摘要:
The present specification discloses a polymer electrolyte fuel cell characterized in that each of the cathode and the anode comprises catalyst particles, a hydrogen ion-conductive polymer electrode, a conductive porous base material and a water repellent agent, and water repellency of at least one of the cathode and the anode varies in a direction of thickness or in a plane direction. As such, by varying the degree of the water repellency of the cathode and the anode on the basis of a position, an excellent polymer electrolyte fuel cell having a high discharge characteristic or more specifically a high current-voltage characteristic in a high current density range.
摘要:
A polymer electrolyte fuel cell is provided comprising: a hydrogen ion conductive polymer electrolyte membrane; an anode and a cathode sandwiching the hydrogen ion conductive polymer electrolyte membrane; an anode side electroconductive separator having a gas channel for supplying a fuel gas to the anode; a cathode side electroconductive separator having a gas channel for supplying an oxidant gas to the cathode; characterized in that the anode and the cathode comprise a gas diffusion layer and a catalyst layer formed on the gas diffusion layer at the side in contact with the hydrogen ion conductive polymer electrolyte membrane, the catalyst layer has catalyst particles and a hydrogen ion conductive polymer electrolyte, and at least either of hydrogen ion conductivity and gas permeability of at least either of the anode and the cathode varies in a thickness direction of the anode or the cathode.
摘要:
A fuel cell system includes a first electrolyte-electrode assembly which comprises a hydrogen ion-conductive electrolyte layer, and a fuel electrode and a hydrogen-generating electrode that sandwich the electrolyte layer; a second electrolyte-electrode assembly which comprises a hydrogen ion-conductive electrolyte layer, and a fuel electrode and an oxidant electrode that sandwich the electrolyte layer; a fuel supplying means for supplying a liquid or gas fuel to the fuel electrode of the first electrolyte-electrode assembly; a means for applying to the fuel electrode of the first electrolyte-electrode assembly a potential which is positive to the hydrogen-generating electrode; and a means for supplying to the fuel electrode of the second electrolyte-electrode assembly hydrogen generated in the hydrogen-generating electrode.
摘要:
A polymer electrolyte fuel cell is provided comprising: a hydrogen ion conductive polymer electrolyte membrane; an anode and a cathode sandwiching the hydrogen ion conductive polymer electrolyte membrane; an anode side electroconductive separator having a gas channel for supplying a fuel gas to the anode; a cathode side electroconductive separator having a gas channel for supplying an oxidant gas to the cathode; characterized in that the anode and the cathode comprise a gas diffusion layer and a catalyst layer formed on the gas diffusion layer at the side in contact with the hydrogen ion conductive polymer electrolyte membrane, the catalyst layer has catalyst particles and a hydrogen ion conductive polymer electrolyte, and at least either of hydrogen ion conductivity and gas permeability of at least either of the anode and the cathode varies in a thickness direction of the anode or the cathode.
摘要:
A polymer electrolyte fuel cell comprising an anode, a cathode, a polymer electrolyte membrane interposed between the anode and the cathode, an anode-side separator plate having a gas flow path to supply fuel gas to the anode and a cathode-side separator plate having a gas flow path to supply oxidant gas to the cathode. Each of the anode and the cathode comprises a catalyst layer in contact with the polymer electrolyte membrane, an electrode supporting material having gas permeability and electronic conductivity, and a water repellent layer interposed between the catalyst layer and the electrode supporting material. The water repellent layer has through holes through which the catalyst layer and the electrode supporting material are electrically connected.
摘要:
A controller (15) performs a stop operation of stopping electric power generation by a fuel cell (3); then performs an activity recovery operation of stopping the supply of a fuel gas by a fuel gas supply unit (10) to an anode (2a), causing an anode inert gas supply unit (13) to supply an inert gas to the anode (2a), and causing an oxidizing gas supply unit (11) to supply an oxidizing gas to a cathode (2b); and performs control such that the fuel gas supply unit (10) resumes supplying the fuel gas to the anode (2a) to resume the electric power generation by the fuel cell (3) after the cell voltage of the fuel cell (3) which is detected by a voltage detector (14) has decreased to a first voltage or lower.
摘要:
Methods are provided for easily obtaining a high performance electrode without using an organic solvent for making an ink of an electrode catalyst or a surfactant for making an ink of a water repellent carbon material. The methods of manufacturing an electrode for a polymer electrolyte fuel cell comprise (a) a step of adhering a polymer electrolyte or a water repellent material to fine electrically conductive particles, and granulating the electrically conductive particles to obtain multinary granules, and (b) a step of depositing the multinary granules in layer form to obtain a catalyst layer or a water repellent layer of an electrode. Apparatus for manufacturing the electrodes, as well as polymer electrolyte fuel cells using the electrodes are also provided.
摘要:
Methods are provided for easily obtaining a high performance electrode without using an organic solvent for making an ink of an electrode catalyst or a surfactant for making an ink of a water repellent carbon material. The methods of manufacturing an electrode for a polymer electrolyte fuel cell comprise (a) a step of adhering a polymer electrolyte or a water repellent material to fine electrically conductive particles, and granulating the electrically conductive particles to obtain multinary granules, and (b) a step of depositing the multinary granules in layer form to obtain a catalyst layer or a water repellent layer of an electrode. Apparatus for manufacturing the electrodes, as well as polymer electrolyte fuel cells using the electrodes are also provided.
摘要:
Methods are provided for easily obtaining a high performance electrode without using an organic solvent for making an ink of an electrode catalyst or a surfactant for making an ink of a water repellent carbon material. The methods of manufacturing an electrode for a polymer electrolyte fuel cell comprise (a) a step of adhering a polymer electrolyte or a water repellent material to fine electrically conductive particles, and granulating the electrically conductive particles to obtain multinary granules, and (b) a step of depositing the multinary granules in layer form to obtain a catalyst layer or a water repellent layer of an electrode. Apparatus for manufacturing the electrodes, as well as polymer electrolyte fuel cells using the electrodes are also provided.
摘要:
The present invention relates to a thermoelectric material containing CoSb.sub.3 compound for converting heat to electricity, and provides a p-type thermoelectric material of CoSb.sub.3 having a high power factor by achieving high Seebeck coefficient consistently with high electric conductivity in a material of CoSb.sub.3 system without causing increase in heat conductivity. By sintering Co.sub.0.07 Pt.sub.0.03 Sb.sub.3 alloy powder using the spark plasma sintering technique, the material is densified, while growth of grains is restricted, so that a higher electric conductivity is achieved with a heat conductivity maintained in a low level, and the figure of merit as a heat-transfer material is improved. Also, by providing such heat insulating layer as an oxide intermediately in a grain boundary of a compound of CoSb.sub.3 in a sintered body, the heat conductivity is reduced. Further, the Seebeck coefficient is increased by adding a rare earth metal to the thermoelectric material of CoSb.sub.3, and allowing it to be precipitated in grain boundaries of the sintered body.