摘要:
The invention disclose a hydrogen fluoride containing composition comprising hydrogen fluoride and a compound which is liquid in the standard state (25° C., 1 atmosphere) and has a boiling point of 120° C. or more and pka of 12 or more at 25° C., and use of the composition for a fluorination agent. The compound which can be preferably used is represented by the formula (1): wherein R1 to R4 are a substituted or unsubstituted alkyl or aryl group and can be the same or different, and R1 or R2 or R3 and R4 can bond to form a ring having a nitrogen atom or a nitrogen atom and other hetero atom, or R1 and R3 can bond to form a ring having a nitrogen atom or a nitrogen atom and other hetero atom. The fluorination agent of the invention exerts effect with a similar reaction mechanism to hydrogen fluoride, can be applied to the halogen exchange reaction of a halogen containing organic compound, and can produce a fluorine containing compound with safety and ease without specific equipment or technique.
摘要:
There is disclosed a convenient and efficient process for producing a fluorinated silicon compound which comprises reacting a silicon compound having at least one group selected from the group consisting of a hydroxyl group, an alkoxy group, and an aryloxy group bonded to silicon atom, with a compound represented by the formula (1): wherein R1, R2, R3, and R4 may be the same or different, and each represents a substituted or unsubstituted, saturated or unsaturated alkyl group, or a substituted or unsubstituted aryl group; and R1 and R2 or R3 and R4 can bond to form a ring having one or more nitrogen atoms or having one or more nitrogen atoms and other hetero atoms; or R1 and R3 can bond to form a ring having two or more nitrogen atoms or having two or more nitrogen atoms and other hetero atoms, to fluorinate the groups.
摘要:
The invention has disclosed a trifluoroacetoxylation agent and a preparation process of the agent, which is safe and ease to handle, very useful in industry, and represented by the formula (1); wherein R1 to R4 are a substituted or unsubstituted, saturated or unsaturated alkyl group or a substituted or unsubstituted aryl group and can be the same or different, R1 and R2 or R3 and R4 can bond to form a ring containing a nitrogen atom or a nitrogen atom and other hetero atoms, and R1 and R3 can bond to form a ring containing a nitrogen atom or a nitrogen atom and other hetero atoms.
摘要:
A preparation process of an acetylene derivative comprising reacting a compound having a skeleton represented by the formula (1): ##STR1## in the molecular formula with a compound represented by the formula (2): ##STR2## wherein R.sup.1, R.sup.2 R.sup.3 and R.sup.4 are individually an alkyl group having 1 to 6 carbon atoms and can be the same or different, R.sup.1 and R.sup.3 can bond each other to form a ring, and R.sup.1 and R.sup.2 or R.sup.3 and R.sup.4 can be bond each other to form one or two heterocyclic rings: or with a compound represented by the formula (3): wherein R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are the same as in the formula (2), and X.sub.1 is a ##STR3## chlorine, bromine or iodine atom.
摘要:
A preparation process of a fluorine substituted aromatic compound comprising reacting an alkali metal or alkali earth metal salt of an aromatic compound having a hydroxy group with an organic fluorinating agent is disclosed. As a representative fluorinating agent, a bis-dialkylamino-difluoromethane compound, for example, 2,2′-difluoro-1,3-dimethylimidazolidine, is exemplified. According to the process, an industrially useful fluorinated aromatic compound, for example, a fluorobenzene, a fluorine substituted benzophenone, a fluorine substituted diarylsulfone can be prepared with ease in economy without specific equipment.
摘要:
A polymer compound suitable for use in organic electroluminescent elements; a process for producing the compound; and an organic electroluminescent element employing the compound. The polymer is a sulfo-containing polymer characterized by having a structure formed by introducing sulfo groups into a polymer comprising repeating units represented by the general formula (1): wherein, in the formula, Ar1 and Ar2 each represents a monovalent aromatic group; Y represents a divalent group comprising an aromatic group; and W represents a divalent aromatic group having 4 to 30 carbon atoms.
摘要:
A polymer compound suitable for use in organic electroluminescent elements; a process for producing the compound; and an organic electroluminescent element employing the compound. The polymer is a sulfo-containing polymer characterized by having a structure formed by introducing sulfo groups into a polymer comprising repeating units represented by the general formula (1): wherein, in the formula, Ar1 and Ar2 each represents a monovalent aromatic group; Y represents a divalent group comprising an aromatic group; and W represents a divalent aromatic group having 4 to 30 carbon atoms.