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1.发明申请DETERMINATION OF THE HYDRODYNAMIC RADII AND/OR CONTENT OF CONSTITUENTS OF A MIXTURE BY ANALYSIS OF THE TAYLOR DISPERSION OF THE MIXTURE IN A CAPILLARY TUBE 审中-公开通过分析毛细管中混合物的水分散度来确定混合物的水动力RADII和/或内容物公开(公告)号：US20110264380A1
公开(公告)日：2011-10-27
申请号：US13055350
申请日：2009-03-13
CPC分类号： B01J19/0053 , B01J2208/00955 , G01N15/1459 , G01N33/442 , G01N2015/0092 , G01N2030/001
摘要： A method for analysing a mixture M comprising (i) a first monodisperse species, and (ii) a second species having a response coefficient which is distinct from the response coefficient of the first species (i) on at least one detection device, said method comprising the following steps: (A) the mixture M is injected at the inlet of a capillary tube and forced to be transported in said tube by the flow of a carrier liquid induced by a positive hydrodynamic and/or hydrostatic pressure between the inlet and the outlet of the capillary, whereby a phenomenon of Taylor dispersion of the species of the mixture M occurs in the tube; (B) by using a detection device able to detect simultaneously both species (i) and (ii) and placed in the region of the outlet of the capillary tube, a signal reflecting the Taylor dispersion obtained in step (A) is measured; (C) the signal obtained in step (B) is analysed, so as to determine specific contributions of species (i) and (ii) and thereby establishing at least one of the followings: —the content of species (i) and/or (ii) in the mixture M; and/or, —the mean hydrodynamic radius of the species (ii) or the hydrodynamic radius of species (i).
摘要翻译： 一种用于分析混合物M的方法，包括（i）第一单分散物质和（ii）具有与至少一种检测装置上的第一物质（i）的响应系数不同的响应系数的第二物质，所述方法 包括以下步骤：（A）混合物M在毛细管的入口处被注入，并且被迫通过由正的流体动力学和/或静水压力引起的载体流在所述管内被输送到入口和 毛细管的出口，由此在管中发生混合物M的种类的泰勒分散现象; （B）通过使用能够同时检测物质（i）和（ii）并且放置在毛细管的出口的区域中的检测装置，测量反映步骤（A）中获得的泰勒色散的信号; （C）分析步骤（B）中获得的信号，以便确定物种（i）和（ii）的具体贡献，从而建立以下至少一个： - 物种（i）和/或 （ii）在混合物M中; 和/或 - 物种（ii）的平均流体动力学半径或物质（i）的流体动力学半径。
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2.发明申请NOVEL DICARBANIONIC INITIATOR, A PROCESS FOR THE PREPARATION AND USE THEREOF 有权新西兰DICARBANIONIC INITIATOR，其制备和使用的过程公开(公告)号：US20070197723A1
公开(公告)日：2007-08-23
申请号：US11539222
申请日：2006-10-06
IPC分类号： C08L53/00 , C08F297/00
CPC分类号： C07F1/02
摘要： The present invention provides a novel dicarbanionic initiator of formula (I). The present process further provides a process for the preparation of dicarbanionic initiator of formula (I) comprising reacting 1-bromo-4-(4′-bromophenoxy)-2-pentadecyl benzene of formula (II) with alkyllithium compound for an effecting halogen-lithium exchange reaction of 1-bromo-4-(4′-bromophenoxy)-2-pentadecyl benzene with sec-butyllithium in the presence of a non polar solvent, at a temperature in the range of 0 to 250 C and its use as an initiator for the synthesis of telechelic polydienes and polystyrenes and SBS or SIS triblock copolymers.
摘要翻译： 本发明提供了新的式（I）二碳酸酯引发剂。 本发明进一步提供了制备式（I）的二羧酸引发剂的方法，包括使式（II）的1-溴-4-（4'-溴苯氧基）-2-十五烷基苯与烷基锂化合物反应， 在非极性溶剂的存在下，在0至25℃的温度下，1-溴-4-（4'-溴苯氧基）-2-十五烷基苯与仲丁基锂的锂交换反应， 并且其用作合成远电离子聚二烯和聚苯乙烯和SBS或SIS三嵌段共聚物的引发剂。
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公开(公告)号：US20130012652A1
公开(公告)日：2013-01-10
申请号：US13581595
申请日：2011-03-15
申请人： José Carlos Araujo Da Silva , Jean-Michel Favrot , Rachid Matmour , Anne Frédérique Salit , Nicolas Seeboth
发明人： José Carlos Araujo Da Silva , Jean-Michel Favrot , Rachid Matmour , Anne Frédérique Salit , Nicolas Seeboth
摘要： The invention relates to a tire comprising at least one rubber composition based on at least one diene elastomer, one reinforcing filler, one chemical crosslinking agent and one modifying agent, chosen from the compounds of following formula (I): where R denotes a unit comprising at least one reactive group, R1 denotes hydrogen, R2 denotes an alkylene radical comprising from 2 to 8 carbon atoms and optionally one or more heteroatoms chosen from S, N, O or Si, A denotes an oxygen or sulphur atom or an ═NH group, preferably an oxygen atom.
摘要翻译： 本发明涉及一种轮胎，其包含至少一种基于至少一种二烯弹性体的橡胶组合物，一种增强填料，一种化学交联剂和一种改性剂，其选自下式（I）的化合物：其中R表示包含 至少一个反应性基团，R 1表示氢，R 2表示包含2至8个碳原子的亚烷基和任选的一个或多个选自S，N，O或Si的杂原子，A表示氧或硫原子或= NH基团 ，优选氧原子。
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公开(公告)号：US09340626B2
公开(公告)日：2016-05-17
申请号：US13581595
申请日：2011-03-15
申请人： José Carlos Araujo Da Silva , Jean-Michel Favrot , Rachid Matmour , Anne Frédérique Salit , Nicolas Seeboth
发明人： José Carlos Araujo Da Silva , Jean-Michel Favrot , Rachid Matmour , Anne Frédérique Salit , Nicolas Seeboth
摘要： The invention relates to a tire comprising at least one rubber composition based on at least one diene elastomer, one reinforcing filler, one chemical crosslinking agent and one modifying agent, chosen from the compounds of following formula (I): where R denotes a unit comprising at least one reactive group, R1 denotes hydrogen, R2 denotes an alkylene radical comprising from 2 to 8 carbon atoms and optionally one or more heteroatoms chosen from S, N, O or Si, A denotes an oxygen or sulphur atom or an ═NH group, preferably an oxygen atom.
摘要翻译： 本发明涉及一种轮胎，其包含至少一种基于至少一种二烯弹性体的橡胶组合物，一种增强填料，一种化学交联剂和一种改性剂，其选自下式（I）的化合物：其中R表示包含 至少一个反应性基团，R 1表示氢，R 2表示包含2至8个碳原子的亚烷基和任选的一个或多个选自S，N，O或Si的杂原子，A表示氧或硫原子或= NH基团 ，优选氧原子。
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公开(公告)号：US07709687B2
公开(公告)日：2010-05-04
申请号：US11539222
申请日：2006-10-06
IPC分类号： C07C43/205 , C07F1/02 , C08F297/04 , C07C41/09
CPC分类号： C07F1/02
摘要： The present invention provides a novel dicarbanionic initiator of formula (I). The present process further provides a process for the preparation of dicarbanionic initiator of formula (I) comprising reacting 1-bromo-4-(4′-bromophenoxy)-2-pentadecyl benzene of formula (II) with alkyllithium compound for an effecting halogen-lithium exchange reaction of 1-bromo-4-(4′-bromophenoxy)-2-pentadecyl benzene with sec-butyllithium in the presence of a non polar solvent, at a temperature in the range of 0 to 25° C. and its use as an initiator for the synthesis of telechelic polydienes and polystyrenes and SBS or SIS triblock copolymers.
摘要翻译： 本发明提供了新的式（I）二碳酸酯引发剂。 本发明进一步提供了制备式（I）的二羧酸引发剂的方法，其包括使式（II）的1-溴-4-（4'-溴苯氧基）-2-十五烷基苯与烷基锂化合物反应， 在非极性溶剂的存在下，在0至25℃的温度范围内，1-溴-4-（4'-溴苯氧基）-2-十五烷基苯与仲丁基锂的锂交换反应及其用途 作为合成远电离子聚二烯和聚苯乙烯和SBS或SIS三嵌段共聚物的引发剂。
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