Photocurable resin composition and optical component
    1.
    发明申请
    Photocurable resin composition and optical component 审中-公开
    光固化树脂组合物和光学组件

    公开(公告)号:US20050256219A1

    公开(公告)日:2005-11-17

    申请号:US10507482

    申请日:2003-03-06

    摘要: The invention relates to a photocurable resin composition comprising: (A) (A1) a (meth)acrylate having a structure shown by the formula (1) or (2), or (A2) an epoxy compound having a structure shown by the formula (1) or (2); (B) a (meth)acrylate having three or more functional groups other than (A1); (C) a radical photoinitiator; (D) a compound having three or more cyclic ether linkages in the molecule other than (A2) and (E) a cationic photoinitiator; the invention also relates to optical parts made from the resins of the invention and use of the resin in other applications.

    摘要翻译: 本发明涉及一种光固化树脂组合物,其包含:(A)(A1)具有式(1)或(2)所示结构的(甲基)丙烯酸酯或(A2)具有式 (1)或(2); (B)除(A1)以外具有3个以上官能团的(甲基)丙烯酸酯; (C)自由基光引发剂; (D)在分子中具有三个或更多个环醚键的化合物(A2)和(E)阳离子光引发剂; 本发明还涉及由本发明的树脂制成的光学部件和在其它应用中使用该树脂。

    Curable liquid composition, cured film, and antistatic laminate
    5.
    发明申请
    Curable liquid composition, cured film, and antistatic laminate 审中-公开
    可固化液体组合物,固化膜和抗静电层压板

    公开(公告)号:US20070155882A1

    公开(公告)日:2007-07-05

    申请号:US10552510

    申请日:2004-04-05

    IPC分类号: C08G73/10 C08K3/22

    摘要: To provide a curable liquid composition excelling in storage stability and curability and capable of forming a coat (film) which excels in antistatic properties, hardness, scratch resistance, and transparency on the surface of various substrates, a cured film of the composition, and an antistatic laminate. A curable liquid composition comprising (A) particles including an oxide of at least one element selected from the group consisting of indium, antimony, zinc, and tin as a major component, (B) a compound having at least two polymerizable unsaturated groups in the molecule, (C) a solvent in which solubility of the component (B) is less than 10 wt %, and (D) a solvent in which solubility of the component (B) is 10 wt % or more, the components (A) and (B) being uniformly dispersed or dissolved in the composition.

    摘要翻译: 为了提供优异的储存稳定性和固化性的可固化液体组合物,并且能够形成在各种基材的表面上的抗静电性,硬度,耐刮擦性和透明性优异的涂层(膜),该组合物的固化膜和 抗静电层压板 一种可固化液体组合物,其包含(A)包含选自由铟,锑,锌和锡组成的组中的至少一种元素的氧化物的主要成分的颗粒,(B)具有至少两个可聚合不饱和基团的化合物 分子,(C)成分(B)的溶解度小于10重量%的溶剂,(D)成分(B)的溶解度为10重量%以上的成分(A) 和(B)均匀地分散或溶解在组合物中。

    Curable composition, cured product thereof, and laminated material
    6.
    发明授权
    Curable composition, cured product thereof, and laminated material 失效
    可固化组合物,其固化产物和层压材料

    公开(公告)号:US07060737B2

    公开(公告)日:2006-06-13

    申请号:US10471256

    申请日:2002-03-29

    IPC分类号: C08F290/06 B29B71/04 B35B5/16

    摘要: The invention relates to a curable resin composition, cured products thereof, and laminated materials. The curable composition comprises: (A-1) acicular oxide particles, the oxide being an oxide of at least one element selected from the group consisting of silicon, aluminum, zirconium, titanium, zinc, germanium, indium, tin, antimony, and cerium, (B) a compound having two or more polymerizable unsaturated groups, (C) a photopolymerization initiator is provided. After cure, the composition has excellent scratch resistance. In addition, it may have excellent antistatic characteristics and transparency. In a preferred embodiment the composition also comprises (A-2) particles other than the acicular particles (A-1), being oxide of at least one element selected from the group consisting of silicon, aluminum, zirconium, titanium, zinc, germanium, indium, tin, antimony, and cerium.

    摘要翻译: 本发明涉及可固化树脂组合物,其固化产物和层压材料。 可固化组合物包含:(A-1)针状氧化物颗粒,氧化物为选自硅,铝,锆,钛,锌,锗,铟,锡,锑和铈中的至少一种元素的氧化物 ,(B)具有两个以上聚合性不饱和基团的化合物,(C)光聚合引发剂。 固化后,该组合物具有优异的耐划伤性。 另外,它具有优异的抗静电特性和透明度。 在一个优选的实施方案中,组合物还包含除了针状颗粒(A-1)之外的(A-2)颗粒,其是选自硅,铝,锆,钛,锌,锗, 铟,锡,锑和铈。

    Photocurable resin composition and optical parts
    7.
    发明授权
    Photocurable resin composition and optical parts 失效
    光固化树脂组合物和光学部件

    公开(公告)号:US06710097B2

    公开(公告)日:2004-03-23

    申请号:US09998929

    申请日:2001-12-03

    IPC分类号: C08F246

    摘要: A photocurable resin composition comprising: (A) a urethane (meth)acrylate produced by reacting at least a polyether polyol with a number average molecular weight of 500 or more having an alkyleneoxy structure in the molecule, an organic polyisocyanate compound, and a (meth)acrylate containing a hydroxyl group; (B) a monofunctional (meth)acrylate shown by the following formula (1), wherein R1 represents a hydrogen atom or a methyl group, R2 represents —(CH2CH2O)p—, —(CH(CH3)CH2O)q—, or —CH2CH(OH)CH2O—, Y1, Y2, and Y3 individually represent a hydrogen atom, bromine atom, alkyl group having 1-10 carbon atoms, phenyl group, or —C(CH3)2C6H5—, and p and q represent integers from 0 to 10; and (C) a photoinitiator; its use and optical parts prepared from the photocurable resin composition.

    摘要翻译: 一种光固化性树脂组合物,其含有:(A)通过至少使分子中具有亚烷基氧基结构的数均分子量为500以上的聚醚多元醇,有机多异氰酸酯化合物和(甲基)丙烯酸酯, )丙烯酸酯;(B)由下式(1)表示的单官能(甲基)丙烯酸酯,其中R 1表示氢原子或甲基,R 2表示 - (CH 2 CH 2 O) , - (CH(CH 3)CH 2 O)q-或-CH 2 CH(OH)CH 2 O-,Y 1,Y 2和Y 3各自表示氢原子,溴原子, 10个碳原子,苯基或-C(CH 3)2 C 6 H 5 - ,p和q表示0至10的整数; 和(C)光引发剂;其用途和由光固化树脂组合物制备的光学部件。

    Curable liquid resin composition
    8.
    发明授权
    Curable liquid resin composition 有权
    可固化液体树脂组合物

    公开(公告)号:US07084187B2

    公开(公告)日:2006-08-01

    申请号:US10488472

    申请日:2002-09-26

    IPC分类号: C08J3/28

    CPC分类号: C09D4/00 C08F230/08

    摘要: To provide a radiation-sensitive curable liquid resin composition having excellent applicability and capable of producing a film excelling in hardness, scratch resistance, adhesion, transparency, and appearance of the surface of the film.A curable liquid resin composition comprising: (A) particles prepared by bonding at least one oxide of an element selected from the group consisting of silicon, aluminum, zirconium, titanium, zinc, germanium, indium, tin, antimony, and cerium to a specific organic compound which comprises a polymerizable unsaturated group and a group shown by —X—C(═Y)—NH— (wherein X is NH, O, or S, and Y is O or S), and preferably a silanol group, (B) a compound having two or more polymerizable unsaturated groups in the molecule, (C) a specific alkylene glycol organic solvent, and preferably (D) a polymerization initiator.

    摘要翻译: 本发明提供一种具有优异适用性且能够制备出优异的薄膜表面的硬度,耐擦伤性,粘附性,透明性和外观的薄膜的辐射敏感性固化性液体树脂组合物。 一种可固化液体树脂组合物,其包含:(A)通过将选自硅,铝,锆,钛,锌,锗,铟,锡,锑和铈中的至少一种元素的氧化物键合到特定的 包含可聚合不饱和基团和由-XC(-Y)-NH-(其中X是NH,O或S,Y是O或S)表示的基团的有机化合物,优选硅烷醇基,(B) 在分子中具有两个以上聚合性不饱和基团的化合物,(C)特定的亚烷基二醇有机溶剂,优选(D)聚合引发剂。

    RADIOACTIVE RAY-CURABLE RESIN COMPOSITION FOR USE IN OPTICAL MEMBER AND OPTICAL MEMBER
    9.
    发明申请
    RADIOACTIVE RAY-CURABLE RESIN COMPOSITION FOR USE IN OPTICAL MEMBER AND OPTICAL MEMBER 审中-公开
    用于光学部件和光学部件的放射性可固化树脂组合物

    公开(公告)号:US20090233103A1

    公开(公告)日:2009-09-17

    申请号:US11917508

    申请日:2006-06-15

    摘要: A radiation-curable resin composition for optical parts comprising (A) 5% to 70% by weight of a urethane (meth)acrylate which is a reaction product of (a) a (meth)acrylate having a hydroxyl group, (b) a polyisocyanate having an aromatic ring, (c) a polyol, and (d) an alcohol having 1 to 4 carbon atoms without a polymerizable unsaturated group, and which has (meth)acryloyl groups in an amount of 40% to 85% by mole of its molecular ends on average of the reaction product; and (B) 10% to 80% by weight of a compound, other than the component (A), having an ethylenically unsaturated group is provided. A cured product of the composition exhibits a high refractive index, excellent property of adhesion to various plastic substrates, appropriate hardness, and little sign of yellowing.

    摘要翻译: 一种光学部件用放射线固化型树脂组合物,其含有(A)5重量%〜70重量%的作为(a)具有羟基的(甲基)丙烯酸酯的反应产物的氨基甲酸酯(甲基)丙烯酸酯,(b) 具有芳环的多异氰酸酯,(c)多元醇,(d)不含可聚合不饱和基团的碳原子数1〜4的醇,(甲基)丙烯酰基的含量为40〜85摩尔% 其分子结束于反应产物的平均值; 和(B)10%至80%重量的具有烯键式不饱和基团的组分(A)以外的化合物。 该组合物的固化产物具有高折射率,对各种塑料基材的粘附性优异,适当的硬度和少黄色迹象。

    Curable liquid resin composition
    10.
    发明申请
    Curable liquid resin composition 有权
    可固化液体树脂组合物

    公开(公告)号:US20050070623A1

    公开(公告)日:2005-03-31

    申请号:US10488472

    申请日:2002-09-26

    CPC分类号: C09D4/00 C08F230/08

    摘要: To provide a radiation-sensitive curable liquid resin composition having excellent applicability and capable of producing a film excelling in hardness, scratch resistance, adhesion, transparency, and appearance of the surface of the film. A curable liquid resin composition comprising: (A) particles prepared by bonding at least one oxide of an element selected from the group consisting of silicon, aluminum, zirconium, titanium, zinc, germanium, indium, tin, antimony, and cerium to a specific organic compound which comprises a polymerizable unsaturated group and a group shown by —X—C(═Y)—NH— (wherein X is NH, O, or S, and Y is O or S), and preferably a silanol group, (B) a compound having two or more polymerizable unsaturated groups in the molecule, (C) a specific alkylene glycol organic solvent, and preferably (D) a polymerization initiator.

    摘要翻译: 本发明提供一种具有优异适用性且能够制备出优异的薄膜表面的硬度,耐擦伤性,粘附性,透明性和外观的薄膜的辐射敏感性固化性液体树脂组合物。 一种可固化液体树脂组合物,其包含:(A)通过将选自硅,铝,锆,钛,锌,锗,铟,锡,锑和铈中的至少一种元素的氧化物键合到特定的 包含可聚合不饱和基团和由-XC(= Y)-NH-(其中X是NH,O或S,Y是O或S)表示的基团的有机化合物,优选硅烷醇基,(B) 在分子中具有两个以上聚合性不饱和基团的化合物,(C)特定的亚烷基二醇有机溶剂,优选(D)聚合引发剂。