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    Process for the facile electrosynthesis of graphene from CO2
    1.
    发明授权
    Process for the facile electrosynthesis of graphene from CO2 有权

    公开(公告)号：US11613815B2

    公开(公告)日：2023-03-28

    申请号：US17812514

    申请日：2022-07-14

    申请人： C2CNT LLC

    发明人： Stuart Licht

    IPC分类号： C25B1/135 ,  C25B1/00 ,  C25B9/17 ,  C25B11/051 ,  C25B11/057 ,  C25B11/075

    摘要： The present invention relates to the production of graphene from CO2 through electrolysis and exfoliation processes. One embodiment is a method for producing graphene comprising (i) performing electrolysis between an electrolysis anode and an electrolysis cathode in a molten carbonate electrolyte to generate carbon nanomaterial on the cathode, and (ii) electrochemically exfoliating the carbon nanomaterial from a second anode to produce graphene. The exfoliating step produces graphene in high yield than thicker, conventional graphite exfoliation reactions. CO2 can be the sole reactant used to produce the valuable product as graphene. This can incentivize utilization of CO2, and unlike alternative products made from CO2 such as carbon monoxide or other fuels such as methane, use of the graphene product does not release this greenhouse gas back into the atmosphere.

    Z-scheme microbial photoelectrochemical system (MPS) for wastewater-to-chemical fuel conversion
    2.
    发明授权
    Z-scheme microbial photoelectrochemical system (MPS) for wastewater-to-chemical fuel conversion 有权

    公开(公告)号：US11581562B2

    公开(公告)日：2023-02-14

    申请号：US16868380

    申请日：2020-05-06

    申请人： Yat Li

    发明人： Yat Li

    IPC分类号： H01M8/16 ,  C02F3/00 ,  C02F1/30 ,  C25B1/55 ,  C25B1/04 ,  C02F1/72 ,  C25B11/031 ,  C25B11/051 ,  C25B11/057 ,  C25B11/077

    摘要： A wastewater to chemical fuel conversion device is provided that includes a housing having a first chamber and a second chamber, where the first chamber includes a bio-photoanode, where the second chamber includes a photocathode, where a backside of the bio-photoanode abuts a first side of a planatized fluorine doped tin oxide (FTO) glass, where a backside of the photocathode abuts a second side of the FTO glass, where a proton exchange membrane separates the first chamber from the second chamber, where the first chamber includes a wastewater input and a reclaimed water output, where the second chamber includes a solar light input and a H2 gas output, where the solar light input is disposed for solar light illumination of the first chamber and the second chamber.

    Electrochemical device comprising thin porous metal sheet
    5.
    发明授权
    Electrochemical device comprising thin porous metal sheet 有权

    公开(公告)号：US11248303B2

    公开(公告)日：2022-02-15

    申请号：US16398468

    申请日：2019-04-30

    申请人： Molecule Works Inc.

    发明人： Wei Liu

    IPC分类号： H01M4/90 ,  H01M2/16 ,  C25B11/031 ,  H01G9/042 ,  H01M8/0236 ,  H01M4/86 ,  C25B1/00 ,  C25B13/02 ,  C25B13/04 ,  H01G9/02 ,  H01G9/052 ,  H01M8/1004 ,  C25B1/04 ,  C25B9/73 ,  C25B11/051 ,  C25B11/057 ,  C25B11/075 ,  H01M50/46 ,  H01M50/431

    摘要： Electrochemical device using thin micro-porous metal sheets. The porous metal sheet may have a thickness less than 200 μm, provides three-dimensional networked pore structures of pore sizes in the range of 2.0 nm to 5.0 μm, and is electrically conductive. The micro-porous metal sheet is used for positively and/or negatively-charged electrodes by providing large specific contact surface area of reactants/electron. Nano-sized catalyst or features can be added inside pores of the porous metal sheet of pore sizes at sub- and micrometer scale to enhance the reaction activity and capacity. Micro-porous ceramic materials may be coated on the porous metal sheet at a thickness of less than 40 μm to enhance the functionality of the porous metal sheet and may function as a membrane separator. The electrochemical device may be used for decomposing molecules and for synthesis of molecules such as synthesis of ammonia from water and nitrogen molecules.

    PROCESS FOR THE FACILE ELECTROSYNTHESIS OF GRAPHENE FROM CO2
    10.
    发明申请
    PROCESS FOR THE FACILE ELECTROSYNTHESIS OF GRAPHENE FROM CO2 有权

    公开(公告)号：US20220372634A1

    公开(公告)日：2022-11-24

    申请号：US17812510

    申请日：2022-07-14

    申请人： C2CNT LLC

    发明人： Stuart LICHT

    IPC分类号： C25B1/00 ,  C25B9/17 ,  C25B11/051 ,  C25B11/057 ,  C25B11/075

    摘要： The present invention relates to the production of graphene from CO2 through electrolysis and exfoliation processes. One embodiment is a method for producing graphene comprising (i) performing electrolysis between an electrolysis anode and an electrolysis cathode in a molten carbonate electrolyte to generate carbon nanomaterial on the cathode, and (ii) electrochemically exfoliating the carbon nanomaterial from a second anode to produce graphene. The exfoliating step produces graphene in high yield than thicker, conventional graphite exfoliation reactions. CO2 can be the sole reactant used to produce the valuable product as graphene. This can incentivize utilization of CO2, and unlike alternative products made from CO2 such as carbon monoxide or other fuels such as methane, use of the graphene product does not release this greenhouse gas back into the atmosphere.