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    PROCESS FOR THE PRODUCTION OF KEROSENE FROM BUTANOLS
    2.
    发明申请
    PROCESS FOR THE PRODUCTION OF KEROSENE FROM BUTANOLS 有权
    从丁醇生产凯洛糖的方法

    公开(公告)号：US20150246855A1

    公开(公告)日：2015-09-03

    申请号：US14427363

    申请日：2013-09-06

    Applicant: IFP Energies nouvelles

    Inventor： Tom Vivien ,  Vincent Coupard ,  Francois Hugues ,  Raphael Huyghe

    IPC: C07C1/24 ,  C10G69/12 ,  C10L1/04 ,  C07C2/10

    CPC classification number: C07C1/24 ,  C07C2/10 ,  C07C2521/12 ,  C10G45/00 ,  C10G50/00 ,  C10G69/126 ,  C10G2300/1011 ,  C10G2400/02 ,  C10G2400/04 ,  C10G2400/08 ,  C10L1/04 ,  C10L2200/0469 ,  C10L2290/08 ,  C10L2290/10 ,  C10L2290/543 ,  Y02P30/20

    Abstract: The invention relates to a process for the production of middle-distillate hydrocarbon-containing bases from a butanol feedstock, with said process comprising at least the following stages: a) isomerizing dehydration of butanol feedstock, b) separating the water from butylenic effluent, c) purifying the organic liquid effluent from stage b), d) oligomerizing of a feedstock that comprises at least a portion of the purified organic effluent from stage c), the entire effluent from stage g), and at least a portion of the light product from stage f), e) oligomerizing the first oligomerization effluent to produce a second oligomerization effluent, f) fractionating said second oligomerization effluent into at least three products: a light product that most comprises the C2 to C4 compounds, an intermediate product that mostly comprises the C5 to C9 compounds, and a middle distillate product that mostly comprises compounds having at least 10 carbon atoms, g) oligomerizing at least a portion of said intermediate product, and h) hydrogenating at least a portion of said middle distillate product.

    Abstract translation: 本发明涉及一种从丁醇原料生产含中间馏分烃的碱的方法，所述方法至少包括以下阶段：a）使丁醇原料脱水异构化，b）将水与丁烯废水分离出来，c 净化来自阶段b）的有机液体流出物，d）原料的低聚，其包含来自阶段c）的纯化的有机流出物的至少一部分，来自阶段g）的全部流出物，以及至少一部分轻质产物 从阶段f），e）使第一低聚流出物低聚以产生第二低聚流出物，f）将所述第二低聚流出物分馏成至少三种产物：大部分包含C2至C4化合物的轻质产物，主要包含 C5至C9化合物，以及主要包含具有至少10个碳原子的化合物的中间馏分产物，g）将至少一部分 所述中间产物，和h）氢化所述中间馏分产物的至少一部分。

    Method for producing hydrocarbons with continuous charging of the catalyst
    6.
    发明授权
    Method for producing hydrocarbons with continuous charging of the catalyst 有权
    用于连续加入催化剂生产烃的方法

    公开(公告)号：US09073803B2

    公开(公告)日：2015-07-07

    申请号：US13713234

    申请日：2012-12-13

    Applicant: IFP ENERGIES NOUVELLES

    Inventor： Marie Claire Marion ,  Fabrice Diehl ,  Francois Hugues

    IPC: C07C27/00 ,  B01J20/34 ,  C07C1/04 ,  B01J37/16 ,  B01J37/18 ,  C10G2/00 ,  B01J23/75 ,  B01J23/89

    CPC classification number: C07C1/0445 ,  B01J23/75 ,  B01J23/8913 ,  B01J37/16 ,  B01J37/18 ,  C10G2/332

    Abstract: The present invention relates to a method for the continuous production of hydrocarbons from synthesis gas in the presence of a catalyst comprising a synthesis step in which a synthesis gas is reacted in the presence of a catalyst in a Fischer-Tropsch synthesis reactor (4), characterised in that, at the same time as the synthesis step, the following successive steps are carried out: a) charging a catalyst precursor comprising cobalt oxide in a reduction reactor (2); b) reducing the catalyst precursor charged in step a) by placing it in contact with a reduction gas comprising hydrogen (H2) and/or carbon monoxide (CO); and c) introducing the catalyst reduced in step b) into the synthesis reactor (4).

    Abstract translation: 本发明涉及一种在催化剂存在下从合成气中连续生产烃的方法，包括合成步骤，其中合成气在费 - 托合成反应器（4）中在催化剂存在下反应， 其特征在于，在合成步骤的同时，进行以下连续步骤：a）在还原反应器（2）中装入包含氧化钴的催化剂前体; b）通过将步骤a）中加入的催化剂前体与包含氢（H 2）和/或一氧化碳（CO）的还原气体接触来还原; 和c）将步骤b）中还原的催化剂引入合成反应器（4）中。

    PROCESS FOR THE PRODUCTION OF MIDDLE DISTILLATES FROM A FEEDSTOCK COMPRISING BUTANOL AND PENTANOL
    7.
    发明申请
    PROCESS FOR THE PRODUCTION OF MIDDLE DISTILLATES FROM A FEEDSTOCK COMPRISING BUTANOL AND PENTANOL 审中-公开
    从包含丁醇和丁香醇的饲料生产中间馏分的方法

    公开(公告)号：US20140249340A1

    公开(公告)日：2014-09-04

    申请号：US14195882

    申请日：2014-03-04

    Applicant: IFP ENERGIES NOUVELLES

    Inventor： Vivien Tom ,  Vincent Coupard ,  Francois Hugues ,  Raphael Huyghe

    IPC: C07C2/08 ,  C07C5/05

    CPC classification number: C07C2/08 ,  C07C1/24 ,  C07C5/05 ,  C07C7/10 ,  C07C7/13 ,  C07C2529/70 ,  C10G3/42 ,  C10G3/44 ,  C10G3/48 ,  C10G3/49 ,  C10G50/00 ,  C10G57/02 ,  C10G2400/02 ,  C10G2400/04 ,  C10G2400/06 ,  C10G2400/08 ,  Y02P30/20 ,  C07C11/08 ,  C07C11/10

    Abstract: The invention relates to a process for the production of middle-distillate hydrocarbon-containing bases from a feedstock comprising butanol and pentanol, with said process comprising at least: a) Isomerizing dehydration of said feedstock; b) Separation of the water that is present in said olefinic effluent; c) Purification of the organic liquid effluent coming from b); d) Selective oligomerization of a feedstock that comprises at least a portion of the purified organic effluent coming from c), to produce a first oligomerization effluent; e) Oligomerization of said first oligomerization effluent in such a way as to produce a second oligomerization effluent; f) Fractionation of said second oligomerization effluent into at least three products, a light product, an intermediate product and a distillate product; g) Oligomerization of at least a portion of said intermediate product; h) Hydrogenation of at least a portion of said distillate product.

    Abstract translation: 本发明涉及一种从包含丁醇和戊醇的原料生产含中间馏分烃的碱的方法，所述方法至少包括：a）使所述原料异构化脱水; b）分离存在于所述烯烃流出物中的水; c）净化来自b）的有机液体流出物; d）原料的选择性低聚，其包含来自c）的至少一部分纯化的有机流出物，以产生第一低聚流出物; e）以这样的方式使所述第一低聚流出物低聚，以产生第二低聚流出物; f）将所述第二低聚流出物分馏成至少三种产物，轻质产物，中间产物和馏出物产物; g）所述中间产物的至少一部分的低聚; h）至少部分所述馏出物产物的氢化。

    Process for production of hydrocarbons with catalyst conditioning
    8.
    发明授权
    Process for production of hydrocarbons with catalyst conditioning 有权
    用催化剂调理生产烃的方法

    公开(公告)号：US08883866B2

    公开(公告)日：2014-11-11

    申请号：US13712232

    申请日：2012-12-12

    Applicant: IFP Energies nouvelles

    Inventor： Marie-Claire Marion ,  Fabrice Diehl ,  Francois Hugues

    IPC: C07C27/00 ,  B01J20/34 ,  B01J37/18 ,  B01J23/89 ,  B01J23/889 ,  B01J23/75 ,  B01J23/83 ,  C10G2/00 ,  B01J21/12 ,  B01J37/02

    CPC classification number: C10G2/332 ,  B01J21/12 ,  B01J23/75 ,  B01J23/83 ,  B01J23/8892 ,  B01J23/8896 ,  B01J23/8913 ,  B01J37/0201 ,  B01J37/18

    Abstract: A method for continuous production of hydrocarbons from synthesis gas in the presence of a cobalt-based catalyst which comprises a step of providing synthesis gas from a source (1) of synthesis gas in a Fischer-Tropsch synthesis reactor (4). The method also includes the following steps: a) conditioning of the catalyst in reduced state in a conditioning reactor (2) by contact with a flow of reducing gas from a synthesis gas source supplying the synthesis reactor, the reducing conditioning gas comprising carbon monoxide (CO) or a mixture comprising hydrogen (H2) and carbon monoxide (CO), the H2/CO molar ratio of which is between 0.1 and 0.9, at a temperature between 200 and 500° C., and a total pressure between 0.1 and 5 MPa and under a gas flow between 1 and 20 NI/h/g of catalyst to be treated, b) supply of reduced catalyst conditioned in step a) to the synthesis reactor (4).

    Abstract translation: 一种在钴基催化剂存在下从合成气中连续生产烃的方法，该方法包括在费 - 托合成反应器（4）中从合成气源（1）提供合成气的步骤。 该方法还包括以下步骤：a）通过与供应合成反应器的合成气源的还原气体流接触，调节反应器（2）中处于还原状态的催化剂，还原调节气体包括一氧化碳（ CO）或H 2 / CO摩尔比为0.1-0.9之间的氢（H 2）和一氧化碳（CO）的混合物，温度为200-500℃，总压力为0.1-5 MPa，并且在待处理催化剂的1至20Ni / h / g之间的气流下，b）将在步骤a）中调节的还原催化剂供应到合成反应器（4）。

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