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    Flame retardant
    4.
    发明授权
    Flame retardant 有权
    不易燃的

    公开(公告)号：US09115312B2

    公开(公告)日：2015-08-25

    申请号：US13075518

    申请日：2011-03-30

    申请人： Klaus Hahn ,  Sabine Fuchs ,  Ingo Bellin ,  Patrick Spies ,  Maximilian Hofmann ,  Peter Deglmann ,  Klemens Massonne ,  Hartmut Denecke ,  Christoph Fleckenstein ,  Geert Janssens ,  Manfred Döring ,  Michael Ciesielski ,  Jochen Wagner

    发明人： Klaus Hahn ,  Sabine Fuchs ,  Ingo Bellin ,  Patrick Spies ,  Maximilian Hofmann ,  Peter Deglmann ,  Klemens Massonne ,  Hartmut Denecke ,  Christoph Fleckenstein ,  Geert Janssens ,  Manfred Döring ,  Michael Ciesielski ,  Jochen Wagner

    IPC分类号： C08J9/00 ,  C08K5/36 ,  C09K21/12 ,  C08K5/49

    CPC分类号： C09K21/12 ,  C08J9/0033 ,  C08J2325/06 ,  C08K5/36 ,  C08K5/49

    摘要： A flame retardant comprising a) at least one sulfur compound of the formula (I) A1-(Z1)m—(S)n—(Z2)p-A2  (I) where the definitions of the symbols and indices are as follows: A1 and A2 are identical or different, being C6-C12-aryl, cyclohexyl, Si(ORa)3, a saturated, partially unsaturated, or aromatic, mono- or bicyclic ring having from 3 to 12 ring members and comprising one or more heteroatoms from the group of N, O, and S, where the system is unsubstituted or has substitution by one or more substituents of the group of O, OH, S, SH, COORb, CONRcRd, C1-C18-alkyl, C1-C18-alkoxy, C1-C18-thioalkyl, C6-C12-aryl, C6-C12-aryloxy, C2-C18-alkenyl, C2-C18-alkenoxy, C2-C18-alkynyl, and C2-C18-alkinoxy; Z1 and Z2 are identical or different, being —CO— or —CS—; Ra is C1-C18-alkyl; Rb, Rc, and Rd are identical or different, being H, C1-C18-alkyl, C6-C12-aryl, or an aromatic, mono- or bicyclic ring having from 3 to 12 ring members and comprising one or more heteroatoms from the group of N, O, and S; m and p are identical or different, being 0 or 1, and n is a natural number from 2 to 10, and b) at least one halogen-free organophosphorus compound having phosphorus content in the range from 5 to 80% by weight, based on the phosphorus compound, is particularly suitable for protecting foams based on styrene polymers.

    摘要翻译： 一种阻燃剂，其包含a）至少一种式（I）A1-（Z1）m-（S）n-（Z2）p-A2（I）的硫化合物，其中符号和指数的定义如下： A1和A2相同或不同，为具有3至12个环成员且包含一个或多个杂原子的饱和，部分不饱和或芳族单环或双环的C 6 -C 12 - 芳基，环己基，Si（OR a）3 由N，O和S的基团组成，其中体系未被取代或被一个或多个O，OH，S，SH，COORb，CONRcRd，C 1 -C 18烷基，C 1 -C 18 - 烷氧基，C 1 -C 18 - 硫代烷基，C 6 -C 12 - 芳基，C 6 -C 12 - 芳氧基，C 2 -C 18烯基，C 2 -C 18 - 烯氧基，C 2 -C 18炔基和C 2 -C 18 - 烷氧基; Z 1和Z 2相同或不同，为-CO-或-CS-; R a是C 1 -C 18 - 烷基; R b，R c和R d相同或不同，为H，C 1 -C 18 - 烷基，C 6 -C 12 - 芳基或具有3至12个环成员并且包含一个或多个来自 N，O，S组; m和p相同或不同，为0或1，n为2至10的自然数，b）至少一种磷含量为5-80重量％的无卤素有机磷化合物，基于 在磷化合物上，特别适用于保护基于苯乙烯聚合物的泡沫体。

    FLAME RETARDANTS
    5.
    发明申请
    FLAME RETARDANTS 审中-公开
    阻燃剂

    公开(公告)号：US20110196052A1

    公开(公告)日：2011-08-11

    申请号：US13022045

    申请日：2011-02-07

    申请人： Klaus Hahn ,  Olaf Kriha ,  Ingo Bellin ,  Patrick Spies ,  Sabine Fuchs ,  Peter Deglmann ,  Klemens Massonne ,  Hartmut Denecke ,  Christoph Fleckenstein ,  Geert Janssens ,  Maximilian Hofmann

    发明人： Klaus Hahn ,  Olaf Kriha ,  Ingo Bellin ,  Patrick Spies ,  Sabine Fuchs ,  Peter Deglmann ,  Klemens Massonne ,  Hartmut Denecke ,  Christoph Fleckenstein ,  Geert Janssens ,  Maximilian Hofmann

    IPC分类号： C08K5/5398 ,  C08L25/06 ,  C08J9/18 ,  C08J9/12

    CPC分类号： C08J9/0038 ,  C08J9/16 ,  C08J2325/04 ,  C08K5/5398 ,  C08L25/06

    摘要： Phosphine sulfide derivatives of the formula (I), S═PR1R2R3  (I) are suitable as flame retardants, in particular for polymers, where the definitions of the symbols in the formula (I) are as follows: R1 and R2 are identical or different, being C1-C12-alkyl, C3-C8-cycloalkyl, which may have no substitution or may have one or more C1-C4-alkyl groups as substituents, C2-C12-alkenyl, C2-C12-alkynyl, C6-C10-aryl, or C8-C10-aryl-C1-C4-alkyl; R3 is H, SH, SR4, OH, OR5 or a —(Y1)n—[P(═X1)R6—(Y2)n]m—P(═X2)R7R8 group; or two groups R1, R2, R3 form, together with the phosphorus atom bonded thereto, a ring system; X1 and X2 are identical or different, being O or S; Y1 and Y2 are identical or different, being O or S; R4, R5, R6, R7 and R8 are identical or different, being independently from one another C1-C12-alkyl, C3-C8-cycloalkyl, which may have no substitution or may have one or more C1-C4-alkyl groups as substituents, C2-C12-alkenyl, C2-C12-alkynyl, C6-C10-aryl, or C6-C10-aryl-C1-C4-alkyl; n is 1 if Y1 and, respectively, Y2 is O, and is 1, 2, 3, 4, 5, 6, 7, or 8 if Y1 and, respectively, Y2 is S, and m is an integer from 0 to 100.

    摘要翻译： 式（I）的硫化膦衍生物，S = PR1R2R3（I）适用作阻燃剂，特别是用于聚合物的阻燃剂，其中式（I）中符号的定义如下：R1和R2相同或不同 可以不具有取代基或可以具有一个或多个C 1 -C 4烷基作为取代基的C 1 -C 12 - 烷基，C 3 -C 8 - 环烷基，C 2 -C 12 - 烯基，C 2 -C 12炔基，C 6 -C 10 - 芳基或C 8 -C 10 - 芳基-C 1 -C 4 - 烷基; R3是H，SH，SR4，OH，OR5或 - （Y1）n- [P（= X1）R6-（Y2）n] m-P（= X2）R7R8组; 或两个基团R 1，R 2，R 3与键合的磷原子一起形成环系; X1和X2相同或不同，为O或S; Y1和Y2相同或不同，为O或S; R 4，R 5，R 6，R 7和R 8相同或不同，彼此独立地为可以不具有取代基或可以具有一个或多个C 1 -C 4 - 烷基作为取代基的C 1 -C 12 - 烷基，C 3 -C 8 - 环烷基 ，C 2 -C 12 - 烯基，C 2 -C 12 - 炔基，C 6 -C 10 - 芳基或C 6 -C 10 - 芳基-C 1 -C 4 - 烷基; 如果Y1和Y1分别为0，则n为1，如果Y1分别为Y2，并且分别为1,2,3,4,5,6,7或8，并且m分别为0至100的整数。 。

    FLAME RETARDANT
    6.
    发明申请
    FLAME RETARDANT 有权
    不易燃的

    公开(公告)号：US20110245360A1

    公开(公告)日：2011-10-06

    申请号：US13075518

    申请日：2011-03-30

    申请人： Klaus Hahn ,  Sabine Fuchs ,  Ingo Bellin ,  Patrick Spies ,  Maximilian Hofmann ,  Peter Deglmann ,  Klemens Massonne ,  Hartmut Denecke ,  Christoph Fleckenstein ,  Geert Janssens

    发明人： Klaus Hahn ,  Sabine Fuchs ,  Ingo Bellin ,  Patrick Spies ,  Maximilian Hofmann ,  Peter Deglmann ,  Klemens Massonne ,  Hartmut Denecke ,  Christoph Fleckenstein ,  Geert Janssens

    IPC分类号： C08J9/00 ,  C09K21/12 ,  C08K5/5313

    CPC分类号： C09K21/12 ,  C08J9/0033 ,  C08J2325/06 ,  C08K5/36 ,  C08K5/49

    摘要： A flame retardant comprising a) at least one sulfur compound of the formula (I) A1-(Z1)m—(S)n—(Z2)p-A2  (I) where the definitions of the symbols and indices are as follows: A1 and A2 are identical or different, being C6-C12-aryl, cyclohexyl, Si(ORa)3, a saturated, partially unsaturated, or aromatic, mono- or bicyclic ring having from 3 to 12 ring members and comprising one or more heteroatoms from the group of N, O, and S, where the system is unsubstituted or has substitution by one or more substituents of the group of O, OH, S, SH, COORb, CONRcRd, C1-C18-alkyl, C1-C18-alkoxy, C1-C18-thioalkyl, C6-C12-aryl, C6-C12-aryloxy, C2-C18-alkenyl, C2-C18-alkenoxy, C2-C18-alkynyl, and C2-C18-alkinoxy; Z1 and Z2 are identical or different, being —CO— or —CS—; Ra is C1-C18-alkyl; Rb, Rc, and Rd are identical or different, being H, C1-C18-alkyl, C6-C12-aryl, or an aromatic, mono- or bicyclic ring having from 3 to 12 ring members and comprising one or more heteroatoms from the group of N, O, and S; m and p are identical or different, being 0 or 1, and n is a natural number from 2 to 10, and b) at least one halogen-free organophosphorus compound having phosphorus content in the range from 5 to 80% by weight, based on the phosphorus compound, is particularly suitable for protecting foams based on styrene polymers.

    摘要翻译： 一种阻燃剂，其包含a）至少一种式（I）A1-（Z1）m-（S）n-（Z2）p-A2（I）的硫化合物，其中符号和指数的定义如下： A1和A2相同或不同，为具有3至12个环成员且包含一个或多个杂原子的饱和，部分不饱和或芳族单环或双环的C 6 -C 12 - 芳基，环己基，Si（OR a）3 由N，O和S的基团组成，其中体系未被取代或被一个或多个O，OH，S，SH，COORb，CONRcRd，C 1 -C 18烷基，C 1 -C 18 - 烷氧基，C 1 -C 18 - 硫代烷基，C 6 -C 12 - 芳基，C 6 -C 12 - 芳氧基，C 2 -C 18烯基，C 2 -C 18 - 烯氧基，C 2 -C 18炔基和C 2 -C 18 - 烷氧基; Z 1和Z 2相同或不同，为-CO-或-CS-; R a是C 1 -C 18 - 烷基; R b，R c和R d相同或不同，为H，C 1 -C 18 - 烷基，C 6 -C 12 - 芳基或具有3至12个环成员并且包含一个或多个来自 N，O，S组; m和p相同或不同，为0或1，n为2至10的自然数，b）至少一种磷含量为5-80重量％的无卤素有机磷化合物，基于 在磷化合物上，特别适用于保护基于苯乙烯聚合物的泡沫体。

    HALOGEN-FREE, FLAME-PROOF POLYMER FOAMS CONTAINING AT LEAST ONE OLIGOPHOSPHORUS COMPOUND
    8.
    发明申请
    HALOGEN-FREE, FLAME-PROOF POLYMER FOAMS CONTAINING AT LEAST ONE OLIGOPHOSPHORUS COMPOUND 审中-公开
    无卤素，含有至少一种寡糖化合物的防火聚合物

    公开(公告)号：US20120178842A1

    公开(公告)日：2012-07-12

    申请号：US13394348

    申请日：2010-09-10

    申请人： Klaus Hahn ,  Olaf Kriha ,  Ingo Bellin ,  Patrick Spies ,  Sabine Fuchs ,  Peter Deglmann ,  Klemens Massonne ,  Hartmut Denecke ,  Christoph Fleckenstein ,  Geert Janssens

    发明人： Klaus Hahn ,  Olaf Kriha ,  Ingo Bellin ,  Patrick Spies ,  Sabine Fuchs ,  Peter Deglmann ,  Klemens Massonne ,  Hartmut Denecke ,  Christoph Fleckenstein ,  Geert Janssens

    IPC分类号： C08K5/51 ,  D01D5/40

    CPC分类号： C08J9/0038 ,  C08J9/232 ,  C08J2325/04 ,  C08K5/50 ,  C09K21/12

    摘要： Halogen-free, flame-retardant polymer foams which comprise, as flame retardant, at least one cyclic or acyclic oligophosphorus compound, and processes for their production. Examples of suitable oligophosphorus compounds are those having the structure Ia, Ib, or Ic: Another group of suitable oligophosphorus compounds is that having one of the following structures IIa, IIb, or IIc: Cyclic oligophosphorus compounds of the following structure III are also suitable: The radicals R1-R5 have been selected independently of one another from the group of C1-C16-alkyl, C1-C16-alkenyl, C1-C16-alkoxy, C1-C16-alkenyloxy, C3-C10-cycloalkyl, C3-C10-cycloalkoxy, C6-C10-aryl, C6-C10-aryloxy, C6-C10-aryl-C1-C16-alkyl, C6-C10-aryl-C1-C16-alkoxy, NR2R3, COR2, COOR2, and CONR2R3 , and the radicals X1 and X2, independently of one another, are O or S.

    摘要翻译： 包含作为阻燃剂的至少一种环状或非环状低聚磷化合物的无卤阻燃聚合物泡沫及其制备方法。 合适的寡磷化合物的实例是具有结构Ia，Ib或Ic的那些：另一组合适的低聚磷化合物是具有以下结构IIa，IIb或IIc之一：以下结构III的环状低聚磷化合物也是合适的： 基团R1-R5彼此独立地选自C 1 -C 16 - 烷基，C 1 -C 16 - 烯基，C 1 -C 16 - 烷氧基，C 1 -C 16 - 烯氧基，C 3 -C 10 - 环烷基，C 3 -C 10 - 环烷氧基，C 6 -C 10 - 芳基，C 6 -C 10 - 芳氧基，C 6 -C 10 - 芳基-C 1 -C 16 - 烷基，C 6 -C 10 - 芳基-C 1 -C 16 - 烷氧基，NR 2 R 3，COR 2，COOR 2和CONR 2 R 3， X1和X2彼此独立地是O或S.

    FLAME RETARDANT
    9.
    发明申请
    FLAME RETARDANT 有权
    不易燃的

    公开(公告)号：US20120252911A1

    公开(公告)日：2012-10-04

    申请号：US13516464

    申请日：2010-12-15

    申请人： Christoph Fleckenstein ,  Hartmut Denecke ,  Ingo Bellin ,  Olaf Kriha ,  Patrick Spies ,  Sabine Fuchs ,  Klemens Massonne ,  Klaus Hahn ,  Peter Deglmann ,  Maximilian Hofmann ,  Alois Kindler

    发明人： Christoph Fleckenstein ,  Hartmut Denecke ,  Ingo Bellin ,  Olaf Kriha ,  Patrick Spies ,  Sabine Fuchs ,  Klemens Massonne ,  Klaus Hahn ,  Peter Deglmann ,  Maximilian Hofmann ,  Alois Kindler

    IPC分类号： C07F9/655 ,  C07F9/6561 ,  C08K5/1535 ,  B29B9/06 ,  C08J9/16

    CPC分类号： C09K21/12 ,  C08J9/0038 ,  C08J9/14 ,  C08J9/20 ,  C08J2325/04 ,  C08K5/49 ,  C08K5/523 ,  C08K5/53 ,  C08K5/5313 ,  C08K5/5377 ,  C08K5/5398 ,  C08L2201/02 ,  C08L2203/14 ,  C08L25/00 ,  C08L25/06

    摘要： Use of a phosphorus compound of the formula (I) as flame retardant, where the definitions of the symbols in the formula (I) are as follows: A is one of the following groups: Y is —P(═X2)SR3R4, H, a straight-chain or branched C1-C12-alkyl group, C5-C6-cycloalkyl, C6-C12-aryl, or benzyl, where the four last-mentioned groups are unsubstituted or have substitution by one or more radicals from the group of C1-C4-alkyl or C1-C4-alkenyl; R1, R2, R3, and R4 are identical or different and are hydrogen, OH, C1-C16-alkyl, C1-C16-alkenyl, C1-C16-alkoxy, C1-C16-alkenoxy, C3-C10-cycloalkyl, C3-C10-cycloalkoxy, C6-C10-aryl, C6-C10-aryloxy, C6-C10-aryl-C1-C16-alkyl, C6-C10-aryl-C1-C16-alkoxy, SR9 COR10, COOR11, CONR12R13 or two radicals R1, R2, R3, or R4 form, together with the phosphorus atom to which they are bonded, or the P—O-A-O—P group, a ring system; R5, R6, R7, and R8 are identical or different and are H, C1-C16-alkyl, C1-C16-alkenyl, C1-C16-alkoxy, C1-C16-alkenoxy; R9, R10, R11, R12, R13 are identical or different and are H, C1-C16-alkyl, C1-C16-alkenyl, C6-C10-aryl, C6-C10-aryl-C1-C16-alkyl, C6-C10-aryl-C1-C16-alkoxy; X1 and X2 are identical or different and are S or O; r and s are identical or different and are 0 or 1; X3, X4, X5, and X6 are identical or different and are S or O, and n is a natural number from 1 to 50.

    摘要翻译： 式（I）的磷化合物作为阻燃剂的用途，其中式（I）中的符号的定义如下：A是以下基团之一：Y是-P（= X 2）SR 3 R 4，H 直链或支链C 1 -C 12 - 烷基，C 5 -C 6 - 环烷基，C 6 -C 12 - 芳基或苄基，其中四个最后提到的基团是未取代的或具有一个或多个自由基 C 1 -C 4 - 烷基或C 1 -C 4 - 烯基; R1，R2，R3和R4相同或不同，为氢，OH，C1-C16 - 烷基，C1-C16 - 烯基，C1-C16 - 烷氧基，C1-C16 - 烯氧基，C3-C10-环烷基，C3- C 1 -C 10 - 芳基，C 6 -C 10 - 芳氧基，C 6 -C 10 - 芳基-C 1 -C 16 - 烷基，C 6 -C 10 - 芳基-C 1 -C 16 - 烷氧基，SR 9 COR 10，COOR 11，CONR 12 R 13或两个基团R 1 R 2，R 3或R 4与它们所键合的磷原子一起形成，或与P-OAO-P基团形成环系; R 5，R 6，R 7和R 8相同或不同，为H，C 1 -C 16 - 烷基，C 1 -C 16 - 烯基，C 1 -C 16 - 烷氧基，C 1 -C 16 - 烯氧基; R9，R10，R11，R12，R13相同或不同，为H，C1-C16 - 烷基，C1-C16 - 烯基，C6-C10-芳基，C6-C10-芳基-C1-C16 - 烷基，C6-C10 芳基-C 1 -C 16 - 烷氧基; X1和X2相同或不同，为S或O; r和s相同或不同，为0或1; X3，X4，X5和X6相同或不同，为S或O，n为1〜50的自然数。

    Flame retardant
    10.
    发明授权
    Flame retardant 有权
    不易燃的

    公开(公告)号：US09234137B2

    公开(公告)日：2016-01-12

    申请号：US13516464

    申请日：2010-12-15

    申请人： Christoph Fleckenstein ,  Hartmut Denecke ,  Ingo Bellin ,  Olaf Kriha ,  Patrick Spies ,  Sabine Fuchs ,  Klemens Massonne ,  Klaus Hahn ,  Peter Deglmann ,  Maximilian Hofmann ,  Alois Kindler

    发明人： Christoph Fleckenstein ,  Hartmut Denecke ,  Ingo Bellin ,  Olaf Kriha ,  Patrick Spies ,  Sabine Fuchs ,  Klemens Massonne ,  Klaus Hahn ,  Peter Deglmann ,  Maximilian Hofmann ,  Alois Kindler

    IPC分类号： C08J9/16 ,  C08K5/1535 ,  C09K21/12 ,  C08J9/00 ,  C08J9/14 ,  C08J9/20 ,  C08K5/49 ,  C08K5/53 ,  C08K5/523 ,  C08K5/5313 ,  C08K5/5377 ,  C08K5/5398

    CPC分类号： C09K21/12 ,  C08J9/0038 ,  C08J9/14 ,  C08J9/20 ,  C08J2325/04 ,  C08K5/49 ,  C08K5/523 ,  C08K5/53 ,  C08K5/5313 ,  C08K5/5377 ,  C08K5/5398 ,  C08L2201/02 ,  C08L2203/14 ,  C08L25/00 ,  C08L25/06

    摘要： Use of a phosphorus compound of the formula (I) as flame retardant, where the definitions of the symbols in the formula (I) are as follows: A is one of the following groups: Y is —P(═X2)SR3R4, H, a straight-chain or branched C1-C12-alkyl group, C5-C6-cycloalkyl, C6-C12-aryl, or benzyl, where the four last-mentioned groups are unsubstituted or have substitution by one or more radicals from the group of C1-C4-alkyl or C1-C4-alkenyl; R1, R2, R3, and R4 are identical or different and are hydrogen, OH, C1-C16-alkyl, C1-C16-alkenyl, C1-C16-alkoxy, C1-C16-alkenoxy, C3-C10-cycloalkyl, C3-C10-cycloalkoxy, C6-C10-aryl, C6-C10-aryloxy, C6-C10-aryl-C1-C16-alkyl, C6-C10-aryl-C1-C16-alkoxy, SR9 COR10, COOR11, CONR12R13 or two radicals R1, R2, R3, or R4 form, together with the phosphorus atom to which they are bonded, or the P—O-A-O—P group, a ring system; R5, R6, R7, and R8 are identical or different and are H, C1-C16-alkyl, C1-C16-alkenyl, C1-C16-alkoxy, C1-C16-alkenoxy; R9, R10, R11, R12, R13 are identical or different and are H, C1-C16-alkyl, C1-C16-alkenyl, C6-C10-aryl, C6-C10-aryl-C1-C16-alkyl, C6-C10-aryl-C1-C16-alkoxy; X1 and X2 are identical or different and are S or O; r and s are identical or different and are 0 or 1; X3, X4, X5, and X6 are identical or different and are S or O, and n is a natural number from 1 to 50.

    摘要翻译： 式（I）的磷化合物作为阻燃剂的用途，其中式（I）中的符号的定义如下：A是以下基团之一：Y是-P（= X 2）SR 3 R 4，H 直链或支链C 1 -C 12 - 烷基，C 5 -C 6 - 环烷基，C 6 -C 12 - 芳基或苄基，其中四个最后提到的基团是未取代的或具有一个或多个自由基 C 1 -C 4 - 烷基或C 1 -C 4 - 烯基; R1，R2，R3和R4相同或不同，为氢，OH，C1-C16 - 烷基，C1-C16 - 烯基，C1-C16 - 烷氧基，C1-C16 - 烯氧基，C3-C10-环烷基，C3- C 1 -C 10 - 芳基，C 6 -C 10 - 芳氧基，C 6 -C 10 - 芳基-C 1 -C 16 - 烷基，C 6 -C 10 - 芳基-C 1 -C 16 - 烷氧基，SR 9 COR 10，COOR 11，CONR 12 R 13或两个基团R 1 R 2，R 3或R 4与它们所键合的磷原子一起形成，或与P-OAO-P基团形成环系; R 5，R 6，R 7和R 8相同或不同，为H，C 1 -C 16 - 烷基，C 1 -C 16 - 烯基，C 1 -C 16 - 烷氧基，C 1 -C 16 - 烯氧基; R9，R10，R11，R12，R13相同或不同，为H，C1-C16 - 烷基，C1-C16 - 烯基，C6-C10-芳基，C6-C10-芳基-C1-C16 - 烷基，C6-C10 芳基-C 1 -C 16 - 烷氧基; X1和X2相同或不同，为S或O; r和s相同或不同，为0或1; X3，X4，X5和X6相同或不同，为S或O，n为1〜50的自然数。