公开(公告)号：US20110245445A1

公开(公告)日：2011-10-06

申请号：US12746081

申请日：2008-10-24

Applicant: Amir Karbasi ,  Esa Korhonen ,  Ensio Hietanen ,  Karin H. Knudsen ,  Kai Hagane ,  Fred Bergmann ,  Klaus Nyfors

Inventor： Amir Karbasi ,  Esa Korhonen ,  Ensio Hietanen ,  Karin H. Knudsen ,  Kai Hagane ,  Fred Bergmann ,  Klaus Nyfors

IPC: C08F6/28 ,  C08F10/00 ,  B29B13/00

CPC classification number: B29C71/0009 ,  B29B9/16 ,  B29C2071/0027 ,  B29C2071/0036 ,  B29K2023/12 ,  C08F6/005

Abstract: The invention is directed to a process for the treatment of plastic material comprising a) providing a liquid; b) contacting the plastic material with the liquid; c) keeping the plastic material in the liquid at Tb−25° C. to Tb of the liquid, wherein Tb is the boiling point of the liquid at the applied pressure; and d) removing the plastic material from the liquid. Furthermore, the invention is directed to the use of a liquid for the treatment of plastic material and to a plant for treating plastic material with a liquid.

Abstract translation: 本发明涉及一种用于处理塑料材料的方法，包括：a）提供液体; b）将塑料材料与液体接触; c）将塑料材料保持在液体中的Tb-25℃至Tb的液体，其中Tb是施加压力下液体的沸点; 和d）从液体中去除塑料材料。 此外，本发明涉及使用液体来处理塑料材料和用于用液体处理塑料材料的设备。

公开(公告)号：US07812102B2

公开(公告)日：2010-10-12

申请号：US09831600

申请日：1999-11-12

Applicant: Jouni Kivelä ,  Klaus Nyfors

Inventor： Jouni Kivelä ,  Klaus Nyfors

IPC: C08F2/00 ,  B01J8/18

CPC classification number: B01J8/24 ,  B01J8/003 ,  B01J8/005 ,  B01J2208/00681 ,  B01J2208/00761 ,  B01J2219/00247 ,  C08F2/34 ,  C08F10/00

Abstract: A method and an apparatus of discharging polymer from a continuously operated gas phase reactor, wherein at least one monomer is polymerized in a bed containing active catalyst formed by catalyst and polymer particles suspended in a fluid, the bed defining a fluidized bed level in said reactor. The invention comprises continuously withdrawing polymer powder from the reactor; and adjusting the discharge rate of the polymer powder so as to maintain a constant bed level during polymerization. By means of the invention the discharge of the polymer can be made truly continuous without any disturbance of the polymerization. The rate of withdrawn polymer can be flexibly adjusted depending on the progress of the polymerization and it can also easily be scaled up if the capacity of the reactor is increased.

Abstract translation: 一种从连续操作的气相反应器中排出聚合物的方法和装置，其中至少一种单体在包含由催化剂形成的活性催化剂和悬浮在流体中的聚合物颗粒的床中聚合，所述床在所述反应器中限定流化床水平 。 本发明包括从反应器中连续取出聚合物粉末; 并调节聚合物粉末的排出速率，以便在聚合过程中保持恒定的床层。 通过本发明，可以使聚合物的排放真正连续，而不会导致聚合紊乱。 退出的聚合物的速率可以根据聚合的进程灵活地调节，并且如果反应器的容量增加，也可以容易地放大。

公开(公告)号：US08916660B2

公开(公告)日：2014-12-23

申请号：US14237366

申请日：2012-11-16

Applicant: Klaus Nyfors ,  Jari Aarila ,  Jari Hatonen ,  Henrik Andtsjo ,  Eira Johansson ,  Mikko Lylykangas

Inventor： Klaus Nyfors ,  Jari Aarila ,  Jari Hatonen ,  Henrik Andtsjo ,  Eira Johansson ,  Mikko Lylykangas

IPC: C08F2/34 ,  C08F6/00 ,  B01J8/00 ,  B01J8/44 ,  C08F2/01 ,  B01J8/18 ,  C08F10/00 ,  C08J11/04 ,  C08F10/02 ,  C08F10/06

CPC classification number: C08F2/01 ,  B01J8/003 ,  B01J8/005 ,  B01J8/1809 ,  B01J2208/00548 ,  B01J2208/0061 ,  B01J2208/00761 ,  B01J2219/00247 ,  B01J2219/00254 ,  C08F2/34 ,  C08F10/00 ,  C08J11/04 ,  Y10S526/92 ,  C08F110/06 ,  C08F2500/12 ,  C08F210/16 ,  C08F210/08

Abstract: Process and apparatus for recovering polymer from a gas phase reactor having a distribution plate via an outlet vessel comprising at least one apparatus for the breakup of polymeric agglomerates, the apparatus further comprising a feed pipe connecting the gas phase reactor and the outlet vessel a return gas line connecting the gas phase reactor and the outlet vessel, means for varying the flow rate through the return gas line from the outlet vessel to the gas phase reactor, and means for varying the outlet rate of polymer product from the outlet vessel.

Abstract translation: 用于从具有分布板的气相反应器中回收聚合物的方法和装置，所述反应器具有经由出口容器的出口容器，所述出口容器包括用于分解聚合物附聚物的至少一种装置，该装置还包括将气相反应器和出口容器连接的回流气体 连接气相反应器和出口容器的管线，用于改变通过从出口容器到气相反应器的回气管线的流速的装置，以及用于改变聚合物产物从出口容器的出口速率的装置。

公开(公告)号：US20140171611A1

公开(公告)日：2014-06-19

申请号：US14237366

申请日：2012-11-16

Applicant: Klaus Nyfors ,  Jari Aarila ,  Jari Hatonen ,  Henrik Andtsjo ,  Eira Johansson ,  Mikko Lylykangas

Inventor： Klaus Nyfors ,  Jari Aarila ,  Jari Hatonen ,  Henrik Andtsjo ,  Eira Johansson ,  Mikko Lylykangas

IPC: B01J8/00 ,  C08F2/01

CPC classification number: C08F2/01 ,  B01J8/003 ,  B01J8/005 ,  B01J8/1809 ,  B01J2208/00548 ,  B01J2208/0061 ,  B01J2208/00761 ,  B01J2219/00247 ,  B01J2219/00254 ,  C08F2/34 ,  C08F10/00 ,  C08J11/04 ,  Y10S526/92 ,  C08F110/06 ,  C08F2500/12 ,  C08F210/16 ,  C08F210/08

Abstract: Process and apparatus for recovering polymer from a a gas phase reactor having a distribution plate via an outlet vessel comprising at least one apparatus for the breakup of polymeric agglomerates, the apparatus further comprising a feed pipe connecting the gas phase reactor and the outlet vessel a return gas line connecting the gas phase reactor and the outlet vessel, means for varying the flow rate through the return gas line from the outlet vessel to the gas phase reactor, and means for varying the outlet rate of polymer product from the outlet vessel.

Abstract translation: 用于从具有分布板的气相反应器中回收聚合物的方法和装置，所述气相反应器具有经由出口容器的出口容器，所述出口容器包括至少一种用于分解聚合物附聚物的装置，该装置还包括将气相反应器和出口容器连接的回流气体 连接气相反应器和出口容器的管线，用于改变通过从出口容器到气相反应器的回气管线的流速的装置，以及用于改变聚合物产物从出口容器的出口速率的装置。

公开(公告)号：US20140042010A1

公开(公告)日：2014-02-13

申请号：US13884623

申请日：2011-11-11

Applicant: Mikko Lylykangas ,  Jukka Räsänen ,  Klaus Nyfors ,  Pekka Malinen

Inventor： Mikko Lylykangas ,  Jukka Räsänen ,  Klaus Nyfors ,  Pekka Malinen

IPC: B01D1/22

CPC classification number: B01D1/22 ,  B01D1/222 ,  B01D3/14 ,  B01D3/28 ,  C01G1/06 ,  C01G23/022 ,  C01G23/024 ,  C01P2006/80 ,  C22B34/1231 ,  Y02P10/23

Abstract: The present invention provides a process for recovering transition metal tetrahalides from a waste stream coming from a catalyst manufacturing process by (a) establishing a mixed stream comprising transition metal tetrahalide and transition metal alkoxyhalides; (b) forming a falling liquid film from the mixed stream of step (a) at a temperature of from 25 to 85° C. and an absolute pressure of from 0.05 to 0.6 bar; and (c) establishing from the film of step (b) a first vapour stream containing from 90 to 100% of recoverable components and a second liquid stream containing about 10 to 80% of titanium haloalkoxides.

Abstract translation: 本发明提供从（a）建立包含过渡金属四卤化物和过渡金属烷氧基卤化物的混合物流，从催化剂制造方法的废料流中回收过渡金属四卤化物的方法; （b）在步骤（a）的混合物流中，在25至85℃的温度和绝对压力为0.05至0.6巴的条件下形成降液体膜; 和（c）从步骤（b）的膜确定含有90至100％可回收组分的第一蒸气流和含有约10至80％钛卤代烷氧化物的第二液流。

公开(公告)号：US07851567B2

公开(公告)日：2010-12-14

申请号：US12065101

申请日：2006-08-08

Applicant: Henrik Andtsjoe ,  Michiel Bergstra ,  Ralf Karlsson ,  Klaus Nyfors ,  Urban Thorngren

Inventor： Henrik Andtsjoe ,  Michiel Bergstra ,  Ralf Karlsson ,  Klaus Nyfors ,  Urban Thorngren

IPC: C08F2/00 ,  C08F110/02

CPC classification number: C08F210/16 ,  C08F2/34 ,  C08F2/001 ,  C08F2/14 ,  C08F210/08 ,  C08F2500/12 ,  C08F2500/03 ,  C08F2500/02 ,  C08F2500/01

Abstract: The present invention relates to a process for the preparation of multimodal ethylene homo- or copolymers in at least two stages, the process comprising preparation of a first ethylene homo- or copolymer fraction in a loop reactor in slurry phase, preparation of a second ethylene homo- or copolymer fraction in a gas phase reactor, by using a catalyst not containing an inorganic oxide support, and operating the gas phase reactor in such conditions that at least part of the gas is recycled, and that at least a part of the recycled gas is condensed and the (partially) condensed gas is re-introduced into the gas phase reactor.

Abstract translation: 本发明涉及在至少两个阶段制备多峰乙烯均聚物或共聚物的方法，该方法包括在淤浆相中的环管反应器中制备第一乙烯均聚物或共聚物部分，制备第二乙烯均聚物 - 或气相反应器中的共聚物部分，通过使用不含无机氧化物载体的催化剂，并且在气态反应器中操作至少部分气体被再循环的条件，并且至少部分循环气体 被冷凝，并将（部分）冷凝的气体重新引入气相反应器。

公开(公告)号：US10369491B2

公开(公告)日：2019-08-06

申请号：US13884623

申请日：2011-11-11

Applicant: Mikko Lylykangas ,  Jukka Räsänen ,  Klaus Nyfors ,  Pekka Malinen

Inventor： Mikko Lylykangas ,  Jukka Räsänen ,  Klaus Nyfors ,  Pekka Malinen

IPC: B01D1/22 ,  G01G23/02 ,  B01D3/14 ,  B01D3/28 ,  C01G23/02 ,  C01G1/06 ,  C22B34/12

Abstract: The present invention provides a process for recovering transition metal tetrahalides from a waste stream coming from a catalyst manufacturing process by (a) establishing a mixed stream comprising transition metal tetrahalide and transition metal alkoxyhalides; (b) forming a falling liquid film from the mixed stream of step (a) at a temperature of from 25 to 85° C. and an absolute pressure of from 0.05 to 0.6 bar; and (c) establishing from the film of step (b) a first vapor stream containing from 90 to 100% of recoverable components and a second liquid stream containing about 10 to 80% of titanium haloalkoxides.

公开(公告)号：US09192905B2

公开(公告)日：2015-11-24

申请号：US14002516

申请日：2012-03-02

Applicant: Erik Eriksson ,  Michiel Bergstra ,  Klaus Nyfors ,  Günter Weickert

Inventor： Erik Eriksson ,  Michiel Bergstra ,  Klaus Nyfors ,  Günter Weickert

IPC: C08F2/01 ,  C08F2/34 ,  B01J8/24 ,  B01J8/38 ,  B01J8/18 ,  B01J19/24 ,  C08F10/00 ,  C08F10/02 ,  C08F210/08 ,  C08F110/06

CPC classification number: B01J8/388 ,  B01J8/1827 ,  B01J8/1872 ,  B01J19/2465 ,  B01J2208/00274 ,  B01J2219/0004 ,  B01J2219/00254 ,  C08F10/00 ,  C08F110/06 ,  C08F2500/12 ,  C08F2/34 ,  C08F2/01

Abstract: The invention relates to a reactor assembly for the production of polymers including a fluidized bed reactor (1) comprising a bottom zone (5), a middle zone (6) and an upper zone (7), an inlet (8) for the fluidization gas located in the bottom zone (5), an outlet (9) for the fluidization gas located in the upper zone (7); the outlet (9) for the fluidization gas being coupled with the fluidized bed reactor (1) via inlet (8); the equivalent cross-sectional diameter of the bottom zone (5) being monotonically increasing with respect to the flow direction of the fluidization gas through the fluidized bed reactor; the middle zone (6) having an essentially constant equivalent cross-sectional diameter with respect to the flow direction of the fluidization gas through the fluidized bed reactor; the equivalent cross-sectional diameter of the upper zone (7) being monotonically decreasing with respect to the flow direction of the fluidization gas through the fluidized bed reactor; wherein that the ratio of the height of the fluidized bed reactor to the equivalent cross-sectional diameter of the middle zone of the fluidized bed reactor is from 2 to 10; and wherein there is an unobstructed passageway in the direction of flow of the fluidization gas through the fluidized bed reactor from the bottom zone (5) to the upper zone (7).

Abstract translation: 本发明涉及一种用于生产聚合物的反应器组件，包括流化床反应器（1），其包括底部区域（5），中间区域（6）和上部区域（7），用于流化的入口（8） 位于底部区域（5）中的气体，位于上部区域（7）中的用于流化气体的出口（9）; 用于流化气体的出口（9）通过入口（8）与流化床反应器（1）联接; 底部区域（5）的等效横截面直径相对于通过流化床反应器的流化气体的流动方向单调增加; 所述中间区域（6）具有相对于通过所述流化床反应器的流化气体的流动方向具有基本恒定的等效横截面直径; 上部区域（7）的等效横截面直径相对于通过流化床反应器的流化气体的流动方向单调减小; 其中流化床反应器的高度与流化床反应器的中间区域的等效横截面直径之比为2至10; 并且其中在从底部区域（5）到上部区域（7）的流化床反应器的流化气体的流动方向上存在无障碍通道。

公开(公告)号：US20140058051A1

公开(公告)日：2014-02-27

申请号：US14002426

申请日：2012-03-02

Applicant: Günter Weickert ,  Erik Eriksson ,  Michiel Bergstra ,  Klaus Nyfors

Inventor： Günter Weickert ,  Erik Eriksson ,  Michiel Bergstra ,  Klaus Nyfors

IPC: B01J8/18 ,  C08F110/06 ,  C08F210/16

CPC classification number: B01J8/1872 ,  B01J8/1827 ,  B01J8/388 ,  B01J19/2465 ,  B01J2208/00274 ,  B01J2219/0004 ,  B01J2219/00254 ,  B01J2219/1947 ,  C08F110/06 ,  C08F210/16

Abstract: Reactor assembly for the production of polymers including a fluidized bed reactor (1) comprising a bottom zone (5), a middle zone (6) and an upper zone (7), an inlet (8) for the fluidization gas located in the bottom zone (5), an outlet (9) for the fluidization gas located in the upper zone (7); the outlet (9) for the fluidization gas being coupled with the fluidized bed reactor (1) via inlet (8) via a gas circulation line; means for separation of solids from gas (2) being connected to said gas circulation line; the equivalent cross-sectional diameter of the upper zone (7) being monotonically decreasing with respect to the flow direction of the fluidization gas through the fluidized bed reactor; the middle zone (6) having an essentially constant equivalent cross-sectional diameter with respect to the flow direction of the fluidization gas through the fluidized bed reactor; the equivalent cross-sectional diameter of the bottom zone (5) being monotonically increasing with respect to the flow direction of the fluidization gas through the fluidized bed reactor; characterized in that the ratio of the height of the fluidized bed reactor to the equivalent cross-sectional diameter of the middle zone of the fluidized bed reactor is from 2 to 10; and whereby said upper zone (7) is directly connected to said middle zone (6).

Abstract translation: 用于生产包括流化床反应器（1）的聚合物的反应器组件包括底部区域（5），中间区域（6）和上部区域（7），用于位于底部的流化气体的入口（8） 区域（5），用于位于上部区域（7）中的流化气体的出口（9）; 用于流化气体的出口（9）通过气体循环管线通过入口（8）与流化床反应器（1）相连; 用于从与所述气体循环管线连接的气体（2）分离固体的装置; 上部区域（7）的等效横截面直径相对于通过流化床反应器的流化气体的流动方向单调减小; 所述中间区域（6）具有相对于通过所述流化床反应器的流化气体的流动方向具有基本恒定的等效横截面直径; 底部区域（5）的等效横截面直径相对于通过流化床反应器的流化气体的流动方向单调增加; 其特征在于，流化床反应器的高度与流化床反应器的中间区域的等效横截面直径之比为2至10; 并且由此所述上部区域（7）直接连接到所述中间区域（6）。

公开(公告)号：US20050152816A1

公开(公告)日：2005-07-14

申请号：US11075921

申请日：2005-03-10

Applicant: Jouni Kivela ,  Klaus Nyfors

Inventor： Jouni Kivela ,  Klaus Nyfors

IPC: C08F2/01 ,  B01J8/00 ,  B01J8/24 ,  C08F2/34 ,  C08F10/00 ,  C08F32/00 ,  C08F36/00 ,  B32B5/02 ,  C08F2/00

CPC classification number: B01J8/24 ,  B01J8/003 ,  B01J8/005 ,  B01J2208/00681 ,  B01J2208/00761 ,  B01J2219/00247 ,  C08F2/34 ,  C08F10/00

Abstract: A method and an apparatus of discharging polymer from a continuously operated gas phase reactor, wherein at least one monomer is polymerized in a bed containing active catalyst formed by catalyst and polymer particles suspended in a fluid, the bed defining a fluidized bed level in said reactor. The invention includes continuously withdrawing polymer powder from the reactor; and adjusting the discharge rate of the polymer powder so as to maintain a constant bed level during polymerization. By means of the invention the discharge of the polymer can be made truly continuous without any disturbance of the polymerization. The rate of withdrawn polymer can be flexibly adjusted depending on the progress of the polymerization and it can also easily be scaled up if the capacity of the reactor is increased.

Abstract translation: 一种从连续操作的气相反应器中排出聚合物的方法和装置，其中至少一种单体在包含由催化剂形成的活性催化剂和悬浮在流体中的聚合物颗粒的床中聚合，所述床在所述反应器中限定流化床水平 。 本发明包括从反应器中连续取出聚合物粉末; 并调节聚合物粉末的排出速率，以便在聚合过程中保持恒定的床层。 通过本发明，可以使聚合物的排放真正连续，而不会导致聚合紊乱。 退出的聚合物的速率可以根据聚合的进程灵活地调节，并且如果反应器的容量增加，也可以容易地放大。