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公开(公告)号：US5219510A
公开(公告)日：1993-06-15
申请号：US588650
申请日：1990-09-26
申请人： Julie S. Machell , I. Daniel Sand
发明人： Julie S. Machell , I. Daniel Sand
CPC分类号： C08J5/18 , C08K5/521 , G03C1/795 , C08J2301/12
摘要： A cellulose ester film which can be melt cast is manufactured by esterfying cellulose to form a cellulose acetate or cellulose acetate propionate having degrees of substitution of DSac=1.9 to 2.6, DSpr=0 to 0.9 and DS.sub.OH =0 to 0.55 and melt compounding the resulting polymer with a non-volatile phosphoric acid ester. A film is formed by melt extruding the compounded polymer onto a cooling surface to form a solid film. The film is then biaxially oriented at 130.degree. to 200.degree. C. and a stretch ratio of 1.25.times. to 2.5.times. in both directions. The resulting product is a film of excellent properties such as surface smoothness, light transmission, low haze, low color, high elastic modulus and curl relaxation after aqueous processing. The melt cast film is useful as a photographic roll film to replace solvent cast cellulose triacetate.
摘要翻译： 可以通过酯化纤维素来形成纤维素以形成醋酸纤维素或醋酸纤维素乙酸酯，其DSac = 1.9至2.6，DSpr = 0至0.9，DSOH = 0至0.55，并将所得的 聚合物与非挥发性磷酸酯。 通过将复合聚合物熔融挤出到冷却表面上以形成固体膜来形成膜。 然后将膜在130℃至200℃双轴取向，并且在两个方向上的拉伸比为1.25×2.5×2.5。 得到的产品是水性处理后的表面平滑性，透光性，低雾度，低颜色，高弹性模量和卷曲松弛等优异的膜。 熔融流延膜可用作照相辊膜以替代溶剂浇铸纤维素三乙酸酯。
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2.发明授权
公开(公告)号：US4482588A
公开(公告)日：1984-11-13
申请号：US496345
申请日：1983-05-19
IPC分类号： B32B27/04 , C08J5/12 , C08L67/00 , C08L77/12 , C09J177/12 , B65D3/00 , B32B27/10 , C08F12/30
CPC分类号： C09J177/12 , B32B27/04 , C08J5/124 , C08L67/00 , C08L77/12 , Y10T428/1379 , Y10T428/1383 , Y10T428/31736 , Y10T428/31757 , Y10T428/31786
摘要： Bonding compositions for bonding polyesters or copolyesters to poly(vinyl alcohol) or copolymers thereof, the composition comprising a poly(esteramide) having an inherent viscosity of at least 0.8 dl/g, said poly(esteramide) containing repeating units from 70 to 90 mol percent of a dicarboxylic acid selected from adipic, pimelic, suberic, azelaic, sebacic acid or combinations thereof and 10 to 30 mol percent of a second linear aliphatic dicarboxylic acid having at least four carbon atoms connected linearly between the two acid groups or an aromatic dicarboxylic acid; repeating units from 10 mol percent to 30 mol percent of a diamine selected from 1,6-hexanediamine, 1,4-cyclohexanebismethylamine or combinations thereof; and repeating units from 90 to 70 mol percent of a glycol selected from ethylene glycol, 1,4-butanediol, 1,4-cyclohexanedimethanol or combinations thereof. The repeating units from the second linear aliphatic dicarboxylic acid and repeating units from the diamine are present in equal molar amounts. Also disclosed are shaped articles comprising a polyester polymer layer and a poly(vinyl alcohol) layer, the layers being bonded together with bonding compositions of this invention.
摘要翻译： 用于将聚酯或共聚酯键合到聚（乙烯醇）或其共聚物的粘合组合物，该组合物包含特性粘度为至少0.8dl / g的聚（酯酰胺），所述聚（酯酰胺）含有70-90mol重量单元 选自己二酸，庚二酸，辛二酸，壬二酸，癸二酸或其组合的二羧酸的百分比和10至30摩尔％的具有至少四个碳原子的直链脂族二羧酸在两个酸基之间直接连接或芳族二羧酸 酸; 从10摩尔％至30摩尔％的选自1,6-己二胺，1,4-环己烷二甲胺或其组合的二胺的重复单元; 以及90-70mol％的选自乙二醇，1,4-丁二醇，1,4-环己烷二甲醇或其组合的二醇的重复单元。 来自第二直链脂族二羧酸的重复单元和来自二胺的重复单元以相等摩尔量存在。 还公开了包含聚酯聚合物层和聚（乙烯醇）层的成型制品，这些层通过本发明的粘合组合物结合在一起。
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公开(公告)号：US5288715A
公开(公告)日：1994-02-22
申请号：US18052
申请日：1993-02-16
申请人： Julie S. Machell , I. Daniel Sand
发明人： Julie S. Machell , I. Daniel Sand
CPC分类号： C08J5/18 , C08K5/521 , G03C1/795 , C08J2301/12
摘要： A cellulose ester film which can be melt cast is manufactured by esterfying cellulose to form a cellulose acetate or cellulose acetate propionate having degrees of substitution of DSac=1.9 to 2.6, DSpr=0 to 0.9 and DS.sub.OH =0 to 0.55 and melt compounding the resulting polymer with a non-volatile phosphoric acid ester. A film is formed by melt extruding the compounded polymer onto a cooling surface to form a solid film. The film is then biaxially oriented at 130.degree. to 200.degree. C. and a stretch ratio of 1.25x to 2.5x in both directions. The resulting product is a film of excellent properties such as surface smoothness, light transmission, low haze, low color, high elastic modulus and curl relaxation after aqueous processing. The melt cast film is useful as a photographic roll film to replace solvent cast cellulose triacetate.
摘要翻译： 可以通过酯化纤维素来形成纤维素以形成醋酸纤维素或醋酸纤维素乙酸酯，其DSac = 1.9至2.6，DSpr = 0至0.9，DSOH = 0至0.55，并将所得的 聚合物与非挥发性磷酸酯。 通过将复合聚合物熔融挤出到冷却表面上以形成固体膜来形成膜。 然后将膜在130度至200度双轴取向，并且在两个方向上的拉伸比为1.25×2.5×2.5倍。 得到的产品是水性处理后的表面平滑性，透光性，低雾度，低颜色，高弹性模量和卷曲松弛等优异的膜。 熔融流延膜可用作照相辊膜以替代溶剂浇铸纤维素三乙酸酯。
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4.发明授权
公开(公告)号：US4481238A
公开(公告)日：1984-11-06
申请号：US496343
申请日：1983-05-19
IPC分类号： B32B7/12 , B32B27/30 , B32B27/36 , C08G63/68 , C08G69/00 , C08G69/44 , C08G73/16 , C08J5/12 , C08L77/00 , C09J167/00 , C09J177/12 , C09J179/00 , B32B15/08
CPC分类号： B32B27/36 , C08G73/16 , C08J5/124 , C09J177/12 , C09J179/00 , Y10T428/1383 , Y10T428/31736 , Y10T428/31757 , Y10T428/31786
摘要： Bonding compositions for bonding polyesters or copolyesters to poly(vinyl alcohol) or copolymers thereof, the composition comprising a poly(esteramide) having an inherent viscosity of at least 0.45 dl/g, said poly(esteramide) containing repeating units from at least 80 mol percent of a dicarboxylic acid selected from pimelic, azelaic, sebacic acid or combinations thereof and optionally up to 20 mol percent of a second linear aliphatic dicarboxylic acid having at least four carbon atoms connected linearly between the two acid groups or an aromatic dicarboxylic acid; repeating units from 5 mol percent to 20 mol percent of 1,2-ethanediamine; and repeating units from 95 to 80 mol percent of a glycol selected from ethylene glycol, 1,4-butanediol, 1,4-cyclohexanedimethanol or combinations thereof. Also disclosed are shaped articles comprising a polyester polymer layer and a poly(vinyl alcohol) layer, the layers being bonded together with bonding compositions of this invention.
摘要翻译： 用于将聚酯或共聚酯键合到聚（乙烯醇）或其共聚物的粘合组合物，该组合物包含特性粘度为至少0.45dl / g的聚（酯酰胺），所述聚（酯酰胺）含有至少80mol 百分比选自庚二酸，壬二酸，癸二酸或其组合的二羧酸和任选至多20摩尔％的具有至少四个碳原子的直链脂族二羧酸在两个酸基之间直接连接或芳族二羧酸; 重复单元为5mol％至20mol％的1,2-乙二胺; 和95〜80摩尔％的选自乙二醇，1,4-丁二醇，1,4-环己烷二甲醇或其组合的二元醇的重复单元。 还公开了包含聚酯聚合物层和聚（乙烯醇）层的成型制品，这些层通过本发明的粘合组合物结合在一起。
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5.发明授权Cellulose esters moidified with anhydrides of dicarboxylic acids and their use in waterborne basecoats 失效与二羧酸的酸酐混合的纤维素酯及其在水性底漆中的用途
公开(公告)号：US5384163A
公开(公告)日：1995-01-24
申请号：US781472
申请日：1991-10-23
申请人： Anna M. Budde , I. Daniel Sand , Alan R. Dunn , Chung M. Kuo
发明人： Anna M. Budde , I. Daniel Sand , Alan R. Dunn , Chung M. Kuo
IPC分类号： C08G18/64 , C09D101/14 , C09D175/04 , C08L1/14
CPC分类号： C09D101/14 , C08G18/6484 , C09D175/04
摘要： Novel coating compositions containing modified cellulose esters are disclosed. The modified cellulose esters contain acid functionality, permitting their dispersion in aqueous systems. The modified cellulose esters are particularly useful as rheology control agents in coatings which are applied as waterborne dispersions. The novel coating compositions are used to produce coated substrates with desirable appearance characteristics.
摘要翻译： 公开了含改性纤维素酯的新型涂料组合物。 改性的纤维素酯含有酸官能团，允许其在含水体系中分散。 改性纤维素酯特别可用作作为水性分散体施用的涂料中的流变控制剂。 新型涂料组合物用于制备具有期望外观特征的涂布基材。
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公开(公告)号：US5104450A
公开(公告)日：1992-04-14
申请号：US588210
申请日：1990-09-26
申请人： I. Daniel Sand , John A. Hyatt , Stephen S. Kelley
发明人： I. Daniel Sand , John A. Hyatt , Stephen S. Kelley
摘要： Blends of cellulose esters and arylene-bis(diaryl phosphate) compounds are described. The blends are useful for preparing film or other molded objects. The blends can possess several desirable properties such as flame-retardation, plasticization, formulaic stabilization and dimensional stabilization.
摘要翻译： 描述了纤维素酯和亚芳基 - 双（磷酸二芳基酯）化合物的共混物。 该混合物可用于制备膜或其它成型物体。 共混物可以具有几种所需的性质，例如阻燃，塑化，配方稳定化和尺寸稳定性。
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公开(公告)号：US4605721A
公开(公告)日：1986-08-12
申请号：US725186
申请日：1985-04-19
IPC分类号： C08F251/02 , C08F251/00 , C08G81/00 , C08G83/00
CPC分类号： C08F251/02
摘要： The present invention relates to novel graft copolymers and to a novel process for the preparation thereof. The polymeric compositions provided by the present invention comprise the reaction product of an ethylenically unsaturated monomer and a carboxylated cellulose ester having an acid number of at least about 5, an inherent viscosity of from about 0.01 to about 1.00 and wherein the anhydroglucose units thereof have ring substituents comprising by weight based on total polymer weight, of from about 0.05 to about 20% hydroxyl groups, from about 0.5 to about 44% acetyl groups, from 0 to about 54% butyryl groups, from 0 to about 47% propionyl groups, from about 0.4 to about 4.0% total carboxyl groups wherein from about 20% to about 100% of these carboxyl groups are non-saponifiable backbone, and wherein the material has a lactone level of from about 4.52.times.10.sup.-15 to about 6.13.times.10.sup.-4. Preferred carboxylated cellulose esters include carboxylated cellulose acetate, carboxylated cellulose acetate propionate, carboxylated cellulose acetate butyrate, and mixtures thereof. Preferred ethylenically unsaturated monomers include acrylic monomers, such as acrylic acid, methacrylic acid, acrylic acid esters, methacrylic acid esters, etc., acrylamides, methacrylamides, and vinyl monomers, such as vinyl aromatic compounds (e.g., styrene, divinylbenzene vinyltoluene, vinylnaphthalene, etc.), vinyl acetate, vinyl chloride, vinyl bromide, vinylidene chloride, vinylidene fluoride, tetrafluoroethylene, etc. The process of the present invention comprises reacting an ethylenically unsaturated monomer and a carboxylated cellulose ester at polymerization temperature (e.g., about 10.degree. to 250.degree. C.) in the substantial absence of an additional initiator.
摘要翻译： 本发明涉及新颖的接枝共聚物及其制备方法。 由本发明提供的聚合物组合物包含烯键式不饱和单体和羧酸化纤维素酯的反应产物，其酸值为至少约5，特性粘度为约0.01至约1.00，并且其中脱水葡萄糖单元具有环 基于总聚合物重量的约0.05至约20％的羟基，约0.5至约44％的乙酰基，0至约54％的丁酰基，0至约47％的丙酰基， 约0.4至约4.0％的总羧基，其中约20％至约100％的这些羧基是不可皂化的主链，并且其中所述材料的内酯水平为约4.52×10-15至约6.13×10-4。 优选的羧化纤维素酯包括羧化纤维素乙酸酯，羧酸纤维素乙酸丙酸酯，羧酸纤维素乙酸丁酸酯及其混合物。 优选的烯属不饱和单体包括丙烯酸单体，例如丙烯酸，甲基丙烯酸，丙烯酸酯，甲基丙烯酸酯等，丙烯酰胺，甲基丙烯酰胺和乙烯基单体，例如乙烯基芳族化合物（例如苯乙烯，二乙烯基苯乙烯基甲苯，乙烯基萘， 乙酸乙烯酯，氯乙烯，溴乙烯，偏二氯乙烯，偏二氟乙烯，四氟乙烯等。本发明的方法包括在聚合温度（例如约10℃至100℃）下使烯属不饱和单体和羧化纤维素酯反应 250℃），基本上不存在另外的引发剂。
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公开(公告)号：US4812495A
公开(公告)日：1989-03-14
申请号：US110158
申请日：1987-10-19
申请人： I. Daniel Sand
发明人： I. Daniel Sand
IPC分类号： C08F2/44 , C08B3/22 , C08F20/10 , C08F220/20 , C09J4/06 , C09J11/04 , C09J101/14 , C08G81/00 , C08G83/00
CPC分类号： C09J101/14 , C08B3/22 , C09J4/06
摘要： Disclosed are anaerobic adhesive compositions which cure under anaerobic conditions, said compositions being comprised of at least one carboxylated cellulose ester such as carboxylated cellulose acetate butyrate or carboxylated cellulose acetate propionate, at least one acrylate monomer, and at least one hydroquinone-based stabilizer. The composition can optionally contain an accelerator.
摘要翻译： 所公开的是在厌氧条件下固化的厌氧粘合剂组合物，所述组合物由至少一种羧化纤维素酯如羧酸纤维素乙酸丁酸酯或羧化纤维素乙酸酯丙酸酯，至少一种丙烯酸酯单体和至少一种基于对苯二酚的稳定剂组成。 组合物可任选地含有促进剂。
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9.发明授权
公开(公告)号：US4604446A
公开(公告)日：1986-08-05
申请号：US686508
申请日：1984-12-26
IPC分类号： C08G63/672 , C08G63/688 , C08G63/18
CPC分类号： C08G63/6886 , C08G63/672
摘要： Disclosed are polyesterether bonding compositions comprising repeating units from trans-1,4-cyclohexanedicarboxylic acid, a difunctional sulfomonomer, a polyetherglycol, 1,4-butanediol or 1,4-cyclohexanedimethanol and ethylene glycol.
摘要翻译： 公开了包含来自反式-1,4-环己烷二羧酸的重复单元，双官能磺基单体，聚醚二醇，1,4-丁二醇或1,4-环己烷二甲醇和乙二醇的聚酯树脂粘合组合物。
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10.发明授权
公开(公告)号：US4482587A
公开(公告)日：1984-11-13
申请号：US496344
申请日：1983-05-19
CPC分类号： C08G69/44 , B32B27/04 , Y10T428/1379 , Y10T428/1383 , Y10T428/31736 , Y10T428/31757 , Y10T428/31786
摘要： Bonding compositions for bonding polyesters or copolyesters to poly(vinyl alcohol) or copolymers thereof, the composition comprising a poly(esteramide) having an inherent viscosity of at least 0.8 dl/g, said poly(esteramide) containing repeating units from at least 70 mol percent of a dicarboxylic acid selected from pimelic, azelaic, sebacic acid or combinations thereof and optionally up to 30 mol percent of a second linear aliphatic dicarboxylic acid having at least four carbon atoms connected linearly between the two acid groups or an aromatic dicarboxylic acid; repeating units from 10 mol percent to 30 mol percent of a diamine selected from 1,6-hexanediamine, 1,4-cyclohexanebismethylamine or combinations thereof; and repeating units from 90 to 70 mol percent of a glycol selected from ethylene glycol, 1,4-butanediol, 1,4-cyclohexanedimethanol or combinations thereof. Also disclosed are shaped articles comprising a polyester polymer layer and a poly(vinyl alcohol) layer, the layers being bonded together with bonding compositions of this invention.
摘要翻译： 用于将聚酯或共聚酯键合到聚（乙烯醇）或其共聚物的粘合组合物，该组合物包含特性粘度为至少0.8dl / g的聚（酯酰胺），所述聚（酯酰胺）含有至少70mol 百分比选自庚二酸，壬二酸，癸二酸或其组合的二羧酸和任选至多30摩尔％的具有至少四个碳原子的直链脂族二羧酸在两个酸基之间直接连接或芳族二羧酸; 从10摩尔％至30摩尔％的选自1,6-己二胺，1,4-环己烷二甲胺或其组合的二胺的重复单元; 以及90-70mol％的选自乙二醇，1,4-丁二醇，1,4-环己烷二甲醇或其组合的二醇的重复单元。 还公开了包含聚酯聚合物层和聚（乙烯醇）层的成型制品，这些层通过本发明的粘合组合物结合在一起。
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