摘要:
Provided is a porous multi-layer film having two or more layers that is used as a separator for battery. In the film, more than 2 layers have different porosities and pore sizes. The film has a thickness of 9 to 50 μm, a machine direction (MD) loop stiffness of 0.008 mg/μm or more, puncture strength of 0.15 N/μm or more, permeability of 1.5×10−5 Darcy or more, shut-down temperature of 140° C. or less, melt-down temperature of 170° C. or more, a transverse direction (TD) maximum shrinkage of 25% or less in Thermomechanical Analysis (TMA) under a load of 1 mN/(1 μm×6 mm), and melt down temperature of 160° C. or more. Since the porous multi-layer film shows excellent thermal stability at high temperature and electrolyte retaining property due to a dual pore structure, the film shows a superior effect when used as a separator for high-capacity/high-power lithium ion battery.
摘要:
Provided is a porous multi-layer film having two or more layers that is used as a separator for battery. In the film, more than 2 layers have different porosities and pore sizes. The film has a thickness of 9 to 50 μm, a machine direction (MD) loop stiffness of 0.008 mg/μm or more, puncture strength of 0.15 N/μm or more, permeability of 1.5×10−5 Darcy or more, shut-down temperature of 140° C. or less, melt-down temperature of 170° C. or more, a transverse direction (TD) maximum shrinkage of 25% or less in Thermomechanical Analysis (TMA) under a load of 1 mN/(1 μm×6 mm), and melt down temperature of 160° C. or more. Since the porous multi-layer film shows excellent thermal stability at high temperature and electrolyte retaining property due to a dual pore structure, the film shows a superior effect when used as a separator for high-capacity/high-power lithium ion battery.
摘要:
Disclosed is a microporous high density polyethylene film for a battery separator and a method of producing the same. The microporous high density polyethylene film includes high density polyethylene with a weight average molecular weight of 2×105-5×105, containing 5 wt % or less molecule with a molecular weight of 1×104 or less. The microporous high density polyethylene film has tensile strengths of 1,100 kg/cm2 or more in transverse and machine directions respectively, a puncture strength of 0.22 N/μm or more, a gas permeability (Darcy's permeability constant) of 1.3×10−5 Darcy or more, and shrinkages of 5% or less in machine and transverse directions, respectively. Particularly, the microporous high density polyethylene film has an excellent extrusion-compoundabiliy and stretchability and a high productivity, and can improve the performances and stability of a battery produced using the same.
摘要翻译:公开了一种用于电池隔膜的微孔高密度聚乙烯膜及其制造方法。 微孔高密度聚乙烯膜包括重均分子量为2×10 5 -5×10 5的高密度聚乙烯,其含有5重量%或更少的分子量为1×10 5 4以下。 微孔高密度聚乙烯膜的横向和机械方向的拉伸强度分别为1100kg / cm 2以上,穿刺强度为0.22N / m 2以上,透气性(达西渗透率常数) 分别为1.3×10 -5以上的达西或以上,并且在纵向和横向上分别为5%以下的收缩。 特别地,微孔高密度聚乙烯膜具有优异的挤出复合性和拉伸性和高生产率,并且可以提高使用其制造的电池的性能和稳定性。
摘要:
Disclosed is a microporous polyethylene film for a battery separator and a method of producing the same. The microporous polyethylene film comprises a resin mixture, which includes 100 parts by weight of composition containing 20-50 wt % polyethylene with a weight average molecular weight of 5×104-3×105 (component I) and 80-50 wt % diluent (component II), 0.1-2 parts by weight of peroxide (component III), and 0.05-0.5 parts by weight of anti-oxidant (component IV). The microporous polyethylene film has a puncture strength of 0.22 N/μm or more and a gas permeability (Darcy's permeability constant) of 1.3×10−5 Darcy or more. The present invention increases production efficiency of the microporous film, and improves performances and stability of the battery when the microporous polyethylene film is used in a battery separator.
摘要:
Disclosed is a microporous polyolefin multilayer film which can be used as a separator for a battery, and a preparing method thereof. The microporous polyolefin multilayer film is a trilayer microporous film which is prepared by a wetting method to have both surface layers containing polyethylene of 95 wt % or more having a melting temperature of 125° C. or more, and an intermediate layer containing polypropylene of 50 to 90 wt % having a melting temperature of 160° C. or more and polyethylene of 10 to 50 wt % having a melting temperature of 125° C. or more, wherein a thickness of the film is 9-50 μm, a puncture strength is 0.15 N/μm or more, a permeability is 1.5×10−5 Darcy or more, a multiplication of the puncture strength and the permeability is 0.4×10−5 Darcy·N/μm or more, a contraction rate in a traverse direction at a temperature of 150° C. for 1 hour is 15% or less, and a melt fracture temperature of 160° C.
摘要:
A microporous polyolefin multilayer film which is used as a separator for a battery is a 3 layer microporous film which is prepared by a wet process to have both surface layers containing polyethylene of 95 wt % or more having a melting temperature of 125° C. or higher, and an inner layer containing polypropylene of 50 to 90 wt % having a melting temperature of 160° C. or higher and polyethylene of 10 to 50 wt % having a melting temperature of 125° C. or higher. A thickness of the film is 9-50/M, a puncture strength is 0.15N//M or more, a permeability is 1.5×10−5 Darcy or more, a multiplication of the puncture strength and the permeability is 0.4×10−5 Darcy·N/μm or more, a shrinkage in a transverse direction at 120° C. for 1 hour is 15% or less, and a melt fracture temperature of 160° C. or higher.
摘要:
Disclosed is a microporous high density polyethylene film for a battery separator and a method of producing the same. The microporous high density polyethylene film includes high density polyethylene with a weight average molecular weight of 2×105-5×105, containing 5 wt % or less molecule with a molecular weight of 1×104 or less. The microporous high density polyethylene film has tensile strengths of 1,100 kg/cm2 or more in transverse and machine directions respectively, a puncture strength of 0.22 N/μm or more, a gas permeability (Darcy's permeability constant) of 1.3×10−5 Darcy or more, and shrinkages of 5% or less in machine and transverse directions, respectively. Particularly, the microporous high density polyethylene film has an excellent extrusion-compoundabiliy and stretchability and a high productivity, and can improve the performances and stability of a battery produced using the same.
摘要翻译:公开了一种用于电池隔膜的微孔高密度聚乙烯膜及其制造方法。 微孔高密度聚乙烯膜包括重均分子量为2×105-5×105的高密度聚乙烯,其含有5重量%以下的分子量为1×10 4以下的分子。 微孔高密度聚乙烯膜的横向和机械方向的抗拉强度分别为1100kg / cm 2以上,穿刺强度为0.22N /μm以上,透气度(达西渗透率常数)为1.3×10-5达西或 分别在机器和横向上分别为5%或更小的收缩率。 特别地,微孔高密度聚乙烯膜具有优异的挤出复合性和拉伸性和高生产率,并且可以提高使用其制造的电池的性能和稳定性。
摘要:
Disclosed is a microporous polyethylene film for a battery separator and a method of producing the same. The microporous polyethylene film comprises a resin mixture, which includes 100 parts by weight of composition containing 20-50 wt % polyethylene with a weight average molecular weight of 5×104-3×105 (component I) and 80-50 wt % diluent (component II), 0.1-2 parts by weight of peroxide (component III), and 0.05-0.5 parts by weight of anti-oxidant (component IV). The microporous polyethylene film has a puncture strength of 0.22 N/μm or more and a gas permeability (Darcy's permeability constant) of 1.3×10−5 Darcy or more. The present invention increases production efficiency of the microporous film, and improves performances and stability of the battery when the microporous polyethylene film is used in a battery separator.
摘要:
Disclosed is a microporous high density polyethylene film for a battery separator and a method of producing the same. The microporous high density polyethylene film includes high density polyethylene with a weight average molecular weight of 2×105−5×105, containing 5 wt % or less molecule with a molecular weight of 1×104 or less. The microporous high density polyethylene film has tensile strengths of 1,100 kg/cm2 or more in transverse and machine directions respectively, a puncture strength of 0.22 N/μm or more, a gas permeability (Darcy's permeability constant) of 1.3×10−5 Darcy or more, and shrinkages of 5% or less in machine and transverse directions, respectively. Particularly, the microporous high density polyethylene film has an excellent extrusion-compoundabiliy and stretchability and a high productivity, and can improve the performances and stability of a battery produced using the same.
摘要翻译:公开了一种用于电池隔膜的微孔高密度聚乙烯膜及其制造方法。 微孔高密度聚乙烯膜包括重均分子量为2×10 5 -5×10 5的高密度聚乙烯,其含有5重量%或更少的分子量为1×10 5 4以下。 微孔高密度聚乙烯膜的横向和机械方向的拉伸强度分别为1100kg / cm 2以上,穿刺强度为0.22N / m 2以上,透气度(达西渗透率常数) 分别为1.3×10 -5以上的达西或以上,并且在纵向和横向上分别为5%以下的收缩。 特别地,微孔高密度聚乙烯膜具有优异的挤出复合性和拉伸性和高生产率,并且可以提高使用其制造的电池的性能和稳定性。
摘要:
Disclosed herein is a microporous polyethylene film for a battery separator and a method of producing the same. The microporous polyethylene film is made from a resin composition. The resin composition comprises 100 parts by weight of a polyethylene composition including 10-50 wt % polyethylene having a weight average molecular weight of from 2×105 to less than 5×105 (component I) and 90-50 wt % diluent (component II), and 0-150 parts by weight of inorganic powder (component III). The film has a puncture strength of 0.20 N/μm or more and a gas permeability (Darcy's permeability constant) of 1×10−5 Darcy or more. The microporous polyethylene film has excellent physical properties, thus improving the performance and stability of a battery.