摘要:
A monomer composition for polymerizing a branch-type silsesquioxane polymer is disclosed. The monomer composition includes hydroxy-substituted cyclic siloxane in a solvent, and the hydroxy-substituted cyclic siloxane includes stereoisomers of cyclic siloxane of cis, trans, random and twist structures at controlled ratios. Also disclosed are a branch-type silsesquioxane polymer synthesized by polymerizing the monomer composition for polymerizing a branch-type silsesquioxane polymer, and a method for synthesizing the same. In accordance with the disclosure, the isomers can be isolated stably at desired ratios. The isolated isomers may be polymerized into polymers of various types. Since the polymers exhibit low dielectric property, they may be utilized as low dielectric materials.
摘要:
A monomer composition for polymerizing a branch-type silsesquioxane polymer is disclosed. The monomer composition includes hydroxy-substituted cyclic siloxane in a solvent, and the hydroxy-substituted cyclic siloxane includes stereoisomers of cyclic siloxane of cis, trans, random and twist structures at controlled ratios. Also disclosed are a branch-type silsesquioxane polymer synthesized by polymerizing the monomer composition for polymerizing a branch-type silsesquioxane polymer, and a method for synthesizing the same. In accordance with the disclosure, the isomers can be isolated stably at desired ratios. The isolated isomers may be polymerized into polymers of various types. Since the polymers exhibit low dielectric property, they may be utilized as low dielectric materials.
摘要:
Disclosed are a method for polymerizing polysilsesquioxane from a trialkoxysiloxane monomer, including: preparing an aqueous organic solution including a trialkoxysiloxane monomer, an organic solvent, water and a catalyst; and selectively preparing a polysilsesquioxane with a cage structure or a polysilsesquioxane with a ladder structure by adjusting the amount of the organic solvent or water in the aqueous organic solution, and a polysilsesquioxane with a cage structure or a polysilsesquioxane with a ladder structure prepared therefrom.
摘要:
The present invention relates to an actuator which is one of the energy conversion devices, and is characterized by improving the ability to convert electrical energy into mechanical energy by way of using a dielectric elastomer composite comprising a filler with an efficient dispersibility. In case of using a conventional resilient dielectric layer, there was a problem in that the operating voltage is high, while advantageously exhibiting a fast response and a high strain. The present invention can provide dielectric elastomer composite actuators that show excellent electromechanical conversion properties, by adding a dispersing agent such as a pyrene derivative or a polymeric compound having an amine end group when preparing the composite wherein carbon-based conductive fillers such as carbon blacks, single-walled carbon nanotubes (SWCNTs), double-walled carbon nanotubes (DWCNTs), multi-walled carbon nanotubes (MWCNTs) and graphenes, or high dielectric fillers such as copper phthalo-cyanine (CuPc), MOFs (metal organic frameworks) and barium titanate (BaTiO3) are comprised in a thermoplastic resilient dielectric layer to enhance the dispersibility of the fillers.
摘要:
The present invention relates to transparent antistatic films using graphene, and methods for preparing the same. The films include conductive particles comprising a single-layer or multi-layer graphene, and a binder. The films are prepared by dispersing graphene in a solvent to obtain a graphene dispersion; dissolving a curable binder to a solvent to obtain a binder solution; mixing the graphene dispersion, the binder solution and optionally an additive to obtain a coating solution; applying the coating solution onto a substrate and drying the solution to form a coated film; and curing the coated film. According to the present invention, transparent or semitransparent antistatic films having excellent permeability, abrasion resistance, scratch resistance, chemical stability and dimensional stability can be prepared. The films also have superior adhesion to substrates and applicability, and thus may be advantageously applied to rigid or flexible substrates.
摘要:
Disclosed are a method for polymerizing polysilsesquioxane from a trialkoxysiloxane monomer, including: preparing an aqueous organic solution including a trialkoxysiloxane monomer, an organic solvent, water and a catalyst; and selectively preparing a polysilsesquioxane with a cage structure or a polysilsesquioxane with a ladder structure by adjusting the amount of the organic solvent or water in the aqueous organic solution, and a polysilsesquioxane with a cage structure or a polysilsesquioxane with a ladder structure prepared therefrom.
摘要:
Disclosed is a light-emitting material including a polysilsesquioxane having a ladder structure with photoactive groups bonded to a siloxane backbone. In addition to superior heat resistance and mechanical property, the light-emitting material provides improved cotability and film property when prepared into a thin film. Further, it provides higher luminous efficiency than the existing organic-based light-emitting material.
摘要:
A low-dielectric constant thin film prepared from a silsesquioxane polymer matrix as a precursor and a method for preparing the same which comprises preparing silsesquioxane sol by adding a stereoisomer of a multi reactive cyclosiloxane to an alkoxysilane are provided. The low-dielectric-constant thin film retains a stable film state even at a curing temperature of −500° C. without being decomposed, a very uniform surface property with a low surface modulus, and a superior coatability as to be coatable smoothly with no crack even with a thickness of 500 nm or larger.
摘要:
Provided is a method for controlling a self-assembled structure of a poly(3-hexylthiophene)-based block copolymer, including: providing a polymer composition containing a block copolymer having a π-conjugated poly(3-hexylthiophene) polymer and a non-conjugated polymer introduced thereto, and a solvent; and coating the polymer composition onto a substrate.According to the method disclosed herein, it is possible to control a self-assembled structure of a poly(3-hexylthiophene)-based block copolymer merely by a relatively simple process including coating the poly(3-hexylthiophene)-based block copolymer onto a substrate with a selected solvent. In this manner, it is possible to control the alignment of conductive domains in the block copolymer so that it is suitable for various organic electronic devices. In addition, the self-assembled polymer structure having various self-assembled structures controlled selectively by the method may be applied to organic electronic devices for designing and developing high-quality devices.
摘要:
Highly regular and well-defined structured polyorganosilsesquioxane polymer with superior heat resistance, combustion resistance and flexibility, wherein same or different kinds of substituents are bonded alternately, and the preparation method thereof. The polyorganosilsesquioxane prepared according to the present invention has a small molecular weight distribution and a high molecular weight, and is soluble in organic solvents because a three-dimensional network structure is not formed during the preparative condensation polymerization. Polyalkylaromaticsilsesquioxane obtained from the preparing method of the present invention is a useful heat-resistant material. It can be used as a heat-resistant coating agent, a protective coating agent of optical fiber, a coating material for resistor, heat-resistant paint, an adhesive and a releasing agent for precise molding. Also, it can be used for the semiconductor protective layer, interlayer dielectrics for semiconductor integration (e.g. LSI), new heat-resistant photoresist, and functional photonics materials.