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公开(公告)号：US3988267A
公开(公告)日：1976-10-26
申请号：US497194
申请日：1974-08-14
CPC分类号： C08G18/791 , C08G18/1875 , C08G2105/02 , Y10S521/902 , Y10S521/904
摘要： Catalysts having the following formula have been found to have unexpectedly high activity for the production of polyurethane and polyisocyanate resins: ##EQU1## where: R, R.sub.1 and R.sub.2 are alkyls having one to four carbon atoms,R.sub.3 and R.sub.4 are independently selected from the group consisting of H, alkyls having one to 12 carbon atoms and aryls and aralkyls having six to 18 carbon atoms, andR.sub.5 is selected from the group consisting of H, an alkyl having one to two carbon atoms and an aryl and an aralkyl having six to 15 carbon atoms.
摘要翻译： 已经发现具有下列结构式的催化剂对聚氨酯和多异氰酸酯树脂的生产具有出人意料的高活性：RR 3 + | R 1 -N-CH 2 -COROR 5 - || R 2 R 4其中：
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公开(公告)号：US4116879A
公开(公告)日：1978-09-26
申请号：US713307
申请日：1976-08-10
CPC分类号： C08G18/1875 , B01J31/08 , B01J31/0239 , C08G2105/02 , Y10S521/902 , Y10S521/904
摘要： Catalysts having the following formula have been found to have unexpectedly high activity for the production of polyurethane and polyisocyanate resins: ##STR1## where: R, R.sub.1 and R.sub.2 are alkyls having 1 to 4 carbon atoms,R.sub.3 and R.sub.4 are independently selected from the group consisting of H, alkyls having 1 to 12 carbon atoms and aryls and aralkyls having 6 to 18 carbon atoms, andR.sub.5 is selected from the group consisting of H, an alkyl having 1 to 2 carbon atoms and an aryl and an aralkyl having 6 to 15 carbon atoms.
摘要翻译： 已经发现具有以下配方的催化剂对于生产聚氨酯和多异氰酸酯树脂具有意想不到的高活性：其中：
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3.发明授权Cyclic quaternary hydroxyalkyl phenoxide catalysts for isocyanate reactions 失效用于异氰酸酯反应的环状季羟基烷基酚盐催化剂
公开(公告)号：US3993652A
公开(公告)日：1976-11-23
申请号：US490946
申请日：1974-07-23
IPC分类号： C08G18/18 , C08G18/20 , C07D295/08
CPC分类号： C08G18/2063 , C08G18/1875 , C08G18/20 , C08G2105/02 , Y10S521/902
摘要： Catalysts having the following formula, prepared in the absence of water, are stable to heat and storage and show high activity in reactions involving organic isocyanates, such as in the production of polyurethane and polyisocyanurate resins: ##EQU1## wherein: A is a mono- or bicyclic tertiary amine having at least 4 carbon atoms in an azine ring,R.sup.1 is H or an alkyl group of 1 to 10 carbon atoms,R.sup.2 is H or an alkyl or aryl group of 1 to 10 carbon atoms, and.phi. is a phenyl group, which may be further substituted by one or more hydroxyl or alkyl groups.Typical compounds, for example, are those corresponding to the formula ##EQU2## wherein: R is H or methyl.
摘要翻译： 在不存在水的情况下制备的具有下式的催化剂对于加热和储存是稳定的，并且在涉及有机异氰酸酯的反应中显示高活性，例如在聚氨酯和聚异氰脲酸酯树脂的生产中：OH |（A + CH- CH-R2）O - > phi | R1其中：
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公开(公告)号：US4225453A
公开(公告)日：1980-09-30
申请号：US921422
申请日：1978-07-03
IPC分类号： C08G18/00 , C08G18/18 , C08G18/28 , C08G18/50 , C08L7/00 , C08L21/00 , C08L67/00 , C08L75/00 , B01J27/02 , C08J9/02
CPC分类号： C08G18/28 , C08G18/5009
摘要： The storage stability of otherwise unstable premix compositions for flame retardant rigid polyurethane foams containing in the premix a chlorinated polyether polyol and a tertiary amine catalyst, is enhanced by incorporation into the premix a synergistic combination of an organic sulfur compound and an unsaturated carbon compound. The preferred sulfur compound is thiourea; among the preferred unsaturated carbon compounds are unsaturated terpenes such as allo-ocimene and unsaturated higher fatty acids such as tall oil fatty acids and mono-, di-, and trienic C.sub.18 acids.
摘要翻译： 通过将有机硫化合物和不饱和碳化合物的协同组合结合到预混物中，增强了预混合氯化聚醚多元醇和叔胺催化剂中含有的阻燃硬质聚氨酯泡沫的其它不稳定的预混物组合物的储存稳定性。 优选的硫化合物是硫脲; 在优选的不饱和碳化合物中，不饱和萜烯如异辛烯和不饱和高级脂肪酸如妥尔油脂肪酸和单 - ，二 - 和 - 三烯C 18酸。
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5.发明授权Use of antimony compounds to retard catalyst deactivation in foam-forming compositions containing aromatic polyester polyols 失效在含芳香族聚酯多元醇的泡沫形成组合物中使用锑化合物来阻止催化剂失活
公开(公告)号：US4761433A
公开(公告)日：1988-08-02
申请号：US128853
申请日：1987-12-04
申请人： John R. Panchak , John M. Trowell
发明人： John R. Panchak , John M. Trowell
CPC分类号： C08G18/163 , C08G18/28 , C08G18/4208 , C08G2101/0025 , C08G2170/60
摘要： Organic antimony compounds can be used to retard deactivation of urethane catalysts during storage of a B side formulation containing aromatic polyester polyols, used in the manufacture of rigid polyurethane foams.
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公开(公告)号：US4239642A
公开(公告)日：1980-12-16
申请号：US53441
申请日：1979-06-29
申请人： Harry V. DePaul , John R. Panchak
发明人： Harry V. DePaul , John R. Panchak
CPC分类号： C08J9/0014 , C08G18/18 , C08G18/28 , C08G18/5006 , C08J2375/04
摘要： The storage stability of otherwise unstable premix compositions for flame retardant rigid polyurethane foams containing in the premix a chlorinated polyether polyol and a tertiary amine catalyst, is enhanced by incorporation into the premix of a minor amount of a vinyl monomer. The preferred vinyl monomers employed are condensation products of acrylic or methacrylic acid with alcohols or amines. Such stabilization prevents premature deactivation of the tertiary amine catalysts contained in the premix.
摘要翻译： 在预混合氯化聚醚多元醇和叔胺催化剂中含有的阻燃硬质聚氨酯泡沫塑料的其它不稳定的预混物组合物的储存稳定性通过掺入少量乙烯基单体的预混物而增强。 所用的优选的乙烯基单体是丙烯酸或甲基丙烯酸与醇或胺的缩合产物。 这种稳定化防止预混物中所含的叔胺催化剂的过早失活。
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