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    Block polymers containing methacrylic acid and derivatives thereof
    1.
    发明授权
    Block polymers containing methacrylic acid and derivatives thereof 失效
    含有甲基丙烯酸及其衍生物的嵌段聚合物

    公开(公告)号：US5166274A

    公开(公告)日：1992-11-24

    申请号：US560265

    申请日：1990-07-30

    申请人： James E. McGrath ,  Timothy E. Long ,  Allan D. Broske ,  Lu H. Tung

    发明人： James E. McGrath ,  Timothy E. Long ,  Allan D. Broske ,  Lu H. Tung

    IPC分类号： C08F297/02

    CPC分类号： C08F297/026

    摘要： Novel diene/methacrylate ester block polymers, especially tertiary butyl methacrylate ester block polymers are uniquely prepared at near ambient temperatures and capable of being hydrolyzed and neutralized to yield the corresponding methacrylic acid and methacrylic acid salt (ionomer) derivatives. The compositions are usefully employed in the preparation of thermoplastic elastomers, adhesives and laminating films.

    摘要翻译： 新的二烯/甲基丙烯酸酯嵌段聚合物，特别是甲基丙烯酸叔丁酯酯嵌段聚合物在接近环境温度下独特地制备并且能够水解和中和以产生相应的甲基丙烯酸和甲基丙烯酸盐（离聚物）衍生物。 该组合物有用地用于制备热塑性弹性体，粘合剂和层合膜。

    Block polymers of methacrylates
    2.
    发明授权
    Block polymers of methacrylates 失效
    甲基丙烯酸酯的嵌段聚合物

    公开(公告)号：US5098959A

    公开(公告)日：1992-03-24

    申请号：US560266

    申请日：1990-07-30

    申请人： James E. McGrath ,  Craig D. DePorter ,  Timothy E. Long

    发明人： James E. McGrath ,  Craig D. DePorter ,  Timothy E. Long

    IPC分类号： C08F297/02 ,  C09J153/00

    CPC分类号： C08F297/026 ,  C09J153/00

    摘要： Novel methacrylate ester block polymers comprising both a hydrolyzable and a non-hydrolyzable ester functionality are capable of being partially hydrolyzed and neutralized to yield the corresponding methacrylic acid and methacrylic acid salt (ionomer) derivatives. The compositions are usefully employed in the preparation of thermoplastic elastomers, adhesives and laminating films.

    摘要翻译： 包含可水解和不可水解的酯官能团的新的甲基丙烯酸酯嵌段聚合物能够被部分水解和中和以产生相应的甲基丙烯酸和甲基丙烯酸盐（离聚物）衍生物。 该组合物有用地用于制备热塑性弹性体，粘合剂和层合膜。

    Side-chain crystallizable polymers for medical applications
    4.
    发明授权
    Side-chain crystallizable polymers for medical applications 有权
    用于医疗应用的侧链可结晶聚合物

    公开(公告)号：US08703113B2

    公开(公告)日：2014-04-22

    申请号：US11335771

    申请日：2006-01-18

    申请人： Donald K. Brandom ,  James E. McGrath ,  Joan Zeltinger ,  Eric V. Schmid ,  Robert K. Schultz

    发明人： Donald K. Brandom ,  James E. McGrath ,  Joan Zeltinger ,  Eric V. Schmid ,  Robert K. Schultz

    IPC分类号： A61K31/74

    CPC分类号： A61L31/18 ,  A61F2/92 ,  A61K49/12 ,  A61K49/126 ,  A61K49/128 ,  A61L31/06 ,  C08F220/00 ,  C08G63/00 ,  C08G63/08

    摘要： Side-chain crystallizable (SCC) polymers are useful in various medical applications. In certain applications, heavy atom containing side-chain crystallizable polymers (HACSCCP's) are particularly useful. An example of a HACSCCP is a polymer that comprises a main chain, a plurality of crystallizable side chains, and a plurality of heavy atoms attached to the polymer. In certain configurations, the heavy atoms are present in an amount that is effective to render the polymer radiopaque. A polymeric material that includes an HACSCCP may be fabricated into a medical device useful for at least partially occluding a body cavity. For example, such a medical device may be an embolotherapy product. A polymeric material that includes a SCC polymer may also be fabricated into other medical devices, such as stents.

    摘要翻译： 侧链可结晶（SCC）聚合物可用于各种医疗应用。 在某些应用中，含重链原子的侧链可结晶聚合物（HACSCCP）特别有用。 HACSCCP的实例是包含主链，多个可结晶侧链和连接到聚合物上的多个重原子的聚合物。 在某些构型中，重质原子以有效使聚合物不透射线的量存在。 包括HACSCCP的聚合物材料可以制造成用于至少部分地封闭体腔的医疗装置。 例如，这种医疗装置可以是电疗产品。 包括SCC聚合物的聚合物材料也可制成其他医疗装置，例如支架。

    Novel mine-terminated poly(arylene ether phosphine oxide) oligomer
    6.
    发明授权
    Novel mine-terminated poly(arylene ether phosphine oxide) oligomer 失效
    新型矿物聚（亚芳基醚氧化膦）低聚物

    公开(公告)号：US5079333A

    公开(公告)日：1992-01-07

    申请号：US552635

    申请日：1990-07-13

    申请人： James E. McGrath ,  Carrington D. Smith

    发明人： James E. McGrath ,  Carrington D. Smith

    IPC分类号： C08G79/04

    CPC分类号： C08G79/04

    摘要： Amine-terminated poly(arylene ether phosphine oxide) oligomers of the general formula ##STR1## where Ar' is phenyl, biphenyl, bisphenol-A, etc., can be formed by reaction of a bisphenol monomer, a dihalo triphenyl phosphine oxide monomer, and an aminophenol.

    摘要翻译： 可以通过双酚单体，二卤代三苯基膦氧化物单体的反应形成通式“IMAGE”的胺封端的聚（亚芳基醚氧化膦）低聚物，其中Ar'是苯基，联苯基，双酚A等， 和氨基苯酚。

    ION-conducting sulfonated polymeric materials
    7.
    发明授权
    ION-conducting sulfonated polymeric materials 有权
    离子导电磺化聚合材料

    公开(公告)号：US08383763B2

    公开(公告)日：2013-02-26

    申请号：US12845874

    申请日：2010-07-29

    申请人： James E. McGrath ,  Michael Hickner ,  Feng Wang ,  Yu-Seung Kim

    发明人： James E. McGrath ,  Michael Hickner ,  Feng Wang ,  Yu-Seung Kim

    IPC分类号： C08G75/20

    CPC分类号： B01D71/82 ,  B01D69/141 ,  B01D71/64 ,  B01D71/68 ,  C08G73/10 ,  C08G75/23

    摘要： Sulfonated polymers are made by the direct polymerization of a sulfonated monomer to form the sulfonated polymers. The types of sulfonated polymers may include polysulfones or polyimides. The sulfonated polymers can be formed into membranes that may be used in proton exchange membrane fuel cells or as ion exchange membranes. The membranes formed from the sulfonated polymers exhibit improved properties over that of Nafion®. A heteropoly acid may be added to the sulfonated polymer to form a nanocomposite membrane in which the heteropoly acid is highly dispersed. The addition of a heteropoly acid to the sulfonated polymer increases the thermal stability of the membrane, enhances the conductivity above 100° C., and reduces the water uptake of the membrane.

    摘要翻译： 磺化聚合物通过磺化单体的直接聚合制成磺化聚合物。 磺化聚合物的类型可以包括聚砜或聚酰亚胺。 磺化聚合物可以形成为可用于质子交换膜燃料电池或作为离子交换膜的膜。 由磺化聚合物形成的膜表现出比Nafion®改善的性能。 可以将杂多酸加入到磺化聚合物中以形成杂多酸高度分散的纳米复合膜。 向磺化聚合物中加入杂多酸增加了膜的热稳定性，提高了100℃以上的电导率，并降低了膜的吸水率。

    Materials for use as proton conducting membranes for fuel cells
    8.
    发明授权
    Materials for use as proton conducting membranes for fuel cells 有权
    用作燃料电池质子导电膜的材料

    公开(公告)号：US07473714B2

    公开(公告)日：2009-01-06

    申请号：US11119353

    申请日：2005-05-02

    申请人： Brian R. Einsla ,  James E. McGrath

    发明人： Brian R. Einsla ,  James E. McGrath

    IPC分类号： B01J49/00 ,  B01J39/20

    CPC分类号： C08J5/2256 ,  C08G65/48 ,  C08G75/23 ,  C08J2371/12 ,  C08J2381/06

    摘要： A family of polymers having pendent sulfonate moieties connected to polymeric main chain phenyl groups are described. These polymers are prepared by the steps of polymerization (using a monomer with a phenyl with an alkoxy substitution), deportation by converting the alkoxy to a hydroxyl, and functionalization of the polymer with a pendant sulfonate group. As an example, sulfonated poly(arylene ether sulfone) copolymers with pendent sulfonic acid groups are synthesized by the direct copolymerization of methoxy-containing poly(arylene ether sulfone)s, then converting the methoxy groups to the reactive hydroxyl form, and finally functionalizing the hydroxyl form with proton-conducting sites through nucleophilic substitution. The family of polymers may have application in proton exchange membranes and in other applications.

    摘要翻译： 描述了具有连接到聚合主链苯基的侧链磺酸酯部分的聚合物族。 这些聚合物通过聚合（使用具有烷氧基取代基的苯基）的单体，通过将烷氧基转化为羟基而进行递送的步骤，以及用磺酸侧基官能化聚合物来制备。 作为例子，通过直接共聚含甲氧基的聚（亚芳基醚砜），然后将甲氧基转化为反应性羟基，合成具有侧链磺酸基的磺化聚（亚芳基醚砜）共聚物，最后使 羟基与质子传导位点通过亲核取代。 聚合物族可以用于质子交换膜和其它应用中。

    Highly conductive thermoplastic composites for rapid production of fuel cell bipolar plates
    9.
    发明授权
    Highly conductive thermoplastic composites for rapid production of fuel cell bipolar plates 失效
    用于快速生产燃料电池双极板的高导电性热塑性复合材料

    公开(公告)号：US07365121B2

    公开(公告)日：2008-04-29

    申请号：US10779804

    申请日：2004-02-18

    申请人： Jianhua Huang ,  Donald G. Baird ,  James E. McGrath

    发明人： Jianhua Huang ,  Donald G. Baird ,  James E. McGrath

    IPC分类号： C08K3/04 ,  C08K3/40 ,  H01M8/00

    CPC分类号： C08K7/02

    摘要： A low cost method of fabricating bipolar plates for use in fuel cells utilizes a wet lay process for combining graphite particles, thermoplastic fibers, and reinforcing fibers to produce a plurality of formable sheets. The formable sheets are then molded into a bipolar plates with features impressed therein via the molding process. The bipolar plates formed by the process have conductivity in excess of 150 S/cm and have sufficient mechanical strength to be used in fuel cells. The bipolar plates can be formed as a skin/core laminate where a second polymer material is used on the skin surface which provides for enhanced conductivity, chemical resistance, and resistance to gas permeation.

    摘要翻译： 制造用于燃料电池的双极板的低成本方法利用湿式铺设方法来组合石墨颗粒，热塑性纤维和增强纤维，以生产多个可成形片材。 然后将可成形片材模制成具有通过模制工艺在其中印刷的特征的双极板。 通过该方法形成的双极板具有超过150S / cm的电导率并且具有足够的机械强度以用于燃料电池。 双极板可以形成为皮肤/芯层压板，其中在皮肤表面上使用第二聚合物材料，其提供增强的导电性，耐化学性和耐气体渗透性。