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    Method to manufacture composite polymer electrolyte membranes coated with inorganic thin films for fuel cells
    1.
    发明申请
    Method to manufacture composite polymer electrolyte membranes coated with inorganic thin films for fuel cells 审中-公开
    制造涂覆有燃料电池无机薄膜的复合高分子电解质膜的方法

    公开(公告)号：US20070231655A1

    公开(公告)日：2007-10-04

    申请号：US11796469

    申请日：2007-04-27

    申请人： Heung-Yong Ha ,  Soon Jong Kwak ,  Daejin Kim ,  Juno Shim ,  In-Hwan Oh ,  Seong-Ahn Hong ,  Tae-Hoon Lim ,  Suk-Woo Nam

    发明人： Heung-Yong Ha ,  Soon Jong Kwak ,  Daejin Kim ,  Juno Shim ,  In-Hwan Oh ,  Seong-Ahn Hong ,  Tae-Hoon Lim ,  Suk-Woo Nam

    IPC分类号： H01M8/10

    CPC分类号： C08J5/2287 ,  C08J2327/18 ,  H01M4/881 ,  H01M8/04197 ,  H01M8/1023 ,  H01M8/1025 ,  H01M8/103 ,  H01M8/1039 ,  H01M8/1055 ,  H01M8/1069 ,  H01M2300/0094 ,  Y02E60/523 ,  Y02P70/56

    摘要： The present invention relates to a method for manufacturing composite polymer electrolyte membranes coated with inorganic thin films for fuel cells using a plasma enhanced chemical vapor deposition (PECVD) method or a reactive sputtering method, so as to reduce the crossover of methanol through polymer electrolyte membranes for fuel cells and enhance the performance of the fuel cells. The manufacturing method of composite polymer electrolyte membranes coated with inorganic thin films for fuel cells according to the present invention is characterized to obtain composite membranes by coating the surface of commercial composite polymer electrolyte membranes for fuel cells with inorganic thin films using a PECVD method or a reactive sputtering method. The inorganic materials to form the inorganic thin films are chosen one or more from the group comprising silicon oxide (SiO2), titanium oxide (TiO2), zirconium oxide (ZrO2), zirconium phosphate (Zr(HPO4)2), zeolite, silicalite, and aluminum oxide (Al2O3). The present invention, by coating the polymer electrolyte membranes for fuel cells with inorganic thin films via a PECVD method or a reactive sputtering method, reduces the methanol crossover sizably without seriously reducing the ionic conductivity of polymer electrolyte membranes, thereby, when applied to fuel cells, realizes a high performance of fuel cells.

    摘要翻译： 本发明涉及使用等离子体增强化学气相沉积（PECVD）法或反应溅射法制造涂覆有燃料电池的无机薄膜的复合聚合物电解质膜的方法，从而减少甲醇通过聚合物电解质膜的交叉 用于燃料电池并增强燃料电池的性能。 根据本发明的用于燃料电池的无机薄膜的复合高分子电解质膜的制造方法的特征在于，通过使用PECVD法或无机薄膜将无机薄膜涂覆用于燃料电池的市售复合高分子电解质膜的表面，来获得复合膜 反应溅射法。 形成无机薄膜的无机材料选自一种或多种，​​其中包括氧化硅（SiO 2），氧化钛（TiO 2），氧化锆（ZrO 2） 磷酸锆（Zr（HPO 4）2）），沸石，硅沸石和氧化铝（Al 2 O 3） SUB> O 3 3）。 本发明通过PECVD法或反应溅射法通过用无机薄膜涂覆燃料电池用聚合物电解质膜，可以在不严重降低聚合物电解质膜的离子电导率的情况下，相应地降低甲醇交换，从而当应用于燃料电池 实现燃料电池的高性能化。

    COMPOSITION COMPRISING A MONOMER FOR POLYMERIZING BRANCH-TYPE SILSESQUIOXANE POLYMER, BRANCH-TYPE SILSESQUIOXANE POLYMER SYNTHESIZED FROM THE SAME AND A METHOD FOR SYNTHESIZING THE SAME
    5.
    发明申请
    COMPOSITION COMPRISING A MONOMER FOR POLYMERIZING BRANCH-TYPE SILSESQUIOXANE POLYMER, BRANCH-TYPE SILSESQUIOXANE POLYMER SYNTHESIZED FROM THE SAME AND A METHOD FOR SYNTHESIZING THE SAME 有权
    用于聚合分支型硅烷聚合物的单体的组合物，从其合成的分支型硅烷基聚合物及其合成方法

    公开(公告)号：US20130165617A1

    公开(公告)日：2013-06-27

    申请号：US13820298

    申请日：2011-09-16

    申请人： Seung Sang Hwang ,  Kyung Youl Baek ,  He Seung Lee ,  Soon Man Hong ,  Soon Jong Kwak ,  Chong Min Koo

    发明人： Seung Sang Hwang ,  Kyung Youl Baek ,  He Seung Lee ,  Soon Man Hong ,  Soon Jong Kwak ,  Chong Min Koo

    IPC分类号： C08G77/04

    CPC分类号： C08G77/04 ,  C07F7/21 ,  C08G77/045 ,  C08G77/16 ,  C08L83/04

    摘要： A monomer composition for polymerizing a branch-type silsesquioxane polymer is disclosed. The monomer composition includes hydroxy-substituted cyclic siloxane in a solvent, and the hydroxy-substituted cyclic siloxane includes stereoisomers of cyclic siloxane of cis, trans, random and twist structures at controlled ratios. Also disclosed are a branch-type silsesquioxane polymer synthesized by polymerizing the monomer composition for polymerizing a branch-type silsesquioxane polymer, and a method for synthesizing the same. In accordance with the disclosure, the isomers can be isolated stably at desired ratios. The isolated isomers may be polymerized into polymers of various types. Since the polymers exhibit low dielectric property, they may be utilized as low dielectric materials.

    摘要翻译： 公开了用于聚合支化型倍半硅氧烷聚合物的单体组合物。 单体组合物在溶剂中包括羟基取代的环状硅氧烷，羟基取代的环状硅氧烷包括顺式，反式，无规和扭曲结构的环状硅氧烷的立体异构体，其受控比例。 还公开了通过使用于聚合支化型倍半硅氧烷聚合物的单体组合物聚合而合成的分支型倍半硅氧烷聚合物及其合成方法。 根据本公开内容，可以以期望的比例稳定地分离异构体。 分离的异构体可以聚合成各种类型的聚合物。 由于聚合物表现出低介电性能，因此它们可以用作低电介质材料。

    DIELECTRIC ELASTOMER COMPOSITES AND ACTUATORS USING THE SAME
    7.
    发明申请
    DIELECTRIC ELASTOMER COMPOSITES AND ACTUATORS USING THE SAME 审中-公开
    电介质弹性体复合材料和使用它的执行器

    公开(公告)号：US20130049530A1

    公开(公告)日：2013-02-28

    申请号：US13643774

    申请日：2010-08-24

    申请人： Chong Min Koo ,  Soon Man Hong ,  Seung Sang Hwang ,  Kyung Youl Baek ,  Soon Jong Kwak ,  Myung Hee Kim ,  Bo Ri Kim ,  Hee La Kwak ,  Kyung Ho Min ,  Youn Duk Park

    发明人： Chong Min Koo ,  Soon Man Hong ,  Seung Sang Hwang ,  Kyung Youl Baek ,  Soon Jong Kwak ,  Myung Hee Kim ,  Bo Ri Kim ,  Hee La Kwak ,  Kyung Ho Min ,  Youn Duk Park

    IPC分类号： H02N11/00 ,  B05D5/12 ,  B82Y99/00

    CPC分类号： H01L41/193 ,  H01L41/0986 ,  H01L41/45

    摘要： The present invention relates to an actuator which is one of the energy conversion devices, and is characterized by improving the ability to convert electrical energy into mechanical energy by way of using a dielectric elastomer composite comprising a filler with an efficient dispersibility. In case of using a conventional resilient dielectric layer, there was a problem in that the operating voltage is high, while advantageously exhibiting a fast response and a high strain. The present invention can provide dielectric elastomer composite actuators that show excellent electromechanical conversion properties, by adding a dispersing agent such as a pyrene derivative or a polymeric compound having an amine end group when preparing the composite wherein carbon-based conductive fillers such as carbon blacks, single-walled carbon nanotubes (SWCNTs), double-walled carbon nanotubes (DWCNTs), multi-walled carbon nanotubes (MWCNTs) and graphenes, or high dielectric fillers such as copper phthalo-cyanine (CuPc), MOFs (metal organic frameworks) and barium titanate (BaTiO3) are comprised in a thermoplastic resilient dielectric layer to enhance the dispersibility of the fillers.

    摘要翻译： 本发明涉及作为能量转换装置之一的致动器，其特征在于，通过使用包含具有高分散性的填料的介电弹性体复合材料，提高将电能转换成机械能的能力。 在使用传统的弹性介电层的情况下，存在操作电压高的问题，同时有利地表现出快速响应和高应变。 通过在制备复合材料时，通过添加分散剂如芘衍生物或具有胺端基的聚合化合物，本发明可以提供显示出优异机电转化性能的介电弹性体复合致动器，其中碳基导电填料如炭黑， 单壁碳纳米管（SWCNT），双壁碳纳米管（DWCNT），多壁碳纳米管（MWCNT）和石墨烯，或高介电填料如铜酞菁（CuPc），MOFs（金属有机骨架）和 钛酸钡（BaTiO 3）包含在热塑性弹性介电层中以增强填料的分散性。