公开(公告)号：US09249364B2

公开(公告)日：2016-02-02

申请号：US13767072

申请日：2013-02-14

Applicant: IFP ENERGIES NOUVELLES

Inventor： Frédéric Feugnet ,  Francois Hugues ,  Natacha Touchais ,  Hugues Dulot ,  Annick Pucci

IPC: C10G69/12 ,  C07C1/00 ,  C07C2/12 ,  C10G11/04 ,  C10G11/05

CPC classification number: C10G69/126 ,  C07C1/00 ,  C07C2/12 ,  C10G11/04 ,  C10G11/05

Abstract: The present invention describes a process for converting a heavy feed which is flexible for the production of propylene, gasoline and middle distillate.The process uses a catalytic cracking unit and a unit for the oligomerization of C4 to C9 olefins. The process of the invention includes selective hydrogenation of the unrefined gasoline cut obtained from the catalytic cracking unit and separation between a light gasoline cut and a heavy gasoline cut, the light gasoline being directed to the oligomerization unit.

Abstract translation: 本发明描述了用于转化可用于生产丙烯，汽油和中间馏分的柔性的重料的方法。 该方法使用催化裂化装置和C4至C9烯烃低聚单元。 本发明的方法包括从催化裂化装置获得的未精制汽油馏分的选择氢化和轻汽油馏分与重汽油馏分之间的分离，轻汽油被引导至低聚单元。

公开(公告)号：US09079812B2

公开(公告)日：2015-07-14

申请号：US13646002

申请日：2012-10-05

Applicant: TOTAL RESEARCH & TECHNOLOGY FELUY ,  IFP ENERGIES NOUVELLES

Inventor： Vincent Coupard ,  Natacha Touchais ,  Stephanie Fleurier ,  Helena Gonzalez Penas ,  Philip De Smedt ,  Walter Vermeiren ,  Cindy Adam ,  Delphine Minoux

IPC: C07C1/24

CPC classification number: C07C1/24 ,  C07C2529/40 ,  Y02P30/48 ,  C07C11/04

Abstract: A process for dehydration of an ethanol feedstock into ethylene, comprising the vaporization of said dilute hydrated ethanol feedstock in an exchanger, with heat exchange with the effluent that is obtained from a last reactor, with said mixture being introduced into said vaporization stage at a pressure that is lower than the pressure of the effluent that is obtained from the last reactor, the compression of the mixture that is vaporized in a compressor, the introduction of the vaporized and compressed mixture, into at least one adiabatic reactor that contains at least one dehydration catalyst.

Abstract translation: 一种将乙醇原料脱水成乙烯的方法，包括在交换器中蒸发所述稀水合乙醇原料，与最后一个反应器获得的流出物进行热交换，所述混合物在压力下被引入所述蒸发阶段 低于从最后一个反应器获得的流出物的压力，在压缩机中蒸发的混合物的压缩，将蒸发和压缩的混合物引入到至少一个绝热反应器中，该绝热反应器含有至少一个脱水 催化剂。

公开(公告)号：US11492304B2

公开(公告)日：2022-11-08

申请号：US17256786

申请日：2019-06-21

Applicant: IFP Energies Nouvelles

Inventor： Frederic Augier ,  Alexandre Vonner ,  Tiago Sozinho ,  Natacha Touchais

IPC: C07C2/32 ,  B01J19/00 ,  B01J19/24 ,  C07C11/08 ,  C07C11/107

Abstract: The invention relates to a process for the oligomerization of ethylene, carried out at a pressure of between 0.1 and 10.0 MPa, at a temperature of between 30 and 200° C., in a cascade of N gas/liquid reactors in series, N being at least equal to 2, comprising a step of introducing a catalytic oligomerization system into at least the first reactor of the cascade, a step of bringing said catalytic system and an optional solvent into contact with ethylene by introducing said ethylene into the lower part of the reaction chamber of at least the first reactor of the cascade, for each reactor n, a step of withdrawing a liquid fraction in the lower part of the reaction chamber of the reactor n, the liquid fraction being separated into two streams: a first stream corresponding to a first, “main”, part of the liquid fraction, which is conveyed to a heat exchanger for cooling; a second stream corresponding to the second part of the liquid fraction which constitutes the liquid feedstock of the following reactor n+1 in the cascade, a step of introducing said second part of the liquid phase withdrawn from the reactor n towards the reaction chamber of the following reactor n+1 in the direction of flow, a step of cooling said first part of the liquid fraction withdrawn from the reactor n in step c) by passing said first part of the liquid fraction into a heat exchanger in order to obtain a cooled liquid fraction, a step of introducing said liquid fraction cooled in step e) at the top of the reaction chamber of said reactor n, the steps a) to f) being carried out, unless indicated otherwise, for each reactor n of the cascade, n being between 1 and N. The invention also relates to a device of N stirred gas/liquid reactors in a cascade, enabling the oligomerization process to be carried out.

公开(公告)号：US09725376B2

公开(公告)日：2017-08-08

申请号：US14647174

申请日：2013-11-18

Applicant: IFP ENERGIES NOUVELLES ,  TOTAL RESEARCH & TECHNOLOGY FELUY

Inventor： Vincent Coupard ,  Natacha Touchais ,  Thomas Plennevaux ,  Emilie Kobel ,  Stephanie Fleurier ,  Walter Vermeiren ,  Delphine Minoux ,  Philip De Smedt ,  Cindy Adam ,  Nikolai Nesterenko

IPC: C01C1/24 ,  C07C1/24 ,  C07C29/76 ,  C07C41/09

CPC classification number: C07C1/24 ,  C07C29/76 ,  C07C41/09 ,  C07C2527/173 ,  C07C2529/40 ,  C07C2529/85 ,  C07C11/04 ,  C07C43/06 ,  C07C31/08

Abstract: The invention relates to a process for dehydration of an ethanol feedstock into ethylene comprising at least the stages: a) A stage for pretreatment of the ethanol feedstock on an acidic solid, b) A stage for evaporation of said pretreated ethanol feedstock in a heat exchanger, c) A stage for superheating said evaporated feedstock in such a way as to bring it to an inlet temperature that is compatible with the temperature of a dehydration reaction, d) A stage for dehydration of said feedstock that is obtained from stage c) in at least one adiabatic reactor that contains at least one dehydration catalyst.

公开(公告)号：US09663414B2

公开(公告)日：2017-05-30

申请号：US14646877

申请日：2013-11-18

Applicant: IFP ENERGIES NOUVELLES ,  TOTAL RESEARCH & TECHNOLOGY FELUY

Inventor： Vincent Coupard ,  Natacha Touchais ,  Thomas Plennevaux ,  Emilie Kobel ,  Stephanie Fleurier ,  Walter Vermeiren ,  Delphine Minoux ,  Philip De Smedt ,  Cindy Adam ,  Nikolai Nesterenko

IPC: C07C1/24 ,  C07C29/76 ,  C07C41/09

CPC classification number: C07C1/24 ,  C07C29/76 ,  C07C41/09 ,  C07C2527/173 ,  C07C2529/40 ,  C07C2529/85 ,  Y02P30/48 ,  C07C43/06 ,  C07C11/04 ,  C07C31/08

Abstract: A process for dehydration of an ethanol feedstock to ethylene by: a) preheating ethanol feedstock by heat exchange with effluent from e), b) pretreating the ethanol feedstock to produce pretreated ethanol feedstock, c) vaporizing a vaporization feedstock containing pretreated ethanol feedstock and at least a portion of the flow of treated water recycled in an exchanger to produce a vaporized feedstock, d) compressing said vaporized feedstock to produce a compressed feedstock, e) dehydrating said compressed feedstock in at least one adiabatic reactor, f) separating the effluent from the last adiabatic reactor of e) into an effluent containing ethylene and an effluent containing water, g) purifying at least a portion of the effluent containing water from 0 and separating at least one flow of treated water and at least one flow of unconverted ethanol, h) recycling at least a portion of the flow of treated water from g) upstream of c).

公开(公告)号：US10857514B2

公开(公告)日：2020-12-08

申请号：US16456313

申请日：2019-06-28

Applicant: IFP Energies nouvelles

Inventor： Frederic Augier ,  Alexandre Vonner ,  Tiago Sozinho ,  Natacha Touchais

IPC: B01J19/24 ,  B01F3/04 ,  B01J8/18 ,  B01J8/22 ,  B01J23/26 ,  B01J23/755 ,  C07C2/24 ,  C07C11/08 ,  C07C11/107

Abstract: Reaction device which makes possible the oligomerization of olefins to give linear olefins and preferably linear α-olefins, comprising a gas/liquid reactor and a reactor of plug-flow type. The reaction device is also employed in an oligomerization process.

公开(公告)号：US20150291485A1

公开(公告)日：2015-10-15

申请号：US14647174

申请日：2013-11-18

Applicant: IFP ENERGIES NOUVELLES ,  TOTAL RESEARCH & TECHNOLOGY FELUY

Inventor： Vincent Coupard ,  Natacha Touchais ,  Thomas Plennevaux ,  Emilie Kobel ,  Stephanie Fleurier ,  Walter Vermeiren ,  Delphine Minoux ,  Philip De Smedt ,  Cindy Adam ,  Nikolai Nesterenko

IPC: C07C1/24 ,  C07C41/09

CPC classification number: C07C1/24 ,  C07C29/76 ,  C07C41/09 ,  C07C2527/173 ,  C07C2529/40 ,  C07C2529/85 ,  C07C11/04 ,  C07C43/06 ,  C07C31/08

Abstract: The invention relates to a process for dehydration of an ethanol feedstock into ethylene comprising at least the stages: a) A stage for pretreatment of the ethanol feedstock on an acidic solid, b) A stage for evaporation of said pretreated ethanol feedstock in a heat exchanger, c) A stage for superheating said evaporated feedstock in such a way as to bring it to an inlet temperature that is compatible with the temperature of a dehydration reaction, d) A stage for dehydration of said feedstock that is obtained from stage c) in at least one adiabatic reactor that contains at least one dehydration catalyst.

Abstract translation: 本发明涉及一种将乙醇原料脱水成乙烯的方法，至少包括以下阶段：a）用于在酸性固体上预处理乙醇原料的阶段，b）在热交换器中蒸发所述预处理的乙醇原料的阶段 c）用于使所述蒸发的原料过热以使其达到与脱水反应的温度相适应的入口温度的阶段，d）用于脱水所述原料的阶段，其从阶段c） 至少一个含有至少一种脱水催化剂的绝热反应器。