 is chloropropyl,are added in amounts of 0.01 to 2.0% by weight, based on the polyols, to the reaction batch.The stabilizing properties of the organofunctional polysiloxanes are superior to those of the known products. The foams, produced pursuant to the invention, have a coarser cell structure and a higher elasticity. The foams are more open-celled as measured by the impression force.
摘要翻译： 在制备高弹性，冷固化聚氨酯泡沫的方法中，平均通式为“IMAGE”的有机官能聚硅氧烷，其中R 1为甲基或R 2，R 2为氯丙基，n为0至12，m为 当R 1为甲基时为1至8，当R 1为氯丙基时为0至6的值，相对于多元醇为0.01至2.0重量％。 有机官能聚硅氧烷的稳定性优于已知产品。 根据本发明生产的泡沫具有较粗的泡孔结构和较高的弹性。 根据印象力量，泡沫更加开放。
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公开(公告)号：US4772698A
公开(公告)日：1988-09-20
申请号：US65886
申请日：1987-06-24
CPC分类号： C08G18/61 , B29C33/64 , C08G18/4009 , C08L75/04 , C08G2120/00
摘要： Process for producing molded polyurethane parts using as internal release agents, compounds of the general formula ##STR1## in amounts of 0.5 to 10 weight percent, based on the reaction formulation, in which at least one R.sup.2 radical in the average molecule represents ##STR2## R.sup.3 is a divalent hydrocarbon radical with 2 to 4 carbon atoms and R.sup.4, R.sup.5 are univalent hydrocarbon radicals or together are part of a morpholine or a piperazine ring. The molded polyurethane parts can be removed from the mold using significantly lower tensional forces without residues being built up on the mold.
摘要翻译： 使用作为内部脱模剂的模塑聚氨酯部件的制备方法，基于反应配方，通式为“I”的化合物的量为0.5至10重量％，其中平均分子中至少一个R 2基团表示
R3是具有2至4个碳原子的二价烃基，R 4，R 5是一价烃基或一起是吗啉或哌嗪环的一部分。 模制的聚氨酯部件可以使用显着较低的拉伸力从模具中移除，而不会在模具上堆积残留物。 -
3.发明授权Process for the production of highly resilient, cold-curing polyurethane foams 失效用于生产高弹性，冷固化聚氨酯泡沫的方法
公开(公告)号：US4478957A
公开(公告)日：1984-10-23
申请号：US532579
申请日：1983-09-15
CPC分类号： C08J9/0061 , C08J2375/04 , C08J2483/00 , Y10S521/904
摘要： The invention relates to a process for the manufacture of highly resilient, cold-curing polyurethane foams with the distinctive feature that polysiloxane-polyoxyalkylene block copolymers with the following characteristics are used as foam stabilizers:(a) the polysiloxane block is linear or branched and contains an average of 4 to 25 silicon atoms, wherein the organic radicals linked to the silicon atoms are polyoxyalkylene or methyl radicals and up to 30% of the methyl radicals can be replaced by substituted alkyl radicals with 1 to 4 carbon atoms, and/or phenyl radicals, and mixtures thereof;(b) the polyoxyalkylene portion consists of at least two polyoxyalkylene blocks, A.sub.1 and A.sub.2, which are formed from oxyethylene and oxypropylene units, wherein block A.sub.1 is formed from 45 to 100 mole percent of oxyethylene units and 55 to 0 mole percent of oxypropylene units and block A.sub.2 is formed from 0 to 50 mole percent of oxyethylene units and 100 to 50 mole percent of oxypropylene units, the molecular weight of the polyoxyalkylene blocks A.sub.1 and A.sub.2 in each case being 150 to 1,200 and the molar ratio of blocks A.sub.1 :A.sub.2 falling in the range of 20:80 to 80:20; and(c) the polysiloxane block is linked to the polyoxyalkylene blocks by SiOC or SiC bridges, 1.5 to 10 polyoxyalkylene blocks being linked to each polysiloxane block on the average.The stabilizers have improved stabilizing properties and form open-cell foams at a relatively wide processing latitude.
摘要翻译： 本发明涉及用于制造具有以下特征的聚硅氧烷 - 聚氧化烯嵌段共聚物作为泡沫稳定剂的独特特征的高弹性，冷固化聚氨酯泡沫的方法：（a）聚硅氧烷嵌段是直链或支链的并含有 平均4至25个硅原子，其中与硅原子连接的有机基团是聚氧化烯或甲基，并且高达30％的甲基可以被具有1至4个碳原子的取代的烷基取代，和/或苯基 自由基及其混合物; （b）聚氧化烯部分由氧化乙烯和氧化丙烯单元形成的至少两个聚氧化烯嵌段A1和A2组成，其中嵌段A1由45-100摩尔％的氧化乙烯单元和55至0摩尔％的氧化丙烯单元形成 并且块A2由0至50摩尔％的氧化乙烯单元和100至50摩尔％的氧化丙烯单元形成，聚氧化烯嵌段A1和A2的分子量在每种情况下为150至1,200，并且嵌段A1：A2的摩尔比 落在20:80至80:20的范围内; 和（c）聚硅氧烷嵌段通过SiOC或SiC桥连接到聚氧化烯嵌段上，1.5至10个聚氧化烯嵌段平均连接到每个聚硅氧烷嵌段。 稳定剂具有改善的稳定性能并且在相对宽的加工范围内形成开孔泡沫。
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4.发明授权
公开(公告)号：US5043409A
公开(公告)日：1991-08-27
申请号：US439267
申请日：1989-11-20
IPC分类号： B29C33/64 , B29C67/24 , C08G18/61 , C08K5/5419 , C08L75/04
CPC分类号： C08K5/5419 , B29C33/64 , C08G18/61 , C08L75/04 , B29C67/246 , B29K2075/00 , C08G2120/00 , C08G2125/00
摘要： In a process for the preparation of molded polyurethane or polyurea articles, especially by the RIM process, internal release agents of the general formula ##STR1## are used. In this formula R.sup.1 =is alkyl with 20 to 40 carbon atoms,R.sup.2 =is R.sup.1 or methyl,R.sup.3 =is --(CH.sub.2).sub.s -- or --[(CH.sub.2).sub.t --].sub.r (OC.sub.2 H.sub.4).sub.x --(OC.sub.3 H.sub.6).sub.y --whereins=3 to 12,t=3 to 12,r=0 or 1,x=0 to 10,y=0 to 10,and the sum of x+y is not less than 1,n=0 to 50,m=2 to 100, m being greater than n,p=0 to 5,with the proviso that the siloxane has a melting point of not less than 38.degree. C.The compounds are finely dispersed with an average particle size of not less than 5 to 100.mu. in amounts of 0.5 to 5 weight percent, based on the reaction formulation. The release agents are preferably suspended in a portion of the polyol or polyolamine that is to be foamed.The release agents exhibit outstanding release properties and, in the event that molded polyurethane or polyurea articles with a cellular core are prepared, do not prevent the development and/or the maintenance of the cellular structure.
摘要翻译： 在制备模塑聚氨酯或聚脲制品的方法中，特别是通过RIM方法，使用通式为＆lt; IMAGE＆gt; + TR＆lt; IMAGE＆gt;的内部脱模剂。 在该式中R1 =是具有20至40个碳原子的烷基，R2 = R1或甲基，R3 =是 - （CH2）s-或 - [（CH2）t-] r（OC2H4）x-（OC3H6） 其中s = 3至12，t = 3至12，r = 0或1，x = 0至10，y = 0至10，x + y之和不小于1，n = 0至50， m = 2〜100，m大于n，p = 0〜5，条件是硅氧烷的熔点不低于38℃。化合物细分散，平均粒径不小于 基于反应制剂，其量为0.5至5重量％的5至100微摩尔。 脱模剂优选悬浮在待发泡的多元醇或多元胺胺的一部分中。 脱模剂具有突出的脱模性能，并且在制备具有多孔芯的模制聚氨酯或聚脲制品的情况下，不妨碍细胞结构的显影和/或维持。
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公开(公告)号：US4692292A
公开(公告)日：1987-09-08
申请号：US813667
申请日：1985-12-26
CPC分类号： B29C33/64 , B29K2503/00
摘要： Process for manufacturing of molded objects by hot-pressing lignocellulose-containing materials with polyisocyanates as binders while using an agent to release the molded article from the surface of the metal press used. A mixture of the organosilicon compounds is applied onto the surface of the cauls or molds which faces the material to be pressed, and cured at a temperature from 100.degree. to 200.degree. C., preferably in the presence of known curing catalysts. The mixture of organosilicon compounds comprising(a) 20 to 65 weight percent of a silicone resin of the general formula ##EQU1## in which R.sup.1 is a low molecular weight alkyl radical with 1 to 4 carbon atoms,a has a value of 1 to 1.7,b has a value of 0.3 to 1.0;(b) 30 to 65 weight percent of an .alpha.,.omega.-methylsiloxanediol with an average molecular weight of 1,000 to 20,000;(c) 5 to 15 weight percent of a silicate ester of the general formula ##EQU2## in which R.sup.2 is a low molecular weight hydrocarbon radical with 2 to 4 carbon atoms,c has a value of 2.1 to 4.0;wherein the sum of components (a), (b) and (c) amounts to 100. The release properties can be further improved if more closely defined polysiloxane block copolymers are used as internal release agents.
摘要翻译： 通过使用多异氰酸酯作为粘合剂将含木素纤维素的材料热压制成模制物体的方法，同时使用试剂从所使用的金属压力机的表面释放模塑制品。 将有机硅化合物的混合物施加到面向被压制材料的凹槽或模具的表面上，并在100℃至200℃的温度下，优选在已知的固化催化剂存在下固化。 有机硅化合物的混合物包含（a）20至65重量％的通式为“IMAGE”的有机硅树脂，其中R 1为具有1至4个碳原子的低分子量烷基，a具有1至1.7的值 ，b的值为0.3〜1.0; （b）30至65重量％的平均分子量为1,000至20,000的α，ω-甲基硅氧烷二醇; （c）5至15重量％的通式为“IMAGE”的硅酸酯，其中R2是具有2至4个碳原子的低分子量烃基，c具有2.1至4.0的值; 其中组分（a），（b）和（c）的总和等于100.如果使用更密切限定的聚硅氧烷嵌段共聚物作为内部脱模剂，则可进一步改善剥离性能。
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公开(公告)号：US5079270A
公开(公告)日：1992-01-07
申请号：US425810
申请日：1989-10-23
CPC分类号： C08G18/698 , B29C33/62 , C08G18/69 , C08L75/00 , B29K2075/00 , B29K2105/04 , C08G2120/00 , C08G2125/00
摘要： A method and composition are disclosed for the preparation of polyurethane and polyurea molded articles, particularly according to the RIM method, in which liquid polybutadiene with an average molecular weight of 1,500 to 6,000 is used as an internal release agent in an amount of 0.5 to 5% by weight, based on the reaction formulation. The release agent is highly effective and demolded products which contain this release agent can be painted over without formation of surface defects.
摘要翻译： 公开了用于制备聚氨酯和聚脲模制品的方法和组合物，特别是根据RIM方法，其中平均分子量为1,500至6,000的液体聚丁二烯用作0.5至5的内部脱模剂 基于反应制剂的重量％。 脱模剂是高度有效的，含有这种脱模剂的脱模产品可以涂覆而不形成表面缺陷。
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公开(公告)号：US4728690A
公开(公告)日：1988-03-01
申请号：US840911
申请日：1986-03-18
CPC分类号： C08G18/61 , B29C33/64 , C08G18/4009 , C08L75/04 , C08G2120/00
摘要： Process for producing molded polyurethane parts using as internal release agents, compounds of the general formula ##STR1## in amounts of 0.5 to 10 weight percent, based on the reaction formulation, in which at least one R.sup.2 radical in the average molecule represents ##STR2## R.sup.3 is a divalent hydrocarbon radical with 2 to 4 carbon atoms and R.sup.4, R.sup.5 are univalent hydrocarbon radicals or together are part of a morpholine or a piperazine ring. The molded polyurethane parts can be removed from the mold using significantly lower tensional forces without residues being built up on the mold.
摘要翻译： 使用作为内部脱模剂的模塑聚氨酯部件的制备方法，基于反应配方，通式为“I”的化合物的量为0.5至10重量％，其中平均分子中至少一个R 2基团表示
R3是具有2至4个碳原子的二价烃基，R 4，R 5是一价烃基或一起是吗啉或哌嗪环的一部分。 模制的聚氨酯部件可以使用显着较低的拉伸力从模具中移除，而不会在模具上堆积残留物。 -
8.发明授权Use of polysiloxane polyoxyalkylene block copolymers for the preparation of rigid polyurethane foams 失效聚硅氧烷聚合物嵌段共聚物用于制备刚性聚氨酯泡沫塑料的应用
公开(公告)号：US5130344A
公开(公告)日：1992-07-14
申请号：US575349
申请日：1990-08-30
IPC分类号： C08J9/00
CPC分类号： C08J9/0061 , C08J2375/04 , C08J2483/00
摘要： A process of preparing rigid polyurethane foams is disclosed, wherein polysiloxane polyoxyalkylene block copolymers which have at least one aminofunctional group of the general formula, ##STR1## which is linked to a silicon atom, are used in an amount of 0.2 to 5% by weight, based on the polyol or the prepolymer having isocyanate groups, to provide polyurethane foams, which otherwise contain closed cells, with at least partially open the cells.
摘要翻译： 公开了一种制备刚性聚氨酯泡沫体的方法，其中具有至少一个通式的氨基官能团（与IMA连接的氨基官能团）的聚硅氧烷聚氧化烯嵌段共聚物的用量为0.2-5重量％ 基于多元醇或具有异氰酸酯基团的预聚物，以提供其它方式包含闭孔的聚氨酯泡沫，至少部分地打开细胞。
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9.发明授权Betaine group-containing polysaccharides with recurring anhydroglucose units, their synthesis and their use in cosmetic preparations 失效含有复合氨基酸单体的含有聚集团的多糖，它们的合成及其在化妆品制备中的应用
公开(公告)号：US5124446A
公开(公告)日：1992-06-23
申请号：US353349
申请日：1989-05-17
CPC分类号： D21H17/24 , A61K8/73 , A61K8/731 , A61K8/732 , A61Q5/02 , A61Q5/12 , C08B11/193 , C08B31/125 , Y10S514/88 , Y10S514/881
摘要： Betaine group-containing polysaccharides with recurring anhydroglucose units of the average, general formula ##STR1## are disclosed. In this formula the R.sup.1 groups are the same or different and represent methyl, (C.sub.n H.sub.2n O).sub.m R.sup.2 or ##STR2## in which n=2 or 3, m=0 to 10, p=0 to 10 and R.sup.2 is a hydrogen atom or the betaine group ##STR3## in which R.sup.3 and R.sup.4 are the same or different and represent an alkyl group with 1 to 4 carbon atoms and R.sup.5 is a divalent aliphatic hydrocarbon group with 1 to 10 carbon atoms, with the proviso that at least 0.5% of the R.sup.1 groups in the polysaccharide molecule represent the betaine group.Also disclosed is a method for the synthesis of these compounds and their use in cosmetic preparations, especially for the care of the hair. In addition, novel compounds of the general formula ##STR4## are disclosed as intermediates in which the substituents R.sup.3, R.sup.4 and R.sup.5 have the above meaning.
摘要翻译： 公开了具有平均通式
的具有重复脱水葡萄糖单元的含甜菜碱基团的多糖。 在该式中，R 1基团相同或不同，表示甲基，（C n H 2n O）m R 2或其中n = 2或3，m = 0至10，p = 0至10，且R 2为氢原子或 甜菜碱组 ，其中R 3和R 4相同或不同，表示具有1至4个碳原子的烷基，R 5是具有1至10个碳原子的二价脂族烃基，条件是至少0.5％ 多糖分子中的R1基团代表甜菜碱组。 还公开了合成这些化合物的方法及其在化妆品制剂中的用途，特别是用于护理头发。 此外，通式（IMAGE）的新化合物作为其中取代基R 3，R 4和R 5具有上述含义的中间体被公开。 -
10.发明授权Process of producing cross-linked urethane-group comprising foams of open-cell structure 失效制备包含开孔结构的泡沫的交联的氨基甲酸酯基团的方法
公开(公告)号：US4211849A
公开(公告)日：1980-07-08
申请号：US564052
申请日：1975-04-01
CPC分类号： C08G18/6688 , C08G18/3851 , C08G18/6677 , C08G2101/005 , Y10S521/904
摘要： In the disclosed process of producing resilient open-celled, cross-linked polyurethane foams, by foaming polyol, polyisocyanate, catalyst and blowing agent, the foaming is effected in the presence of a cross-linker which is a saturated or unsaturated, aliphatic, cycloaliphatic, heteroaliphatic or arylaliphatic crystalline polyhydroxy compound having at least 3 hydroxy groups. The crystalline polyhydroxy compound is insoluble or only slightly soluble in the polyol to be foamed and melts within the temperature range of about 60.degree.-160.degree. C. The amount of crystalline polyhydroxy compound to be used corresponds to about 0.1-5.0 hydroxy equivalent weights per 1 hydroxy equivalent weight of the polyol to be foamed.
摘要翻译： 在所公开的生产弹性开孔交联聚氨酯泡沫的方法中，通过发泡多元醇，多异氰酸酯，催化剂和发泡剂，发泡在交联剂的存在下进行，交联剂是饱和或不饱和的，脂族的，脂环族的 ，具有至少3个羟基的杂脂族或芳脂族结晶多羟基化合物。 结晶多羟基化合物不溶于或仅微溶于待发泡的多元醇中并在约60-160℃的温度范围内熔融。结晶多羟基化合物的用量相当于每个约0.1-5.0羟基当量重量 1待发泡多元醇的羟基当量重量。
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