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35 条记录 (耗时 0.173 秒)

    Catalytic component and its use in olefin polymerization
    1.
    发明授权
    Catalytic component and its use in olefin polymerization 失效
    催化组分及其在烯烃聚合中的应用

    公开(公告)号：US06433108B1

    公开(公告)日：2002-08-13

    申请号：US09505968

    申请日：2000-02-17

    申请人： Jean Malinge ,  Claude Brun ,  Jean-Loup Lacombe

    发明人： Jean Malinge ,  Claude Brun ,  Jean-Loup Lacombe

    IPC分类号： C08F402

    CPC分类号： C08F10/00 ,  C08F110/02 ,  C08F210/16 ,  C08F4/6555 ,  C08F4/6546 ,  C08F2500/07 ,  C08F2500/04 ,  C08F210/14

    摘要： The invention relates to a process for the manufacture of a solid catalytic component for the polymerization or copolymerization of olefins, resulting in a polymer or copolymer with broadened molecular mass distribution. The process includes a first stage including bringing into contact a) a solid support including at its surface at least 5 hydroxyl groups per square nanometre (OH/nm2) and b) an organic magnesium derivative, and optionally, preferably, c) an aluminoxane, to obtain a first solid, and then a second stage including bringing the first solid and a chlorinating agent into contact to obtain a second solid and then, in a later stage, impregnation of the second solid with a transition metal derivative.

    摘要翻译： 本发明涉及制备用于烯烃聚合或共聚的固体催化剂组分的方法，产生具有扩大分子量分布的聚合物或共聚物。 该方法包括使第一阶段包括接触）固体支持物，其表面包括每平方毫米至少5个羟基（OH / nm 2）和b）有机镁衍生物，和任选地优选c）铝氧烷，以获得 第一固体，然后包括使第一固体和氯化剂接触以获得第二固体，然后在稍后阶段中用过渡金属衍生物浸渍第二固体。

    Process for preparation of a transition metal component for a catalytic system of polymerization of olefins
    3.
    发明授权
    Process for preparation of a transition metal component for a catalytic system of polymerization of olefins 失效
    制备烯烃聚合催化体系的过渡金属组分的方法

    公开(公告)号：US4536484A

    公开(公告)日：1985-08-20

    申请号：US614279

    申请日：1984-05-25

    申请人： Jean-Loup Lacombe ,  Claude Brun

    发明人： Jean-Loup Lacombe ,  Claude Brun

    IPC分类号： C08F4/00 ,  C08F4/60 ,  C08F4/62 ,  C08F4/64 ,  C08F4/659 ,  C08F10/00 ,  C08F4/68

    CPC分类号： C08F10/00 ,  Y10S526/904

    摘要： A process for preparation of a transition metal component of a catalytic system for the polymerization of olefins, wherein an organo-magnesium-aluminum reaction product is formed by bringing into contact, a halogenated, alkylated or alkoxylated magnesium compound with an organo-aluminum compound, then subjecting the reaction product to a chlorination and to a treatment by a compound of a transition metal such as Ti, V, Zr and Cr.As an organo-aluminum compound there is used one or several aluminoxane compounds of the formula ##STR1## wherein R' is an alkyl or from C.sub.1 to C.sub.16, the R"s form together a radical --O-- or designate each a radical R' and n is an integer of from 0 to 20.The transition metal component obtained can be used in combination with a co-catalyst and eventually an electron donor to form a catalytic system apt to polymerize the alpha-olefins.

    摘要翻译： 一种制备用于烯烃聚合的催化体系的过渡金属组分的方法，其中通过与有机铝化合物接触卤代烷基化或烷氧基化镁化合物形成有机镁 - 铝反应产物， 然后对反应产物进行氯化处理，并通过Ti，V，Zr和Cr等过渡金属的化合物进行处理。 作为有机铝化合物，使用一种或几种式IMAMA的铝氧烷化合物，其中R'是烷基或C1至C16，R'的形式一起是基团-O-或表示每个基团R '，n为0至20的整数。所得到的过渡金属组分可以与助催化剂和最终的电子给体结合使用以形成易于聚合α-烯烃的催化体系。

    Process for preparing a catalyst component, resultant catalyst system, and process for synthesis of polymers
    4.
    发明授权
    Process for preparing a catalyst component, resultant catalyst system, and process for synthesis of polymers 失效
    制备催化剂组分，反应催化剂体系的方法和合成聚合物的方法

    公开(公告)号：US5075270A

    公开(公告)日：1991-12-24

    申请号：US872113

    申请日：1986-06-09

    申请人： Claude Brun ,  Jean-Loup Lacombe

    发明人： Claude Brun ,  Jean-Loup Lacombe

    IPC分类号： C08F4/60 ,  C08F4/62 ,  C08F4/64 ,  C08F4/654 ,  C08F4/658 ,  C08F4/659 ,  C08F10/00

    CPC分类号： C08F10/00 ,  Y10S526/901 ,  Y10S526/904

    摘要： A process for preparing a transition metal component for a catalyst system wherein a specified aluminosiloxane derivative is reacted with a monohalopenated, alkylated, or alkoxylated compound of magnesium and the reaction product is chlorinated and reacted with a transition metal; a catalyst system comprising such transition metal component and a cocatalyst selected from organometallic compounds of a metal of Groups I through III of the Periodic Table; and the process of synthesizing olefin homopolymers and copolymers utilizing such catalyst system.

    摘要翻译： 一种制备催化剂体系的过渡金属组分的方法，其中特定的铝硅氧烷衍生物与镁的单卤化，烷基化或烷氧基化的化合物反应，将该反应产物氯化并与过渡金属反应; 包含这种过渡金属组分和选自元素周期表第I至III族金属的有机金属化合物的助催化剂的催化剂体系; 以及利用这种催化剂体系合成烯烃均聚物和共聚物的方法。

    Hydroprocessing catalyst, method for the preparation thereof and use of the same
    7.
    发明授权
    Hydroprocessing catalyst, method for the preparation thereof and use of the same 有权
    加氢处理催化剂，其制备方法及其用途

    公开(公告)号：US07741241B2

    公开(公告)日：2010-06-22

    申请号：US11795519

    申请日：2006-01-19

    申请人： Thierry Cholley ,  Jean-Pierre Dath ,  Claude Brun ,  Georges Fremy ,  Francis Humblot

    发明人： Thierry Cholley ,  Jean-Pierre Dath ,  Claude Brun ,  Georges Fremy ,  Francis Humblot

    IPC分类号： B01J23/88

    CPC分类号： C10G47/12 ,  B01J21/04 ,  B01J23/85 ,  B01J23/882 ,  B01J23/94 ,  B01J31/0202 ,  B01J37/0203 ,  B01J37/20 ,  B01J38/52 ,  C10G45/04 ,  C10G45/08 ,  C10G47/06 ,  C10G47/10 ,  C10G2300/1037 ,  C10G2300/301 ,  C10G2300/44 ,  C10G2300/703

    摘要： The invention relates to a hydrocarbon hydroconversion catalyst comprising a carrier based on refractory oxide, a metal of the group VIII, and a metal of the group VIB. Said catalyst is characterised in that it also comprises at least one organic compound selected from the alkene diols of formula (I) wherein R1 represents a C2-10 alkenylene group, preferably C2-4 alkenylene, a C6-18 arylene group, or a C7-18 alkylene-arylene group, and each R2 independently represents a hydrogen atom or a C1-18 alkyl group, a C1-18 alkenyl group, a C6-18 aryl group, a C3-8 cycloalkyl group, or a C7-20 alkylaryl or arylalkyl group, or the two groups R2 together form a divalent C2-18 group, the carbonated chain of the R2 groups containing or carrying at least one heteroatom selected from S, N and O. The invention also relates to a method for preparing one such catalyst, and to the use of said catalyst for hydrotreatment or hydroconversion.

    摘要翻译： 本发明涉及一种烃加氢转化催化剂，其包含基于难熔氧化物的载体，第Ⅷ族金属和VIB族金属。 所述催化剂的特征在于其还包含至少一种选自式（I）的烯烃二醇的有机化合物，其中R 1表示C 2-10亚烯基，优选C 2-4亚烯基，C 6-18亚芳基或C7 -18亚烷基 - 亚芳基，各R2独立地表示氢原子或C1-18烷基，C1-18烯基，C6-18芳基，C3-8环烷基或C7-20烷基芳基 或芳基烷基，或两个基团R2一起形成二价C 21-18基团，R 2基团的碳酸化链含有或携带至少一个选自S，N和O的杂原子。本发明还涉及一种制备一种 这种催化剂，以及所述催化剂用于加氢处理或加氢转化的用途。

    Process for polymerization in a gaseous phase using heterogeneous catalysis and a spherical reactor for carrying out the process
    8.
    发明授权
    Process for polymerization in a gaseous phase using heterogeneous catalysis and a spherical reactor for carrying out the process 失效
    使用多相催化在气相中聚合的方法和用于进行该方法的球形反应器

    公开(公告)号：US4467080A

    公开(公告)日：1984-08-21

    申请号：US444872

    申请日：1982-11-29

    申请人： Claude Brun ,  Robert Pelletier

    发明人： Claude Brun ,  Robert Pelletier

    IPC分类号： C08F2/00 ,  B01F7/00 ,  B01F7/18 ,  B01F15/00 ,  B01F15/06 ,  B01J8/10 ,  C08F2/34 ,  C08F10/00

    CPC分类号： B01J8/10 ,  B01F15/00798 ,  B01F7/18 ,  C08F10/00 ,  B01F15/06 ,  B01F7/00208 ,  B01F7/00275 ,  B01J2219/187 ,  B01J2219/1942 ,  Y10S526/901 ,  Y10S526/904

    摘要： The invention relates to a process for polymerizing in an aqueous phase using heterogeneous catalysis and to a spherical reactor for carrying out said process. At least one monomer which is gaseous under the reaction conditions is just in contact with a solid catalyst in an agitated polymerization zone. The polymerization zone is defined by a spherical wall and the agitation is effected by means of a turbine unit having blades driven in rotation. The blades extend alongside the wall on 10 to 60% of its surface. The particles of the catalyst and the growing polymer powder are driven by centrifugal force onto at least a part of the spherical wall and fall back into the central part of the spherical zone, thereby ensuring a thorough and uniform mixing without any dead zone. The invention is useful for prepolymerizing or polymerizing olefins.

    摘要翻译： 本发明涉及使用多相催化在水相中聚合的方法和用于进行所述方法的球形反应器。 至少一种在反应条件下为气态的单体在搅拌聚合区中刚好与固体催化剂接触。 聚合区域由球形壁限定，并且通过具有旋转驱动的叶片的涡轮机单元进行搅拌。 叶片沿壁面延伸10至60％的表面。 催化剂和生长的聚合物粉末的颗粒通过离心力驱动到球形壁的至少一部分上并落回球形区域的中心部分，从而确保彻底均匀的混合而没有任何死区。 本发明可用于预聚合或聚合烯烃。

    Process for sulphurization of hydrotreating catalysts
    9.
    发明授权
    Process for sulphurization of hydrotreating catalysts 有权
    加氢处理催化剂硫化工艺

    公开(公告)号：US06325920B1

    公开(公告)日：2001-12-04

    申请号：US09553409

    申请日：2000-04-20

    申请人： Claude Brun ,  Thierry Cholley ,  Geoges Fremy

    发明人： Claude Brun ,  Thierry Cholley ,  Geoges Fremy

    IPC分类号： C10G4504

    摘要： The invention relates to a process for the sulphurization of catalysts for the hydrotreating of hydrocarbon feedstocks. According to the invention, a small amount of at least one orthophthalic acid ester is added to the sulphurization agent used to sulphurize the catalyst. The catalysts thus sulphurized prove to be more active than conventionally sulphurized catalysts.

    摘要翻译： 本发明涉及用于加氢处理烃原料的催化剂的硫化方法。 根据本发明，向用于硫化催化剂的硫化剂中加入少量至少一种邻苯二甲酸酯。 因此，如此硫化的催化剂比常规硫化催化剂更具有活性。