摘要:
There is provided a block, segmented or graft copolymer having polyorganosiloxane segments and self-associating hard segments, which copolymer is capable of forming a solid, generally non-tacky release coating without the requirement of curing. The release coating comprises the polyorganosiloxane copolymer admixed with an MQ resin wherein the amount of MQ resin is generally between 1 and 30 weight percent of the polyorganosiloxane content preferably 1 to 20 weight percent. The MQ resin modifies the copolymer release material to have a higher release than the copolymer itself, generally at least 10 percent and preferable at least 20 percent up to 50 percent or higher with the readhesion values decreasing by 50 percent or less, preferably 40 percent or less.
摘要:
Methods of crossliiiking functional and nonfunctional silicones are described. The methods include exposing the silicones to ultraviolet radiation having a spectrum comprising at least one intensity peak below 240 nm in an inert atmosphere. Articles prepared by such methods, including release liners and adhesive articles are also described.
摘要:
Pressure sensitive adhesives comprising an acrylate polymer and surface-modified nanoparticles are described. The surface-modified nanoparticles comprise a nanoparticle having a silica surface and surface modifying groups covalently attached to the silica surface. At least one surface-modifying group is a polymeric silane surface modifying group. At least one surface-modifying group is a non-polymeric silane surface modifying group. Methods of preparing such adhesives, including their exposure to UVA and UVC radiation are also described.
摘要:
Methods of preparing hybrid aerogels are described. The methods include co-condensing a metal oxide precursor and an organo-functional metal oxide precursor, and crosslinking the organo-functional groups with an ethylenically-unsaturated crosslink agent. Thermal energy and actinic radiation crosslinking are described. Both supercritical aerogel and xerogels, including hydrophobic supercritical aerogel and xerogels, are described. Aerogel articles, including flexible aerogel articles are also disclosed.
摘要:
Methods of forming hybrid aerogels are described. The methods include forming a hybrid aerogel from a metal oxide precursor and a branched telechelic copolymer, e.g., co-hydrolyzing and co-condensing the metal oxide precursor and the branched telechelic copolymer. Aerogels and aerogel articles, including hydrophobic aerogels and hydrophobic aerogel articles are also described.
摘要:
Methods of making cut adhesive articles are described. The methods involve: providing a crosslinked pressure sensitive adhesive layer disposed on a substrate, embossing a surface of the crosslinked pressure sensitive adhesive layer to form a microstructured crosslinked pressure sensitive adhesive layer having a microstructured adhesive surface, and die cutting the microstructured crosslinked pressure sensitive adhesive layer.
摘要:
The present invention concerns an extrusion formed reticulated web, mesh or netting including reticulated hook fasteners for use with hook and loop fasteners the polymer netting comprising two sets of strands at angles to each other. The first set of strands are a plurality of oriented (molecular orientation created by stretching) strands extending in a first direction and are generally mutually parallel and linear. The second set of strands are a plurality of substantially parallel strands attached only to a first face of the first set of oriented strands. The first set of oriented strands occupy a first planar cross-sectional area in the thickness direction of the formed netting. Said second set of oriented strands occupy a second planar cross-sectional area in the thickness direction of the formed netting. Preferably, these first and second planar cross-sectional areas are substantially mutually exclusive and are abutting. The polymer netting is preferably made by extruding a thermoplastic resin through a die plate, which die plate is shaped to form a base film layer and spaced ridges or ribs projecting from a surface of the base layer. The spaced ridges or ribs formed by the die form the first set of strands forming the reticulated mesh or netting. The second set of transverse strands are formed by transversely cutting the base layer at spaced locations along a length, at a transverse angle to the ridges or ribs, to form discrete cut portions. Subsequently longitudinal stretching of the ridges (in the direction of the ridges or the machine direction) separates these cut portions of the backing, which cut portion then form the second set of spaced apart strands of the reticulated mesh or netting.
摘要:
The present invention concerns a reticulated web, mesh or netting the polymeric netting comprising two sets of strands at angles to each other and formed from a profile extruded three dimensional film having a first face and a second face. The profile extruded film is cut in regular intervals along the X-dimension on one or more faces or alternatively in alternating fashion on the first face and the second face. The cut film is then stretched (oriented) in the lengthwise dimension creating a nonplanar netting characterized by land portions on the top and bottom surfaces with connecting leg portions extending between the land portion on the top and bottom surfaces.
摘要:
The present invention is directed at a hook strand. These hook strands have a base layer with first top face and a second bottom face and two side faces. Hook elements on the strand extend from at least one face and the hook elements have engaging arms that extend at an angle of from 1 to 90 degrees relative to the longitudinal extent of the strands.
摘要:
There is provided a loop laminate for use in a hook and loop fastening system or a hook and loop fastening system. The loop laminate first comprises a backing layer, having a first face and a second face. The backing layer has a plurality of elevated projections extending from at least the first face of the backing layer wherein some of the projections extend by a distance of at least 50 μm. A loop material is attached to at least some of the projections such that said loop material is raised off the backing layer over at least some portion of the distance between adjacent attached projections to allow for hook heads of hooks to easily penetrate the loop material. The hook fastening material has hooks that are arranged in a manner so as to not substantially engage the projections when the hook fastener is engaged with the loop laminate