公开(公告)号：US10213708B2

公开(公告)日：2019-02-26

申请号：US14560179

申请日：2014-12-04

Applicant: INSTITUTO MEXICANO DEL PETROLEO

Inventor： Enrique Cevada Maya ,  Laura Veronica Castro Sotelo ,  Edgar Ivan Hernandez Carbajal ,  Cesar Andres Flores Sandoval ,  Alfonso Lopez Ortega ,  Aristeo Estrada Buendia ,  Fernando Alvarez Ramirez ,  Arquimedes Estrada Martinez ,  Flavio Salvador Vazquez Moreno

IPC: C10G29/22 ,  B01D19/04

Abstract: The present invention relates to the application based on alkyl acrylate homopolymers, such as antifoaming agents in crude oils with densities of 10 to 40° API. Evaluation tests in “live” crude oil, under similar gas-liquid separation equipment conditions, showed that these polymers based on alkyl acrylate are effective foaming inhibitors in heavy and super-heavy crude oils, reducing the foam between 15 and 50% faster compared to crude oil without an antifoaming agent. Some acrylics show better performance than commercial silicon-based polymers, which suppress foam 20-25% faster than the blank. The antifoaming agents of this invention, based on alkyl acrylate and totally free of silicon, is an advantageous option, to replace the silicone-based foam inhibitors currently on the market.

公开(公告)号：US10207983B2

公开(公告)日：2019-02-19

申请号：US14581778

申请日：2014-12-23

Applicant: INSTITUTO MEXICANO DEL PETROLEO

Inventor： Raul Hernandez Altamirano ,  Luis Silvestre Zamudio Rivera ,  Violeta Yasmin Mena Cervantes ,  Hiram Isaac Beltran Conde ,  Marco Antonio Dominguez Aguilar ,  Jaquelin Martinez Viramontes ,  Aristeo Estrada Buendia

IPC: C07C227/10 ,  C07C227/16 ,  C07C227/26 ,  C07C229/16 ,  C23F11/14 ,  C10L1/222 ,  C10L1/223 ,  C10L10/04 ,  C07C229/12 ,  C07C229/24 ,  C09K15/20 ,  C10L1/14 ,  C10L1/16 ,  C10L1/182 ,  C10L1/198

Abstract: N-alkyl, N-alkenyl, N-cycloalkyl, N-aryl amino or imino propionic acids with an alkyl chain ranging from 6 to 18 carbons, or alkenyl chain from 8 to 30 carbons, are obtained from a reaction process in the absence of solvent at a temperature range from 30 to 180° C. and a time of 1 to 10 hours at atmospheric pressure. Formulations composed of N-alkyl or N-alkenyl or N-cycloalkyl or N-aryl amino or imino propionic acids, polyethers derived from propylene oxide or ethylene oxide or copolymer thereof and a solvent consisting of aromatic compounds such as toluene or xylene, diesel or gasoline or alcohols such as isopropanol and ethanol, or mixtures thereof, are obtained inhibit ferrous metal corrosion of pipelines and storage tanks and transport crude oil and liquid fuels. A method inhibiting corrosion of ferrous metals adds an effective amount of the corrosion inhibitor to a petroleum based material such as crude oil and liquid fuels such as gasoline, diesel fuel, and aviation fuel.

公开(公告)号：US10125226B2

公开(公告)日：2018-11-13

申请号：US14296097

申请日：2014-06-04

Applicant: INSTITUTO MEXICANO DEL PETROLEO

Inventor： Cesar Andres Flores Sandoval ,  Eugenio Alejandro Flores Oropeza ,  Alfonso Lopez Ortega ,  Jose Gonzalo Hernandez Cortez ,  Aristeo Estrada Buendia ,  Laura Veronica Castro Sotelo ,  Reyna Reyes Martinez ,  Fernando Alvarez Ramirez ,  Arquimedes Estrada Martinez ,  Flavio Salvador Vazquez Moreno

IPC: C08G81/00 ,  C08L71/02 ,  C08G65/333 ,  C08G65/334 ,  C08G65/08

Abstract: A chemical synthesis process is provided for the functionalization of monodispersed triblock copolymer (POEw-POPy-POEw) with secondary or tertiary amines at a semi-industrial level in glass reactors having a capacity between 1 L and 100 L. The process includes two stages where the first stage uses an alkylsulfonyl or arylsulfonyl chloride to obtain better leaving groups, and the second stage is the nucleophilic substitution with secondary or tertiary amines, to obtain the bifunctionalized triblock copolymers. The main advantage for this process is to reduce the quantity of unitary process done in each stage, the optimization of reaction times, and the stoichiometric relationships.

公开(公告)号：US10167249B2

公开(公告)日：2019-01-01

申请号：US14563234

申请日：2014-12-08

Applicant: INSTITUTO MEXICANO DEL PETROLEO

Inventor： Raul Hernandez Altamirano ,  Luis Silvestre Zamudio Rivera ,  Violeta Yasmin Mena Cervantes ,  Hiram Isaac Beltran Conde ,  Marco Antonio Dominguez Aguilar ,  Jaquelin Martinez Viramontes ,  Aristeo Estrada Buendia

IPC: C07C227/10 ,  C07C227/16 ,  C07C227/26 ,  C07C229/16 ,  C23F11/14 ,  C10L1/222 ,  C10L1/223 ,  C10L10/04 ,  C07C229/12 ,  C07C229/24 ,  C09K15/20 ,  C10L1/14 ,  C10L1/16 ,  C10L1/182 ,  C10L1/198

Abstract: N-alkyl, N-alkenyl, N-cycloalkyl, N-aryl amino or imino propionic acids with an alkyl chain ranging from 6 to 18 carbons, or alkenyl chain from 8 to 30 carbons, are obtained from a reaction process in the absence of solvent at a temperature range from 30 to 180° C. and a time of 1 to 10 hours at atmospheric pressure. Formulations composed of N-alkyl or N-alkenyl or N-cycloalkyl or N-aryl amino or imino propionic acids, polyethers derived from propylene oxide or ethylene oxide or copolymer thereof and a solvent consisting of aromatic compounds such as toluene or xylene, diesel or gasoline or alcohols such as isopropanol and ethanol, or mixtures thereof, are obtained inhibit ferrous metal corrosion of pipelines and storage tanks and transport crude oil and liquid fuels. A method inhibiting corrosion of ferrous metals adds an effective amount of the corrosion inhibitor to a petroleum based material such as crude oil and liquid fuels such as gasoline, diesel fuel, and aviation fuel.

公开(公告)号：US20150089861A1

公开(公告)日：2015-04-02

申请号：US14563234

申请日：2014-12-08

Applicant: INSTITUTO MEXICANO DEL PETROLEO

Inventor： Raul Hernandez Altamirano ,  Luis Silvestre Zamudio Rivera ,  Violeta Yasmin Mena Cervantes ,  Hiram Isaac Beltran Conde ,  Marco Antonio Dominguez Aguilar ,  Jaquelin Martinez Viramontes ,  Aristeo Estrada Buendia

IPC: C10L10/04 ,  C09K15/20 ,  C07C227/10 ,  C07C229/12 ,  C10L1/222 ,  C07C229/24

CPC classification number: C07C227/16 ,  C07C227/10 ,  C07C227/26 ,  C07C229/12 ,  C07C229/16 ,  C07C229/24 ,  C09K15/20 ,  C10L1/143 ,  C10L1/1608 ,  C10L1/1616 ,  C10L1/1824 ,  C10L1/1985 ,  C10L1/2222 ,  C10L1/223 ,  C10L10/04 ,  C10L2200/0259 ,  C10L2200/0423 ,  C10L2200/043 ,  C10L2200/0446 ,  C10L2230/14 ,  C10L2270/023 ,  C10L2270/026 ,  C10L2270/04 ,  C10L2270/10 ,  C10L2300/20 ,  C23F11/143

Abstract: N-alkyl, N-alkenyl, N-cycloalkyl, N-aryl amino or imino propionic acids with an alkyl chain ranging from 6 to 18 carbons, or alkenyl chain from 8 to 30 carbons, are obtained from a reaction process in the absence of solvent at a temperature range from 30 to 180° C. and a time of 1 to 10 hours at atmospheric pressure. Formulations composed of N-alkyl or N-alkenyl or N-cycloalkyl or N-aryl amino or imino propionic acids, polyethers derived from propylene oxide or ethylene oxide or copolymer thereof and a solvent consisting of aromatic compounds such as toluene or xylene, diesel or gasoline or alcohols such as isopropanol and ethanol, or mixtures thereof, are obtained inhibit ferrous metal corrosion of pipelines and storage tanks and transport crude oil and liquid fuels. A method inhibiting corrosion of ferrous metals adds an effective amount of the corrosion inhibitor to a petroleum based material such as crude oil and liquid fuels such as gasoline, diesel fuel, and aviation fuel.

公开(公告)号：US09518231B2

公开(公告)日：2016-12-13

申请号：US14338941

申请日：2014-07-23

Applicant: INSTITUTO MEXICANO DEL PETROLEO

Inventor： Gabriel Cendejas Santana ,  Eugenio Alejandro Flores Oropeza ,  Laura Veronica Castro Sotelo ,  Aristeo Estrada Buendia ,  Marcelo Lozada y Cassou ,  Flavio Salvador Vazquez Moreno

IPC: C07C213/00 ,  C07D295/00 ,  C10G33/04 ,  C08G65/333 ,  C08L71/02 ,  C08G65/26 ,  B01D17/05

CPC classification number: C10G33/04 ,  C08G65/2624 ,  C08G65/2627 ,  C08G65/263 ,  C08G65/33306 ,  C08G65/33317 ,  C08G2650/50 ,  C08G2650/58 ,  C08L71/02

Abstract: The present invention relates to demulsifying and dehydrating formulations of heavy crude oil based block copolymers amine bifunctionalized with low polydispersities. These formulations can contain solvents whose boiling point is in the range from 35 to 200° C., preferably: dichloromethane, chloroform, toluene, xylenes, turbosine, naphtha or mixtures thereof.

Abstract translation: 本发明涉及以低多分散性双功能化的重质原油基嵌段共聚物胺的破乳和脱水配方。 这些制剂可以含有沸点在35-200℃的溶剂，优选二氯甲烷，氯仿，甲苯，二甲苯，铀，石脑油或其混合物。

公开(公告)号：US20150112096A1

公开(公告)日：2015-04-23

申请号：US14581778

申请日：2014-12-23

Applicant: INSTITUTO MEXICANO DEL PETROLEO

Inventor： Raul Hernandez Altamirano ,  Luis Silvestre Zamudio Rivera ,  Violeta Yasmin Mena Cervantes ,  Hiram Isaac Beltran Conde ,  Marco Antonio Dominguez Aguilar ,  Jaquelin Martinez Viramontes ,  Aristeo Estrada Buendia

IPC: C07C227/16

CPC classification number: C07C227/16 ,  C07C227/10 ,  C07C227/26 ,  C07C229/12 ,  C07C229/16 ,  C07C229/24 ,  C09K15/20 ,  C10L1/143 ,  C10L1/1608 ,  C10L1/1616 ,  C10L1/1824 ,  C10L1/1985 ,  C10L1/2222 ,  C10L1/223 ,  C10L10/04 ,  C10L2200/0259 ,  C10L2200/0423 ,  C10L2200/043 ,  C10L2200/0446 ,  C10L2230/14 ,  C10L2270/023 ,  C10L2270/026 ,  C10L2270/04 ,  C10L2270/10 ,  C10L2300/20 ,  C23F11/143

Abstract: N-alkyl, N-alkenyl, N-cycloalkyl, N-aryl amino or imino propionic acids with an alkyl chain ranging from 6 to 18 carbons, or alkenyl chain from 8 to 30 carbons, are obtained from a reaction process in the absence of solvent at a temperature range from 30 to 180° C. and a time of 1 to 10 hours at atmospheric pressure. Formulations composed of N-alkyl or N-alkenyl or N-cycloalkyl or N-aryl amino or imino propionic acids, polyethers derived from propylene oxide or ethylene oxide or copolymer thereof and a solvent consisting of aromatic compounds such as toluene or xylene, diesel or gasoline or alcohols such as isopropanol and ethanol, or mixtures thereof, are obtained inhibit ferrous metal corrosion of pipelines and storage tanks and transport crude oil and liquid fuels. A method inhibiting corrosion of ferrous metals adds an effective amount of the corrosion inhibitor to a petroleum based material such as crude oil and liquid fuels such as gasoline, diesel fuel, and aviation fuel.

Abstract translation: 具有6至18个碳原子的烷基链或8至30个碳的链烯基链的N-烷基，N-烯基，N-环烷基，N-芳基氨基或亚氨基丙酸得自不存在 溶剂，在大气压下在30至180℃的温度和1至10小时的时间内进行。 由N-烷基或N-烯基或N-环烷基或N-芳基氨基或亚氨基丙酸组成的制剂，衍生自环氧丙烷或环氧乙烷的聚醚或其共聚物，以及由芳族化合物如甲苯或二甲苯，柴油或 获得汽油或醇，例如异丙醇和乙醇，或其混合物，从而抑制管线和储罐的黑色金属腐蚀并运输原油和液体燃料。 一种抑制黑色金属腐蚀的方法，对石油类材料如汽油，柴油和航空燃料等原油和液体燃料，增加了有效量的缓蚀剂。

公开(公告)号：US20140336285A1

公开(公告)日：2014-11-13

申请号：US14338941

申请日：2014-07-23

Applicant: INSTITUTO MEXICANO DEL PETROLEO

Inventor： Gabriel Cendejas Santana ,  Eugenio Alejandro Flores Oropeza ,  Laura Veronica Castro Sotelo ,  Aristeo Estrada Buendia ,  Marcelo Lozada y Cassou ,  Flavio Salvador Vazquez Moreno

IPC: C10G33/04 ,  C08G65/26

CPC classification number: C10G33/04 ,  C08G65/2624 ,  C08G65/2627 ,  C08G65/263 ,  C08G65/33306 ,  C08G65/33317 ,  C08G2650/50 ,  C08G2650/58 ,  C08L71/02

Abstract: The present invention relates to demulsifying and dehydrating formulations of heavy crude oil based block copolymers amine bifunctionalized with low polydispersities. These formulations can contain solvents whose boiling point is in the range from 35 to 200° C., preferably: dichloromethane, chloroform, toluene, xylenes, turbosine, naphtha or mixtures thereof

Abstract translation: 本发明涉及以低多分散性双功能化的重质原油基嵌段共聚物胺的破乳和脱水配方。 这些制剂可以含有沸点在35-200℃的溶剂，优选二氯甲烷，氯仿，甲苯，二甲苯，湍流，石脑油或其混合物