公开(公告)号：US20100282591A1

公开(公告)日：2010-11-11

申请号：US12808368

申请日：2008-12-22

Applicant: Henrik Andtsjo ,  Maarit Aarni-Sirvio

Inventor： Henrik Andtsjo ,  Maarit Aarni-Sirvio

IPC: C02F1/04 ,  C02F1/26

CPC classification number: C07C37/72 ,  B01D3/143 ,  B01D17/0211 ,  B01D17/0214 ,  B01D17/047 ,  C02F1/04 ,  C02F1/26 ,  C02F2101/32 ,  C02F2101/345 ,  C02F2209/06 ,  C07C37/685 ,  C07C37/74 ,  C07C39/04

Abstract: The present application concerns a process for the removal of hydrocarbons from an aqueous stream, which process may include conducting a phenol-containing water stream into a separation column, separating the phenol-containing water in the column using heat to form an overhead portion and a bottoms portion, and collecting the overhead portion as well as the bottoms portion. Further, the process may include adding an eluent to an aqueous stream, thereby forming an aqueous mixture, subsequently conducting the aqueous mixture into a separation vessel, wherein it is allowed to settle into two phases, which form a hydrocarbon stream and a phenol-containing water stream, subsequently collecting the hydrocarbon stream, and conducting the phenol-containing water stream to the separation column for further separation.

Abstract translation: 本申请涉及从水流中除去烃的方法，该方法可以包括将含苯酚的水流导入分离塔，使用热分离柱中的含苯酚的水以形成塔顶馏分和 底部部分，以及收集顶部部分以及底部部分。 此外，该方法可以包括向含水物流中加入洗脱液，从而形成水性混合物，随后将含水混合物导入分离容器中，其中将其沉降为两相，其形成烃流和含苯酚的 水流，随后收集烃流，并将含苯酚的水流导入分离塔进行进一步分离。

公开(公告)号：US20080045674A1

公开(公告)日：2008-02-21

申请号：US10592638

申请日：2005-04-28

Applicant: Henrik Andtsjo

Inventor： Henrik Andtsjo

IPC: C08F110/02 ,  B01J19/24 ,  C08F2/06 ,  C08F10/02

CPC classification number: C08F10/02 ,  C08F110/02 ,  C08F2/14

Abstract: Process and apparatus for continuously producing olefin polymers in a slurry phase reactor in a hydrocarbon diluent or liquid monomer. The process comprises continuously withdrawing from the slurry phase reactor a polymer slurry containing polymer and a fluid phase, which contains hydrocarbons and optionally hydrogen, and concentrating the slurry with a self-cleaning screen by removing a part of the fluid phase to provide a concentrated slurry. The openings of the screen, which can have a planar or cylindrical configuration, are smallest at the inflow surface of the screen and increases towards the outflow surface. By the present invention, the need for service and maintenance is significantly reduced.

Abstract translation: 在烃稀释剂或液体单体中的淤浆相反应器中连续生产烯烃聚合物的方法和设备。 该方法包括连续地从淤浆相反应器中取出含有聚合物的聚合物浆料和含有烃和任选的氢的流体相，并通过除去一部分流体相使自清洁筛网浓缩浆料以提供浓缩浆料 。 屏幕的开口可以具有平面或圆柱形构造，在屏幕的流入表面处最小，并朝着流出表面增加。 通过本发明，显着地减少了对服务和维护的需求。

公开(公告)号：US5326835A

公开(公告)日：1994-07-05

申请号：US920569

申请日：1992-08-20

Applicant: Antero Ahvenainen ,  Kari Sarantila ,  Henrik Andtsjo ,  Jouni Takakarhu ,  Ari Palmroos

Inventor： Antero Ahvenainen ,  Kari Sarantila ,  Henrik Andtsjo ,  Jouni Takakarhu ,  Ari Palmroos

IPC: C08F2/00 ,  B01J8/24 ,  B01J19/24 ,  C08F2/06 ,  C08F2/34 ,  C08F10/00 ,  C08F10/02 ,  C08F110/02 ,  C08F297/08 ,  C08L23/08

CPC classification number: C08F297/083 ,  B01J19/2435 ,  B01J8/24 ,  C08F110/02 ,  Y02P20/544 ,  Y10S526/905

Abstract: The invention concerns a multi-stage process for producing polyethylene having a bimodal and/or broad molecular weight distribution in the presence of an ethylene polymerizing catalyst system in a multistep reaction sequence, in which the first reaction step is a liquid phase polymerization step and the second reaction step is formed by one or more gas-phase polymerization steps. According to the process of the invention in the first reaction step ethylene is polymerized in a loop reactor (10) in an inert low-boiling hydrocarbon medium the residence time being at least 10 minutes, reaction mixture is discharged from the loop reactor (10) and at least a substantial part of the inert hydrocarbon mixture is separated and the polymer is transferred into one or more gas-phase reactors (30), where the polymerization is completed in the presence of ethylene and optionally hydrogen and a comonomer. As an inert hydrocarbon medium in the loop reactor (10) propane can be used and the polymerization can be carried out also so that the mixture of inert hydrocarbon, monomer, hydrogen and optional comonomer is under supercritical conditions.

Abstract translation: PCT No.PCT / FI91 / 00406 Sec。 371日期：1992年8月20日 102（e）日期1992年8月20日PCT 1991年12月20日PCT PCT。 出版物WO92 / 12182 日本1992年7月23日。本发明涉及在多步反应序列中在乙烯聚合催化剂体系存在下生产具有双峰和/或宽分子量分布的聚乙烯的多阶段方法，其中第一反应步骤为 通过一个或多个气相聚合步骤形成液相聚合步骤和第二反应步骤。 根据本发明在第一反应步骤中的方法，乙烯在环状反应器（10）中在惰性低沸点烃介质中聚合，停留时间为至少10分钟，反应混合物从环管反应器（10）排出， 并且将至少大部分惰性烃混合物分离并将聚合物转移到一个或多个气相反应器（30）中，其中聚合在乙烯和任选的氢气和共聚单体存在下完成。 作为环管反应器（10）中的惰性烃介质，可以使用丙烷，也可以进行聚合，使得惰性烃，单体，氢和任选的共聚单体的混合物处于超临界条件下。

公开(公告)号：US08758573B2

公开(公告)日：2014-06-24

申请号：US12808368

申请日：2008-12-22

Applicant: Henrik Andtsjo ,  Maarit Aarni-Sirvio

Inventor： Henrik Andtsjo ,  Maarit Aarni-Sirvio

IPC: C02F1/04 ,  B01D3/34 ,  C07C39/04 ,  B01D17/02

CPC classification number: C07C37/72 ,  B01D3/143 ,  B01D17/0211 ,  B01D17/0214 ,  B01D17/047 ,  C02F1/04 ,  C02F1/26 ,  C02F2101/32 ,  C02F2101/345 ,  C02F2209/06 ,  C07C37/685 ,  C07C37/74 ,  C07C39/04

Abstract: The present application concerns a process for the removal of hydrocarbons from an aqueous stream, which process may include conducting a phenol-containing water stream into a separation column, separating the phenol-containing water in the column using heat to form an overhead portion and a bottoms portion, and collecting the overhead portion as well as the bottoms portion. Further, the process may include adding an eluent to an aqueous stream, thereby forming an aqueous mixture, subsequently conducting the aqueous mixture into a separation vessel, wherein it is allowed to settle into two phases, which form a hydrocarbon stream and a phenol-containing water stream, subsequently collecting the hydrocarbon stream, and conducting the phenol-containing water stream to the separation column for further separation.

Abstract translation: 本申请涉及从水流中除去烃的方法，该方法可以包括将含苯酚的水流导入分离塔，使用热分离柱中的含苯酚的水以形成塔顶馏分和 底部部分，以及收集顶部部分以及底部部分。 此外，该方法可以包括向含水物流中加入洗脱液，从而形成水性混合物，随后将含水混合物导入分离容器中，其中将其沉降为两相，其形成烃流和含苯酚的 水流，随后收集烃流，并将含苯酚的水流导入分离塔进行进一步分离。

公开(公告)号：US20060052552A1

公开(公告)日：2006-03-09

申请号：US10532607

申请日：2003-10-27

Applicant: Marianna Vuorikari ,  Esa Korhonen ,  Henrik Andtsjo ,  Samuli Zitting

Inventor： Marianna Vuorikari ,  Esa Korhonen ,  Henrik Andtsjo ,  Samuli Zitting

IPC: C08F2/00 ,  B01J19/18 ,  B01J19/00

CPC classification number: B01J19/2435 ,  B01J8/0055 ,  B01J8/20 ,  B01J8/26 ,  B01J2219/00006 ,  B01J2219/0004 ,  B01J2219/00254 ,  C08F10/00 ,  C08F110/02 ,  C08F210/16 ,  C08F2/01 ,  C08F2/001 ,  C08F2/34 ,  C08F2/14 ,  C08F2500/12 ,  C08F210/08

Abstract: The present invention concerns a process and an apparatus for continuous polymerisation of olefin monomers in a cascade of polymerisation reactors. According to the process, an olefin monomer is polymerised first in slurry phase in an inert hydrocarbon diluent in at least one loop reactor and then, subsequently, in gas phase in at least one gas phase reactor. According to the invention, a polymer slurry is continuously withdrawn from the loop reactor and optionally concentrated. The concentrated slurry is conducted to a high pressure flash unit in order to remove the remaining fluid phase, and fed to the gas phase reactor. With the process described in this invention, it is possible to produce bimodal polyethylene with good properties. The operation of the process is stable because of the truly continuous operation.

公开(公告)号：US08916660B2

公开(公告)日：2014-12-23

申请号：US14237366

申请日：2012-11-16

Applicant: Klaus Nyfors ,  Jari Aarila ,  Jari Hatonen ,  Henrik Andtsjo ,  Eira Johansson ,  Mikko Lylykangas

Inventor： Klaus Nyfors ,  Jari Aarila ,  Jari Hatonen ,  Henrik Andtsjo ,  Eira Johansson ,  Mikko Lylykangas

IPC: C08F2/34 ,  C08F6/00 ,  B01J8/00 ,  B01J8/44 ,  C08F2/01 ,  B01J8/18 ,  C08F10/00 ,  C08J11/04 ,  C08F10/02 ,  C08F10/06

CPC classification number: C08F2/01 ,  B01J8/003 ,  B01J8/005 ,  B01J8/1809 ,  B01J2208/00548 ,  B01J2208/0061 ,  B01J2208/00761 ,  B01J2219/00247 ,  B01J2219/00254 ,  C08F2/34 ,  C08F10/00 ,  C08J11/04 ,  Y10S526/92 ,  C08F110/06 ,  C08F2500/12 ,  C08F210/16 ,  C08F210/08

Abstract: Process and apparatus for recovering polymer from a gas phase reactor having a distribution plate via an outlet vessel comprising at least one apparatus for the breakup of polymeric agglomerates, the apparatus further comprising a feed pipe connecting the gas phase reactor and the outlet vessel a return gas line connecting the gas phase reactor and the outlet vessel, means for varying the flow rate through the return gas line from the outlet vessel to the gas phase reactor, and means for varying the outlet rate of polymer product from the outlet vessel.

Abstract translation: 用于从具有分布板的气相反应器中回收聚合物的方法和装置，所述反应器具有经由出口容器的出口容器，所述出口容器包括用于分解聚合物附聚物的至少一种装置，该装置还包括将气相反应器和出口容器连接的回流气体 连接气相反应器和出口容器的管线，用于改变通过从出口容器到气相反应器的回气管线的流速的装置，以及用于改变聚合物产物从出口容器的出口速率的装置。

公开(公告)号：US20140171611A1

公开(公告)日：2014-06-19

申请号：US14237366

申请日：2012-11-16

Applicant: Klaus Nyfors ,  Jari Aarila ,  Jari Hatonen ,  Henrik Andtsjo ,  Eira Johansson ,  Mikko Lylykangas

Inventor： Klaus Nyfors ,  Jari Aarila ,  Jari Hatonen ,  Henrik Andtsjo ,  Eira Johansson ,  Mikko Lylykangas

IPC: B01J8/00 ,  C08F2/01

CPC classification number: C08F2/01 ,  B01J8/003 ,  B01J8/005 ,  B01J8/1809 ,  B01J2208/00548 ,  B01J2208/0061 ,  B01J2208/00761 ,  B01J2219/00247 ,  B01J2219/00254 ,  C08F2/34 ,  C08F10/00 ,  C08J11/04 ,  Y10S526/92 ,  C08F110/06 ,  C08F2500/12 ,  C08F210/16 ,  C08F210/08

Abstract: Process and apparatus for recovering polymer from a a gas phase reactor having a distribution plate via an outlet vessel comprising at least one apparatus for the breakup of polymeric agglomerates, the apparatus further comprising a feed pipe connecting the gas phase reactor and the outlet vessel a return gas line connecting the gas phase reactor and the outlet vessel, means for varying the flow rate through the return gas line from the outlet vessel to the gas phase reactor, and means for varying the outlet rate of polymer product from the outlet vessel.

Abstract translation: 用于从具有分布板的气相反应器中回收聚合物的方法和装置，所述气相反应器具有经由出口容器的出口容器，所述出口容器包括至少一种用于分解聚合物附聚物的装置，该装置还包括将气相反应器和出口容器连接的回流气体 连接气相反应器和出口容器的管线，用于改变通过从出口容器到气相反应器的回气管线的流速的装置，以及用于改变聚合物产物从出口容器的出口速率的装置。

公开(公告)号：US20080039597A1

公开(公告)日：2008-02-14

申请号：US11578138

申请日：2005-04-29

Applicant: Marianna Vuorikari ,  Esa Korhonen ,  Henrik Andtsjo ,  Samuli Zitting

Inventor： Marianna Vuorikari ,  Esa Korhonen ,  Henrik Andtsjo ,  Samuli Zitting

IPC: C08J11/04 ,  B01J19/00

CPC classification number: B01J19/1837 ,  B01J8/0015 ,  B01J2208/00274 ,  B01J2208/003 ,  B01J2208/00761 ,  B01J2219/00006 ,  C08F6/003 ,  C08F6/20 ,  C08F10/02 ,  C08F110/02 ,  C08F210/16 ,  C08L23/04 ,  C08F2/14 ,  C08F210/08

Abstract: The present invention concerns a process and an apparatus for continuous polymerisation of olefin monomers. In particular, the present invention concerns a process and an apparatus for continuous polymerisation olefin monomers like ethylene and other monomers, wherein an olefin monomer is polymerised in slurry phase in an inert hydrocarbon diluent in at least one loop reactor. According to the invention, a polymer slurry is continuously withdrawn from the loop reactor and concentrated. The concentrated slurry is conducted to a flash unit in order to remove the remaining fluid phase, and gas obtained is compressed in a flash gas compressor before it is being fed to a distillation section. By means of the present invention it is possible reduce the size of the flash gas compressor and the capacity of the distillation sections. This significantly reduces investment cost for a continuously operated polymerization apparatus.

Abstract translation: 本发明涉及烯烃单体连续聚合的方法和设备。 特别地，本发明涉及用于连续聚合烯烃单体如乙烯和其它单体的方法和设备，其中烯烃单体在淤浆相中在惰性烃稀释剂中在至少一个环管反应器中聚合。 根据本发明，聚合物浆液从环流反应器中连续取出并浓缩。 将浓缩的浆料送入闪蒸装置以除去剩余的流体相，所获得的气体在进料到蒸馏段之前在闪蒸气体压缩机中被压缩。 通过本发明，可以减小闪蒸气体压缩机的尺寸和蒸馏段的容量。 这显着降低了连续操作的聚合装置的投资成本。

公开(公告)号：US5391654A

公开(公告)日：1995-02-21

申请号：US66004

申请日：1993-05-25

Applicant: Antero Ahvenainen ,  Kari Sarantila ,  Henrik Andtsjo

Inventor： Antero Ahvenainen ,  Kari Sarantila ,  Henrik Andtsjo

IPC: C08F2/34 ,  C08F2/06 ,  C08F4/00 ,  C08F4/60 ,  C08F10/00 ,  C08F10/02 ,  C08F110/02

CPC classification number: C08F10/02 ,  C08F110/02 ,  Y02P20/544 ,  Y10S526/905

Abstract: The invention relates to a method for homo- or copolymerizing ethene in the presence of a Ziegler-Natta or other catalyst and a possible comonomer and hydrogen for preparing a homo- or copolymer of ethene in particle form in propane. In accordance with the invention, the polymerization is performed in a loop reactor under such supercritical conditions where the temperature is higher than the critical temperature of the mixture formed by ethene, propane and a possible hydrogen and a comonomer, but lower than the melting temperature of the ethene polymer forming in the polymerization, and the pressure is higher than the critical pressure of said mixture.

Abstract translation: PCT No.PCT / FI91 / 00397 Sec。 371日期：1993年5月25日 102（e）日期1993年5月25日PCT 1991年12月18日PCT PCT。 公开号WO92 / 12181 日本1992年7月23日。本发明涉及在齐格勒 - 纳塔或其他催化剂和可能的共聚单体和氢气存在下均匀或共聚乙烯的方法，用于制备丙烷中颗粒形式的乙烯的均聚物或共聚物 。 根据本发明，聚合反应在环流反应器中在这样的超临界条件下进行，其中温度高于由乙烯，丙烷和可能的氢和共聚单体形成的混合物的临界温度，但低于熔融温度 聚合中形成的乙烯聚合物，并且压力高于所述混合物的临界压力。