Process of producing cyclohexylbenzene
    4.
    发明授权
    Process of producing cyclohexylbenzene 有权
    生产环己基苯的方法

    公开(公告)号:US09365467B2

    公开(公告)日:2016-06-14

    申请号:US13883742

    申请日:2011-12-02

    摘要: In a process for producing cyclohexylbenzene, benzene is contacted with hydrogen under hydroalkylation conditions effective to form a first effluent stream comprising cyclohexylbenzene, cyclohexane, methylcyclopentane, and unreacted benzene. At least a portion of the first effluent stream is contacted with a dehydrogenation catalyst under dehydrogenation conditions to convert at least a portion of the cyclohexane to benzene thereby forming a second effluent stream. The amount of methylcyclopentane in the second effluent stream is different by no more than 65% of the total amount of the portion of the first effluent stream, said amounts being on a weight basis. A methylcyclopentane-containing stream is removed from either the first or the second effluent stream and at least a portion of the second effluent stream containing benzene is recycled to the hydroalkylation step.

    摘要翻译: 在生产环己基苯的方法中,苯在有效形成包含环己基苯,环己烷,甲基环戊烷和未反应苯的第一流出物流的加氢烷基化条件下与氢气接触。 在脱氢条件下,将至少一部分第一流出物流与脱氢催化剂接触以将至少一部分环己烷转化为苯,从而形成第二流出物流。 第二流出物流中的甲基环戊烷的量不同于第一流出物流的部分总量的不超过65%,所述量基于重量。 从第一或第二流出物流中除去含甲基环戊烷的物流,并将含有苯的第二流出物流的至少一部分再循环至加氢烷基化步骤。

    Process for producing phenol
    5.
    发明授权
    Process for producing phenol 有权
    苯酚生产工艺

    公开(公告)号:US09115060B2

    公开(公告)日:2015-08-25

    申请号:US14347279

    申请日:2012-08-29

    摘要: In a process for producing phenol, cyclohexylbenzene hydroperoxide is cleaved to produce a cleavage effluent stream comprising phenol and cyclohexanone and at least a portion of the cleavage effluent stream is fractionated to produce a first fraction richer in cyclohexanone than the cleavage effluent stream portion and a second fraction richer in phenol and depleted in cyclohexanone as compared with said cleavage effluent stream portion. At least a portion of the second fraction is then contacted with a dehydrogenation catalyst in a dehydrogenation reaction zone under dehydrogenation conditions effective to convert at least a portion of the cyclohexanone in said second fraction portion into phenol and cyclohexanol.

    摘要翻译: 在生产苯酚的方法中,将环己基苯氢过氧化物切割以产生包含苯酚和环己酮的裂解流出料流,并将至少一部分裂解流出物流分馏以产生比裂解流出物流部分富含环己酮的第一馏分,第二馏分 与所述裂解流出物流部分相比,苯酚中的馏分比较富含,耗尽环己酮。 然后在有效将至少一部分所述第二级分部分中的环己酮转化成苯酚和环己醇的脱氢条件下,至少部分第二馏分与脱氢催化剂在脱氢反应区中接触。

    Hydrogen purification process
    6.
    发明授权
    Hydrogen purification process 有权
    氢气净化过程

    公开(公告)号:US09017641B2

    公开(公告)日:2015-04-28

    申请号:US13983974

    申请日:2011-11-21

    摘要: In a process for purifying a hydrogen stream, the stream is contacted with a first washing fluid in a first purification zone under conditions effective to transfer at least some water from the hydrogen stream to the first washing fluid, thereby transforming the hydrogen stream into a water-depleted hydrogen stream. At least a portion of the water-depleted hydrogen stream may then be transferred from the first purification zone to a second purification zone, where it is contacted with a second washing fluid under conditions effective to transfer at least some oxygenates from the water-depleted hydrogen stream to the second washing fluid.

    摘要翻译: 在纯化氢气流的方法中,在有效地将至少一些水从氢气流转移到第一洗涤流体的条件下,使该物流与第一净化区中的第一洗涤流体接触,从而将氢气流转化为水 分离的氢气流。 然后可以将至少一部分的贫水氢气流从第一纯化区转移到第二纯化区,在第二纯化区中,在有效从至少一些含氧化合物转移至水中的氢的条件下与第二洗涤流体接触 流到第二洗涤液。

    Process of Producing Cyclohexylbenzene
    7.
    发明申请
    Process of Producing Cyclohexylbenzene 有权
    生产环己基苯的工艺

    公开(公告)号:US20140371498A1

    公开(公告)日:2014-12-18

    申请号:US13883742

    申请日:2011-12-02

    IPC分类号: C07C2/74 C07C6/12 C07C5/367

    摘要: In a process for producing cyclohexylbenzene, benzene is contacted with hydrogen under hydroalkylation conditions effective to form a first effluent stream comprising cyclohexylbenzene, cyclohexane, methylcyclopentane, and unreacted benzene. At least a portion of the first effluent stream is contacted with a dehydrogenation catalyst under dehydrogenation conditions to convert at least a portion of the cyclohexane to benzene thereby forming a second effluent stream. The amount of methylcyclopentane in the second effluent stream is different by no more than 65% of the total amount of the portion of the first effluent stream, said amounts being on a weight basis. A methylcyclopentane-containing stream is removed from either the first or the second effluent stream and at least a portion of the second effluent stream containing benzene is recycled to the hydroalkylation step.

    摘要翻译: 在生产环己基苯的方法中,苯在有效形成包含环己基苯,环己烷,甲基环戊烷和未反应苯的第一流出物流的加氢烷基化条件下与氢气接触。 在脱氢条件下,将至少一部分第一流出物流与脱氢催化剂接触以将至少一部分环己烷转化为苯,从而形成第二流出物流。 第二流出物流中的甲基环戊烷的量不同于第一流出物流的部分总量的不超过65%,所述量基于重量。 从第一或第二流出物流中除去含甲基环戊烷的物流,并将含有苯的第二流出物流的至少一部分再循环至加氢烷基化步骤。

    Hydrogenation process
    8.
    发明授权
    Hydrogenation process 有权
    氢化过程

    公开(公告)号:US08658834B2

    公开(公告)日:2014-02-25

    申请号:US13516414

    申请日:2010-11-23

    IPC分类号: C07C37/06 C07C2/76

    摘要: The present invention relates to a hydrogenation process that may be used in connection with the production of phenol. In the process, a composition comprising: (i) cyclohexylbenzene; and (ii) a hydrogenable component are contacted with hydrogen in the presence of a hydrogenation catalyst under hydrogenation conditions. The hydrogenable component can be one or more of an olefin, a ketone or phenol. The hydrogenation catalyst has hydrogenation component and a support.

    摘要翻译: 本发明涉及可用于生产苯酚的氢化方法。 在该方法中,组合物包含:(i)环己基苯; 和(ii)可氢化组分在氢化条件下在氢化催化剂存在下与氢气接触。 可氢化组分可以是烯烃,酮或苯酚中的一种或多种。 氢化催化剂具有氢化组分和载体。