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    ORGANOALUMINUM COMPOUND
    1.
    发明申请
    ORGANOALUMINUM COMPOUND 失效
    有机铬化合物

    公开(公告)号：US20110295031A1

    公开(公告)日：2011-12-01

    申请号：US13115608

    申请日：2011-05-25

    申请人： Hisanori ITOH ,  Yoji HORI

    发明人： Hisanori ITOH ,  Yoji HORI

    IPC分类号： C07F5/06 ,  C07C35/17

    CPC分类号： C07F5/066 ,  B01J31/143 ,  B01J2231/52 ,  C07B2200/07 ,  C07C29/56 ,  C07C2601/14 ,  C07C35/17

    摘要： A catalyst for obtaining isopulegol of high diastereoselectivity by highly selective cyclization reaction of citronellal is provided. The present invention relates to an organoaluminum compound obtained by reacting at least one organoaluminumoxy compound selected from the group consisting of chain aluminoxanes, cyclic aluminoxanes and bis(dialkylaluminumoxy)alkylboranes, with at least one hydroxy compound selected from the group consisting of diarylphenols, bis(diarylphenol) compounds, biaryldiols, dimethanols and silanols.

    摘要翻译： 提供了通过香茅醛的高度选择性环化反应获得高非对映选择性的异ule醇的催化剂。 本发明涉及通过使至少一种选自链铝氧烷，环状铝氧烷和双（二烷基铝氧基）烷基硼烷的有机铝氧化合物与至少一种选自二芳基酚，二（ 二芳基苯酚）化合物，联芳二醇，二甲醇和硅烷醇。

    CATALYST FOR ASYMMETRIC HYDROGENATION
    2.
    发明申请
    CATALYST FOR ASYMMETRIC HYDROGENATION 有权
    不对称加氢催化剂

    公开(公告)号：US20100324338A1

    公开(公告)日：2010-12-23

    申请号：US12792016

    申请日：2010-06-02

    申请人： Hironori MAEDA ,  Yoji HORI

    发明人： Hironori MAEDA ,  Yoji HORI

    IPC分类号： C07C45/62 ,  B01J31/02 ,  C07C29/17

    CPC分类号： C07D207/06 ,  B01J31/181 ,  B01J2231/645 ,  B01J2531/821 ,  B01J2531/822 ,  B01J2531/824 ,  B01J2531/827 ,  B01J2531/828 ,  B01J2531/847 ,  C07B53/00 ,  C07B2200/07 ,  C07C45/62 ,  C07D207/08 ,  C07D207/16 ,  C07D233/32 ,  C07D241/44 ,  C07D405/04 ,  C07C47/21

    摘要： This invention aims at providing a catalyst for producing an optically active aldehyde or an optically active ketone, which is an optically active carbonyl compound, by carrying out selective asymmetric hydrogenation of an α,β-unsaturated carbonyl compound, particularly a catalyst which is insoluble in a reaction mixture for obtaining optically active citronellal which is useful as a flavor or fragrance, by carrying out selective asymmetric hydrogenation of citral, geranial or neral; and a method for producing a corresponding optically active carbonyl compound. The invention relates to a catalyst for asymmetric hydrogenation of an α,β-unsaturated carbonyl compound, which comprises a powder of at least one metal selected from metals belonging to Group 8 to Group 10 of the Periodic Table, or a metal-supported substance in which at least one metal selected from metals belonging to Group 8 to Group 10 of the Periodic Table is supported on a support, an optically active cyclic nitrogen-containing compound and an acid.

    摘要翻译： 本发明的目的在于提供一种用于制备光学活性醛或光学活性酮的催化剂，它是光学活性的羰基化合物，通过进行α，bgr-不饱和羰基化合物的选择性不对称氢化，特别是不溶于 在用于获得可用作香料或香料的光学活性香茅醛的反应混合物中，通过进行柠檬醛，香叶醛或香精的选择性不对称氢化; 以及制备相应的光学活性羰基化合物的方法。 本发明涉及一种α，β-不饱和羰基化合物的不对称氢化催化剂，它包括选自属于元素周期表第8至第10族金属的至少一种金属的粉末或金属负载物质 其中选自属于元素周期表第8族至第10族的金属中的至少一种金属负载在载体上，光学活性环状含氮化合物和酸。