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公开(公告)号：US09321676B2
公开(公告)日：2016-04-26
申请号：US14702284
申请日：2015-05-01
Applicant: Intermolecular Inc. , Guardian Industries Corp.
Inventor： Mohd Fadzli Anwar Hassan , Brent Boyce , Guowen Ding , Muhammad Imran , Minh Huu Le , Zhi-Wen Wen Sun , Yu Wang , Yongli Xu
CPC classification number: C03C17/23 , C03C17/06 , C03C17/34 , C03C17/36 , C03C17/3626 , C03C17/3644 , C03C17/366 , C03C2217/211 , C03C2217/24 , C30B23/00 , C30B25/00 , G02B5/208 , G02B5/285 , Y10T428/24868 , Y10T428/24975 , Y10T428/265
Abstract: A bi-layer seed layer can exhibit good seed property for an infrared reflective layer, together with improved thermal stability. The bi-layer seed layer can include a thin zinc oxide layer having a desired crystallographic orientation for a silver infrared reflective layer disposed on a bottom layer having a desired thermal stability. The thermal stable layer can include aluminum, magnesium, or bismuth doped tin oxide (AlSnO, MgSnO, or BiSnO), which can have better thermal stability than zinc oxide but poorer lattice matching for serving as a seed layer template for silver (111).
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公开(公告)号：US09296651B2
公开(公告)日：2016-03-29
申请号：US14299341
申请日：2014-06-09
Inventor： Mohd Fadzli Anwar Hassan , Richard Blacker , Guowen Ding , Muhammad Imran , Jingyu Lao , Minh Huu Le , Yiwei Lu , Zhi-Wen Wen Sun
CPC classification number: C03C17/366 , C03C17/2453 , C03C17/36 , C03C17/3618 , C03C17/3642 , C23C14/08 , C23C28/32 , C23C28/345 , H01B3/10
Abstract: A transparent dielectric composition comprising tin, oxygen and one of aluminum or magnesium with preferably higher than 15% by weight of aluminum or magnesium offers improved thermal stability over tin oxide with respect to appearance and optical properties under high temperature processes. For example, upon a heat treatment at temperatures higher than 500 C, changes in color and index of refraction of the present transparent dielectric composition are noticeably less than those of tin oxide films of comparable thickness. The transparent dielectric composition can be used in high transmittance, low emissivity coated panels, providing thermal stability so that there are no significant changes in the coating optical and structural properties, such as visible transmission, IR reflectance, microscopic morphological properties, color appearance, and haze characteristics, of the as-coated and heated treated products.
Abstract translation: 包含锡，氧和铝或镁中的一种优选高于15重量％的铝或镁的透明电介质组合物相对于在高温过程下的外观和光学性质提供了比氧化锡更好的热稳定性。 例如，当在高于500℃的温度下进行热处理时，本发明透明电介质组合物的颜色变化和折射率显着小于具有相当厚度的氧化锡膜的变化。 透明电介质组合物可用于高透光率，低发射率涂层面板，提供热稳定性，使得涂层的光学和结构性能如可见透射率，IR反射率，微观形态特性，颜色外观和 涂层和加热处理产品的雾度特性。
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公开(公告)号：US09703024B2
公开(公告)日：2017-07-11
申请号：US15346884
申请日：2016-11-09
Applicant: Intermolecular Inc. , Guardian Industries Corp.
Inventor： Guizhen Zhang , Brent Boyce , Jeremy Cheng , Guowen Ding , Muhammad Imran , Daniel Schweigert , Yongli Xu
CPC classification number: G02B5/208 , B29D11/00865 , C03C17/36 , C03C17/3626 , C03C17/3639 , C03C17/3644 , C03C17/366 , C03C17/3681 , C03C23/007 , C03C2217/43 , C03C2217/48 , C03C2218/154 , C23C14/083 , C23C14/085 , C23C14/14 , C23C14/22 , E06B9/24 , E06B2009/2417 , E06B2009/2464 , G02B5/26 , G02F1/091 , G02F2001/094 , Y10T428/24975 , Y10T428/265
Abstract: Disclosed herein are systems, methods, and apparatus for forming low emissivity panels that may include a substrate and a reflective layer formed over the substrate. The low emissivity panels may further include a top dielectric layer formed over the reflective layer such that the reflective layer is formed between the top dielectric layer and the substrate. The top dielectric layer may include a ternary metal oxide, such as zinc tin aluminum oxide. The top dielectric layer may also include aluminum. The concentration of aluminum may be between about 1 atomic % and 15 atomic % or between about 2 atomic % and 10 atomic %. An atomic ratio of zinc to tin in the top dielectric layer may be between about 0.67 and about 1.5 or between about 0.9 and about 1.1.
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4.发明授权Systems, methods, and apparatus for production coatings of low-emissivity glass including a ternary alloy 有权包括三元合金在内的低辐射玻璃生产涂料的系统，方法和装置公开(公告)号：US09499899B2
公开(公告)日：2016-11-22
申请号：US14139350
申请日：2013-12-23
Applicant: INTERMOLECULAR INC. , Guardian Industries Corp.
Inventor： Guizhen Zhang , Brent Boyce , Jeremy Cheng , Guowen Ding , Muhammad Imran , Minh Huu Le , Daniel Schweigert , Yongli Xu
CPC classification number: G02B5/208 , B29D11/00865 , C03C17/36 , C03C17/3626 , C03C17/3639 , C03C17/3644 , C03C17/366 , C03C17/3681 , C03C23/007 , C03C2217/43 , C03C2217/48 , C03C2218/154 , C23C14/083 , C23C14/085 , C23C14/14 , C23C14/22 , E06B9/24 , E06B2009/2417 , E06B2009/2464 , G02B5/26 , G02F1/091 , G02F2001/094 , Y10T428/24975 , Y10T428/265
Abstract: Disclosed herein are systems, methods, and apparatus for forming low emissivity panels that may include a substrate and a reflective layer formed over the substrate. The low emissivity panels may further include a top dielectric layer formed over the reflective layer such that the reflective layer is formed between the top dielectric layer and the substrate. The top dielectric layer may include a ternary metal oxide, such as zinc tin aluminum oxide. The top dielectric layer may also include aluminum. The concentration of aluminum may be between about 1 atomic % and 15 atomic % or between about 2 atomic % and 10 atomic %. An atomic ratio of zinc to tin in the top dielectric layer may be between about 0.67 and about 1.5 or between about 0.9 and about 1.1.
Abstract translation: 本文公开了用于形成低辐射率面板的系统，方法和装置，其可以包括衬底和形成在衬底上的反射层。 低发射率面板还可以包括在反射层上形成的顶部电介质层，使得反射层形成在顶部电介质层和衬底之间。 顶部介电层可以包括三元金属氧化物，例如锌锡氧化铝。 顶部电介质层也可以包括铝。 铝的浓度可以在约1原子％至15原子％之间或约2原子％至10原子％之间。 顶部电介质层中锌与锡的原子比可以在约0.67至约1.5之间或约0.9至约1.1之间。
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5.发明授权Base-layer consisting of two materials layer with extreme high/low index in low-e coating to improve the neutral color and transmittance performance 有权基层由低e涂层中具有极高/低折射率的两层材料层组成，以改善中性色和透光性能公开(公告)号：US09365450B2
公开(公告)日：2016-06-14
申请号：US13728042
申请日：2012-12-27
Applicant: Intermolecular Inc. , Guardian Industries Corp.
Inventor： Guowen Ding , Brent Boyce , Muhammad Imran , Minh Huu Le , Zhi-Wen Sun , Yu Wang , Yongli Xu
IPC: C03C17/36
CPC classification number: C03C17/36 , C03C17/3618 , C03C17/3644 , C03C17/366 , C03C17/3681 , C03C2217/734 , Y10T428/24975
Abstract: Low emissivity coated panels can be fabricated using a base layer having a low refractive index layer on a high refractive index layer. The low refractive index layer can have refractive index less than 1.5, and can include MgF2, CaF2, SiO2, or BO. The high refractive index layer can have refractive index greater than 2.3, and can include TiOx, NbOx, or BiOx. The multilayer base structure can allow color tuning with enhanced transmission, for example, as compared to similar structures having single layer base layer.
Abstract translation: 可以使用在高折射率层上具有低折射率层的基底层来制造低发射率涂层面板。 低折射率层可以具有小于1.5的折射率，并且可以包括MgF 2，CaF 2，SiO 2或BO。 高折射率层可以具有大于2.3的折射率，并且可以包括TiO x，NbO x或BiO x。 与具有单层基底层的类似结构相比，多层基底结构可以允许具有增强的透射率的颜色调节。
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Patent Agency Ranking
公开(公告)号：US20140287254A1
公开(公告)日：2014-09-25
申请号：US14299341
申请日：2014-06-09
Inventor： Mohd Fadzli Anwar Hassan , Richard Blacker , Guowen Ding , Muhammad Imran , Jingyu Lao , Minh Huu Le , Yiwei Lu , Zhi-Wen Wen Sun
CPC classification number: C03C17/366 , C03C17/2453 , C03C17/36 , C03C17/3618 , C03C17/3642 , C23C14/08 , C23C28/32 , C23C28/345 , H01B3/10
Abstract: A transparent dielectric composition comprising tin, oxygen and one of aluminum or magnesium with preferably higher than 15% by weight of aluminum or magnesium offers improved thermal stability over tin oxide with respect to appearance and optical properties under high temperature processes. For example, upon a heat treatment at temperatures higher than 500 C, changes in color and index of refraction of the present transparent dielectric composition are noticeably less than those of tin oxide films of comparable thickness. The transparent dielectric composition can be used in high transmittance, low emissivity coated panels, providing thermal stability so that there are no significant changes in the coating optical and structural properties, such as visible transmission, IR reflectance, microscopic morphological properties, color appearance, and haze characteristics, of the as-coated and heated treated products.
Abstract translation: 包含锡，氧和铝或镁中的一种优选高于15重量％的铝或镁的透明电介质组合物相对于在高温过程下的外观和光学性质提供了比氧化锡更好的热稳定性。 例如，当在高于500℃的温度下进行热处理时，本发明透明电介质组合物的颜色变化和折射率显着小于具有相当厚度的氧化锡膜的变化。 透明电介质组合物可用于高透光率，低发射率涂层面板，提供热稳定性，使得涂层的光学和结构性能如可见透射率，IR反射率，微观形态特性，颜色外观和 涂层和加热处理产品的雾度特性。
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7.发明授权Barrier layers comprising Ni-inclusive alloys and/or other metallic alloys, double barrier layers, coated articles including double barrier layers, and methods of making the same 有权包含Ni的合金和/或其它金属合金的阻挡层，双阻挡层，包括双重阻挡层的涂覆制品及其制造方法公开(公告)号：US09556067B2
公开(公告)日：2017-01-31
申请号：US15093939
申请日：2016-04-08
Applicant: Guardian Industries Corp.
Inventor： Muhammad Imran , Bernd Disteldorf , Marcus Frank , Richard Blacker
IPC: B32B17/06 , B32B15/04 , C03C17/36 , E06B3/673 , E06B3/66 , G02B5/08 , E06B3/663 , E06B9/24 , G02B5/20 , C22C19/05
CPC classification number: C03C17/3642 , C03C17/36 , C03C17/3618 , C03C17/3626 , C03C17/3639 , C03C17/3644 , C03C17/3649 , C03C17/3652 , C03C17/366 , C03C17/3681 , C03C2217/22 , C03C2217/256 , C03C2217/261 , C03C2217/281 , C03C2217/73 , C03C2218/154 , C22C19/055 , C22C19/056 , C22C19/057 , E06B3/66 , E06B3/6612 , E06B3/663 , E06B3/67 , E06B3/673 , E06B9/24 , E06B2009/2417 , G02B5/0808 , G02B5/208 , Y10T29/49826 , Y10T428/12549
Abstract: Certain example embodiments relate to Ni-inclusive ternary alloy being provided as a barrier layer for protecting an IR reflecting layer comprising silver or the like. The provision of a barrier layer comprising nickel, chromium, and/or molybdenum and/or oxides thereof may improve corrosion resistance, as well as chemical and mechanical durability. In certain examples, more than one barrier layer may be used on at least one side of the layer comprising silver. In still further examples, a NixCryMoz-based layer may be used as the functional layer, rather than or in addition to as a barrier layer, in a coating.
Abstract translation: 一些示例性实施方案涉及提供作为用于保护包含银等的IR反射层的阻挡层的Ni包覆三元合金。 提供包含镍，铬和/或钼和/或其氧化物的阻挡层可提高耐腐蚀性以及化学和机械耐久性。 在某些实施例中，可以在包含银的层的至少一侧上使用多于一个的阻挡层。 在另外的实例中，NixCryMoz基层可以用作功能层，而不是或作为阻挡层添加到涂层中。
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公开(公告)号：US09499437B2
公开(公告)日：2016-11-22
申请号：US14690557
申请日：2015-04-20
Applicant: Guardian Industries Corp.
Inventor： Muhammad Imran , Francis Wuillaume , Brent Boyce
CPC classification number: C03C17/3607 , C03C17/36 , C03C17/3618 , C03C17/3626 , C03C17/3639 , C03C17/3642 , C03C17/3644 , C03C17/3652 , C03C17/366 , C03C17/3681 , C03C2217/78 , C03C2218/322 , Y10T428/12549 , Y10T428/265 , Y10T428/31678
Abstract: A coated article is provided so as to include a low-E (low emissivity) coating having an infrared (IR) reflecting layer(s) of or including a material such as silver (Ag), which is provided between a pair of contact layers. The low-E coating includes an overcoat having at least one layer of or including zirconium oxide and/or a substantially metallic layer. The overcoat has been found to improve the durability of the coating without significantly sacrificing desired optical characteristics. Such coated articles may be used in the context of windows.
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9.发明授权Coated article with low-E coating including tin oxide inclusive layer(s) with additional metal(s) 有权具有低E涂层的涂层制品，包括含有金属的附加金属氧化锡层，公开(公告)号：US09028983B2
公开(公告)日：2015-05-12
申请号：US14538869
申请日：2014-11-12
Applicant: Guardian Industries Corp.
Inventor： Muhammad Imran , Brent Boyce , Jean-Marc Lemmer , Marcus Frank , Yongli Xu
CPC classification number: C03C17/3618 , C03C17/3417 , C03C17/3429 , C03C17/3435 , C03C17/3626 , C03C17/3639 , C03C17/3642 , C03C17/3644 , C03C17/3652 , C03C17/366 , C03C17/3681 , C03C17/3689 , C03C2217/211 , C03C2217/216 , C03C2217/219 , C03C2217/23 , C03C2217/256
Abstract: A coated article includes a coating, such as a low emissivity (low-E) coating, supported by a substrate (e.g., glass substrate). The coating includes at least one dielectric layer including tin oxide that is doped with another metal(s). The coating may also include one or more infrared (IR) reflecting layer(s) of or including material such as silver or the like, for reflecting at least some IR radiation. In certain example embodiments, the coated article may be heat treated (e.g., thermally tempered, heat bent and/or heat strengthened). Coated articles according to certain example embodiments of this invention may be used in the context of windows, including monolithic windows for buildings, IG windows for buildings, etc.
Abstract translation: 涂覆制品包括由衬底（例如玻璃衬底）支撑的涂层，例如低发射率（低E）涂层。 该涂层包括至少一个包含掺杂有另一种金属的氧化锡的电介质层。 涂层还可以包括用于反射至少一些IR辐射的一种或多种红外（IR）反射层或者包括诸如银等的材料。 在某些示例性实施例中，涂覆的制品可以被热处理（例如热回火，热弯曲和/或热加强）。 根据本发明的某些示例性实施例的涂层制品可以在窗户的上下文中使用，包括建筑物的整体窗口，建筑物的IG窗口等。
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公开(公告)号：US08916235B2
公开(公告)日：2014-12-23
申请号：US13736330
申请日：2013-01-08
Applicant: Guardian Industries Corp.
Inventor： Muhammad Imran , Bernd Disteldorf , Marcus Frank , Richard Blacker
CPC classification number: C03C17/3435 , C03C17/06 , C03C17/36 , C03C17/3602 , C03C17/3626 , C03C17/3649 , C03C17/3652 , C03C17/366 , C03C17/3681 , Y10T156/10 , Y10T428/12549
Abstract: Certain example embodiments relate to Ni-inclusive ternary alloy being provided as a barrier layer for protecting an IR reflecting layer comprising silver or the like. The provision of a barrier layer comprising nickel, chromium, and/or molybdenum and/or oxides thereof may improve corrosion resistance, as well as chemical and mechanical durability. In certain examples, more than one barrier layer may be used on at least one side of the layer comprising silver. In still further examples, a NixCryMoz-based layer may be used as the functional layer, rather than or in addition to as a barrier layer, in a coating.
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