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公开(公告)号:US20230227988A1
公开(公告)日:2023-07-20
申请号:US17803894
申请日:2023-01-12
Inventor: Viktor Balema , Sonal Padalkar , Ihor Hlova , Tian Lan , Oleksandr Dolotko , Vitalij K. Pecharsky , Duane D. Johnson , Arjun K. Pathak , Prashant Singh
IPC: C25B11/075 , C25D5/02 , C23C18/16 , C25D3/50 , C23C18/42 , C25D13/02 , C25B1/04 , C25B11/091 , C25B11/051 , C25B11/057 , G01N27/48
CPC classification number: C25B11/075 , C25D5/02 , C23C18/1639 , C25D3/50 , C23C18/42 , C25D13/02 , C25B1/04 , C25B11/091 , C25B11/051 , C25B11/057 , G01N27/48
Abstract: A cathode is provided for electrolysis of water wherein the cathode material comprises a multi-principal element, transition metal dichalcogenide material that has four or more chemical elements and that is a single phase, solid solution. The pristine cathode material does not contain platinum as a principal (major) component. However, a cathode comprising a transition metal dichalcogenide having platinum (Pt) nanosized islands or precipitates disposed thereon is also provided.
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公开(公告)号:US11585000B2
公开(公告)日:2023-02-21
申请号:US16602420
申请日:2019-10-01
Inventor: Viktor Balema , Sonal Padalkar , Ihor Hlova , Tian Lan , Oleksandr Dolotko , Vitalij K. Pecharsky , Duane D. Johnson , Arjun K. Pathak , Prashant Singh
IPC: C25B11/075 , C25B1/04 , C25B11/051 , C25B11/057 , C25B11/091 , C25D3/50 , C25D5/02 , C23C18/42 , C23C18/16 , C25D13/02 , G01N27/48
Abstract: A cathode is provided for electrolysis of water wherein the cathode material comprises a multi-principal element, transition metal dichalcogenide material that has four or more chemical elements and that is a single phase, solid solution. The pristine cathode material does not contain platinum as a principal (major) component. However, a cathode comprising a transition metal dichalcogenide having platinum (Pt) nanosized islands or precipitates disposed thereon is also provided.
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公开(公告)号:US09663364B2
公开(公告)日:2017-05-30
申请号:US14757132
申请日:2015-11-23
Inventor: Vitalij K. Pecharsky , Shalabh Gupta , Marek Pruski , Ihor Hlova , Andra Castle
Abstract: A method is provided for making alkali metal hydrides by mechanochemically reacting alkali metal and hydrogen gas under mild temperature (e.g room temperature) and hydrogen pressure conditions without the need for catalyst, solvent, and intentional heating or cooling.
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公开(公告)号:US12163236B2
公开(公告)日:2024-12-10
申请号:US17803894
申请日:2023-01-12
Inventor: Viktor Balema , Sonal Padalkar , Ihor Hlova , Tian Lan , Oleksandr Dolotko , Vitalij K. Pecharsky , Duane D. Johnson , Arjun K. Pathak , Prashant Singh
IPC: C25B11/075 , C23C18/16 , C23C18/42 , C25B1/04 , C25B11/051 , C25B11/057 , C25B11/091 , C25D3/50 , C25D5/02 , C25D13/02 , G01N27/48
Abstract: A cathode is provided for electrolysis of water wherein the cathode material comprises a multi-principal element, transition metal dichalcogenide material that has four or more chemical elements and that is a single phase, solid solution. The pristine cathode material does not contain platinum as a principal (major) component. However, a cathode comprising a transition metal dichalcogenide having platinum (Pt) nanosized islands or precipitates disposed thereon is also provided.
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公开(公告)号:US11919781B2
公开(公告)日:2024-03-05
申请号:US17300772
申请日:2021-11-01
Inventor: Viktor Balema , Ihor Hlova , Vitalij K. Pecharsky
CPC classification number: C01G39/06 , B02C15/004 , B02C19/06 , C01B19/002 , C01G41/00 , C01G41/006 , C01P2002/01 , C01P2002/72 , C01P2002/85 , C01P2002/88 , C01P2004/03 , C01P2004/04 , C01P2004/20 , C01P2004/30
Abstract: A method embodiment involves preparing single metal or mixed transition metal chalcogenide using exfoliation of two or more different bulk transition metal dichalcogenides in a manner to form an intermediate hetero-layered transition metal chalcogenide structure, which can be treated to provide a single-phase transition metal chalcogenide.
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公开(公告)号:US11764416B2
公开(公告)日:2023-09-19
申请号:US16873846
申请日:2020-07-23
Inventor: Viktor Balema , Ihor Hlova , Oleksandr Dolotko , Vitalij K. Pecharsky
CPC classification number: H01M10/54 , C22B1/005 , C22B3/14 , C22B23/00 , C22B23/0446 , C22B59/00 , C22B3/44
Abstract: Certain method embodiments are described and useful for recycling permanent magnet materials (e.g. permanent magnet alloys) and battery materials (e.g. battery electrode materials) to extract critical and/or valuable elements including REEs, Co and Ni. Method embodiments involve reacting such material with at least one of an ammonium salt and an iron (III) salt to achieve at least one of a liquid phase chemical reaction and a mechanochemical reaction.
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公开(公告)号:US10273156B2
公开(公告)日:2019-04-30
申请号:US15118788
申请日:2015-02-12
Inventor: Shalabh Gupta , Vitalij K. Pecharsky , Takeshi Kobayashi , Marek Pruski , Ihor Hlova
Abstract: In some examples, a method of forming alane (AlH3), the method comprising reacting one of: 1) a MAlH4, wherein M is an alkali metal; 2) alkali-metal hydride, MH; or 3) alkali-metal with one or more aluminum halides (AlX3, where X is a halogen), via a mechanochemical process, to form the alane, wherein the reaction is substantially solvent free and carried out in an environment with a temperature between approximately 250 K and approximately 330 K.
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公开(公告)号:US20170050846A1
公开(公告)日:2017-02-23
申请号:US15118788
申请日:2015-02-12
Inventor: Shalabh Gupta , Vitalij K. Pecharsky , Takeshi Kobayashi , Marek Pruski , Ihor Hlova
CPC classification number: C01B6/06 , C01B3/0026
Abstract: In some examples, a method of forming alane (AlH3), the method comprising reacting one of: 1) a MAlH4, wherein M is an alkali metal; 2) alkali-metal hydride, MH; or 3) alkali-metal with one or more aluminum halides (AlX3, where X is a halogen), via a mechanochemical process, to form the alane, wherein the reaction is substantially solvent free and carried out in an environment with a temperature between approximately 250 K and approximately 330 K.
Abstract translation: 在一些实例中,形成丙烷(AlH 3)的方法,所述方法包括使以下物质之一:1)MAH 4,其中M是碱金属; 2)碱金属氢化物,MH; 或3)碱金属与一种或多种卤化铝(AlX 3,其中X为卤素)通过机械化学方法形成丙烯,其中反应基本上无溶剂,并且在温度在约 250 K和约330 K.
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公开(公告)号:US20170022060A1
公开(公告)日:2017-01-26
申请号:US14757132
申请日:2015-11-23
Inventor: Vitalij K. Pecharsky , Shalabh Gupta , Marek Pruski , Ihor Hlova , Andra Castle
Abstract: A method is provided for making alkali metal hydrides by mechanochemically reacting alkali metal and hydrogen gas under mild temperature (e.g room temperature) and hydrogen pressure conditions without the need for catalyst, solvent, and intentional heating or cooling.
Abstract translation: 提供了在温和的温度(例如室温)和氢气压力条件下使碱金属和氢气机械化学反应制备碱金属氢化物的方法,而不需要催化剂,溶剂和有意的加热或冷却。
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公开(公告)号:US11289248B2
公开(公告)日:2022-03-29
申请号:US16501027
申请日:2019-02-11
Inventor: Arjun K. Pathak , Yaroslav Mudryk , Oleksandr Dolotko , Vitalij K. Pecharsky
Abstract: A magnetocaloric material comprising a La—Fe—Si based alloy composition that is compositionally modified to include a small but effective amount of at least one of Al, Ga, and In to improve mechanical stability of the alloy (substantially reduce alloy brittleness), improve thermal conductivity, and preserve comparable or provide improved magnetocaloric effects. The alloy composition may be further modified by inclusion of at least one of Co, Mn, Cr, and V as well as interstitial hydrogen.
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