Processes for lifting spent catalyst into a regenerator in an oxygenate to olefins reaction system
    1.
    发明授权
    Processes for lifting spent catalyst into a regenerator in an oxygenate to olefins reaction system 有权
    将废催化剂提升到含氧化合物到烯烃反应体系中的再生器的方法

    公开(公告)号:US07459595B2

    公开(公告)日:2008-12-02

    申请号:US11050199

    申请日:2005-02-03

    IPC分类号: C07C1/00 B01J20/34

    摘要: This invention provides processes for transporting catalyst, preferably in an oxygenate to olefins reaction system. In one embodiment, an oxygenate contacts molecular sieve catalyst particles in a reactor under conditions effective to form an effluent stream comprising light olefins and forming coked catalyst particles. At least a portion of the coked catalyst particles are transported from the reactor or a device associated therewith to a catalyst regenerator through a conduit in a fluidized manner with a fluidizing medium comprising air and steam. At least a portion of the coked catalyst particles are regenerated in the catalyst regenerator to form regenerated catalyst particles, which are ultimately directed back to the reactor.

    摘要翻译: 本发明提供了将催化剂,优选在含氧化合物转化为烯烃反应体系的方法。 在一个实施方案中,含氧化合物在有效形成包含轻质烯烃和形成焦化催化剂颗粒的流出物流的条件下在反应器中与分子筛催化剂颗粒接触。 焦化的催化剂颗粒的至少一部分从反应器或与其相关的装置通过管道以流化方式通过导管从包含空气和蒸汽的流化介质输送到催化剂再生器。 焦化催化剂颗粒的至少一部分在催化剂再生器中再生以形成再生的催化剂颗粒,其最终被引导回反应器。

    Oxygenate to olefin process
    3.
    发明授权
    Oxygenate to olefin process 有权
    氧化烯到烯烃工艺

    公开(公告)号:US06965057B2

    公开(公告)日:2005-11-15

    申请号:US10807818

    申请日:2004-03-24

    摘要: The invention relates to a process for converting an oxygenate feedstock into an olefin product stream comprising (a) contacting an oxygenate feedstock with a molecular sieve catalyst in a reactor under conditions effective to convert the feedstock into an olefin product stream and to form carbonaceous deposits on the catalyst; (b) contacting at least a portion of the catalyst having said carbonaceous deposits with an oxygen containing gas under conditions effective to obtain a regenerated catalyst having a reduced carbonaceous deposit level and having an increased molecular oxygen content; (c) removing at least 60% by volume of said molecular oxygen from the regenerated catalyst based upon the total volume of molecular oxygen; (d) returning said regenerated catalyst to said reactor; and (e) repeating steps (a)–(d).

    摘要翻译: 本发明涉及一种将含氧化合物原料转化成烯烃产物流的方法,该方法包括(a)在有效将原料转化成烯烃产物流并形成碳质沉积物的条件下,使反应器中的含氧化合物原料与分子筛催化剂接触 催化剂; (b)在有效获得具有降低的碳沉积物水平并且具有增加的分子氧含量的再生催化剂的条件下使至少一部分具有所述碳质沉积物的催化剂与含氧气体接触; (c)基于分子氧的总体积从再生催化剂中除去至少60体积%的所述分子氧; (d)将所述再生催化剂返回到所述反应器; 和(e)重复步骤(a) - (d)。

    Method of circulating catalyst between a catalyst regenerator and an external catalyst cooler
    4.
    发明授权
    Method of circulating catalyst between a catalyst regenerator and an external catalyst cooler 有权
    在催化剂再生器和外部催化剂冷却器之间循环催化剂的方法

    公开(公告)号:US07906697B2

    公开(公告)日:2011-03-15

    申请号:US12059717

    申请日:2008-03-31

    IPC分类号: C07C2/04

    摘要: This invention relates to efficiently regenerating catalyst particles by minimizing the formation of localized “hot spots” and “cold spots” in a regeneration zone. Specifically this invention relates to a method for controlling regenerator temperature in an oxygenates-to-olefins system, comprising the steps of: contacting an oxygenate feed in a reactor with a catalytically effective amount of molecular sieve-containing catalyst under conditions effective for converting said oxygenate to a product containing light olefins and forming a coked catalyst; contacting a portion of the coked catalyst in a regenerator, having a catalyst bed height (Hc), an inlet height (Hi), and an outlet height (Ho), with an oxygen-containing regeneration medium under conditions effective to at least partially regenerate the coked catalyst; and conducting a portion of the catalyst from the regenerator to a catalyst cooler to form a cooled catalyst portion, wherein Ho is greater than Hi.

    摘要翻译: 本发明涉及通过最小化再生区中局部“热点”和“冷点”的形成来有效地再生催化剂颗粒。 具体地说,本发明涉及一种用于控制含氧化合物至烯烃体系中的再生器温度的方法,其包括以下步骤:在有效转化所述含氧化合物的条件下使反应器中的含氧化合物进料与催化有效量的含分子筛催化剂接触 涉及含有轻质烯烃并形成焦化催化剂的产品; 在具有催化剂床高度(Hc),入口高度(Hi)和出口高度(Ho))的再生器中使一部分焦化催化剂与含氧再生介质在有效至少部分再生的条件下接触 焦化催化剂; 并将催化剂的一部分从再生器导入催化剂冷却器以形成冷却的催化剂部分,其中Ho大于Hi。

    Method Of Circulating Catalyst Between A Catalyst Regenerator And An External Catalyst Cooler
    6.
    发明申请
    Method Of Circulating Catalyst Between A Catalyst Regenerator And An External Catalyst Cooler 有权
    催化剂再生器与外部催化剂冷却器之间循环催化剂的方法

    公开(公告)号:US20090192341A1

    公开(公告)日:2009-07-30

    申请号:US12059717

    申请日:2008-03-31

    IPC分类号: C07C2/04

    摘要: This invention relates to efficiently regenerating catalyst particles by minimizing the formation of localized “hot spots” and “cold spots” in a regeneration zone. Specifically this invention relates to a method for controlling regenerator temperature in an oxygenates-to-olefins system, comprising the steps of: contacting an oxygenate feed in a reactor with a catalytically effective amount of molecular sieve-containing catalyst under conditions effective for converting said oxygenate to a product containing light olefins and forming a coked catalyst; contacting a portion of the coked catalyst in a regenerator, having a catalyst bed height (Hc), an inlet height (Hi), and an outlet height (Ho), with an oxygen-containing regeneration medium under conditions effective to at least partially regenerate the coked catalyst; and conducting a portion of the catalyst from the regenerator to a catalyst cooler to form a cooled catalyst portion, wherein Ho is greater than Hi.

    摘要翻译: 本发明涉及通过最小化再生区中局部“热点”和“冷点”的形成来有效地再生催化剂颗粒。 具体地说,本发明涉及一种用于控制含氧化合物至烯烃体系中的再生器温度的方法,包括以下步骤:在有效转化所述含氧化合物的条件下使反应器中的含氧化合物进料与催化有效量的含分子筛的催化剂接触 涉及含有轻质烯烃并形成焦化催化剂的产品; 在具有催化剂床高度(Hc),入口高度(Hi)和出口高度(Ho))的再生器中使一部分焦化催化剂与含氧再生介质在有效至少部分再生的条件下接触 焦化催化剂; 并将催化剂的一部分从再生器导入催化剂冷却器以形成冷却的催化剂部分,其中Ho大于Hi。

    Process of producing cyclohexylbenzene
    10.
    发明授权
    Process of producing cyclohexylbenzene 有权
    生产环己基苯的方法

    公开(公告)号:US09365467B2

    公开(公告)日:2016-06-14

    申请号:US13883742

    申请日:2011-12-02

    摘要: In a process for producing cyclohexylbenzene, benzene is contacted with hydrogen under hydroalkylation conditions effective to form a first effluent stream comprising cyclohexylbenzene, cyclohexane, methylcyclopentane, and unreacted benzene. At least a portion of the first effluent stream is contacted with a dehydrogenation catalyst under dehydrogenation conditions to convert at least a portion of the cyclohexane to benzene thereby forming a second effluent stream. The amount of methylcyclopentane in the second effluent stream is different by no more than 65% of the total amount of the portion of the first effluent stream, said amounts being on a weight basis. A methylcyclopentane-containing stream is removed from either the first or the second effluent stream and at least a portion of the second effluent stream containing benzene is recycled to the hydroalkylation step.

    摘要翻译: 在生产环己基苯的方法中,苯在有效形成包含环己基苯,环己烷,甲基环戊烷和未反应苯的第一流出物流的加氢烷基化条件下与氢气接触。 在脱氢条件下,将至少一部分第一流出物流与脱氢催化剂接触以将至少一部分环己烷转化为苯,从而形成第二流出物流。 第二流出物流中的甲基环戊烷的量不同于第一流出物流的部分总量的不超过65%,所述量基于重量。 从第一或第二流出物流中除去含甲基环戊烷的物流,并将含有苯的第二流出物流的至少一部分再循环至加氢烷基化步骤。