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    Method of colouring keratin-containing fibres
    1.
    发明申请
    Method of colouring keratin-containing fibres 审中-公开
    含角蛋白纤维的着色方法

    公开(公告)号：US20050166337A1

    公开(公告)日：2005-08-04

    申请号：US10505596

    申请日：2003-02-18

    申请人： Jean-Marie Adam ,  Taher Yousaf ,  Beate Frohling

    发明人： Jean-Marie Adam ,  Taher Yousaf ,  Beate Frohling

    IPC分类号： A61K8/40 ,  A61K8/41 ,  A61K8/46 ,  A61Q5/10 ,  A61K7/13 ,  C07C245/02

    CPC分类号： A61K8/466 ,  A61K8/40 ,  A61K8/415 ,  A61Q5/10

    摘要： The present invention relates to a method of colouring keratin-containing fibres comprising applying at least one diazonium compound of formula Ia or Ib, wherein R1 to R5 are each independently of the others C1-C12alkyl, C5-C14aryl, C5-C8cycloalkyl, C6-C20aralkyl, C1-C12alkoxy or C1-C12alkylthio unsubstituted or substituted by one or more halogen atoms, nitro, cyano or alkoxy groups; or hydrogen, halogen, hydroxy, nitro, COOH, SO3H, CN, SCN, C1-C4alkylsulfonyl, phenylsulfonyl, benzylsulfonyl, di-C1-C4alkylaminosulfonyl, C1-C4alkylcarbonylamino, C1-C4alkoxysulfonyl or dihydroxy-C1-C4alkylaminosulfonyl and X− is o−, COO− or SO3−, and at least one coupling component, preferably a a water-soluble to the material to be coloured and causing them to react at a pH in the range of 8 to 12.

    摘要翻译： 本发明涉及一种着色含角蛋白的纤维的方法，包括施用至少一种式Ia或Ib的重氮化合物，其中R 1至R 5各自独立地为 其它C 1 -C 12烷基，C 5 -C 14芳基，C 5 - C 1 -C 8环烷基，C 6 -C 20芳烷基，C 1 -C 3 - 未取代或被一个或多个卤素原子，硝基，氰基或烷氧基取代的C 1 -C 12烷氧基或C 1 -C 12烷硫基; 或氢，卤素，羟基，硝基，COOH，SO 3 H，CN，SCN，C 1 -C 4烷基磺酰基，苯基磺酰基，苄基磺酰基 ，C 1 -C 4烷基氨基磺酰基，C 1 -C 4烷基羰基氨基，C 1 -C 4烷基氨基磺酰基，C 1 -C 4烷基氨基磺酰基，C 1 -C 4烷基氨基磺酰基，C 1 -C 4烷基氨基磺酰基， 烷基磺酰基或二羟基-C 1 -C 4烷基氨基磺酰基和X - 或至少一种偶联组分，优选为水溶性至（Ⅳ） 待着色的物质，使其在8〜12范围内的pH反应。

    Method of coloring porous material
    2.
    发明授权
    Method of coloring porous material 失效
    多孔材料着色方法

    公开(公告)号：US07041143B2

    公开(公告)日：2006-05-09

    申请号：US10469619

    申请日：2002-02-28

    申请人： Jean-Marie Adam ,  Taher Yousaf ,  Beate Fröhling

    发明人： Jean-Marie Adam ,  Taher Yousaf ,  Beate Fröhling

    IPC分类号： A61K7/13 ,  D06P1/02

    CPC分类号： C09B67/0079 ,  C07C245/24

    摘要： A method of coloring porous material, especially human hair, is described, which method comprises applying to the material being colored, in any desired order successively, or simultaneously, a) a capped diazonium compound and b) a water-soluble coupling component under conditions such that, initially, coupling does not take place, and then causing the capped diazonium compound present on the material to react with the coupling component.

    摘要翻译： 描述了多孔材料，特别是人发的着色方法，该方法包括以任何所需的顺序依次或同时施用着色的材料a）封端的重氮化合物和b）在条件下的水溶性偶联组分 使得最初不发生偶合，然后使存在于材料上的封端重氮化合物与偶联组分反应。

    Method of colouring porous material
    4.
    发明申请
    Method of colouring porous material 失效
    多孔材料着色方法

    公开(公告)号：US20050251932A1

    公开(公告)日：2005-11-17

    申请号：US10525300

    申请日：2003-08-26

    申请人： Jean-Marie Adam ,  Taher Yousaf ,  Victor Eliu

    发明人： Jean-Marie Adam ,  Taher Yousaf ,  Victor Eliu

    IPC分类号： A61K8/49 ,  A61Q5/06 ,  A61Q5/10 ,  C07C245/24 ,  C09B67/00 ,  C09B67/36 ,  C07C245/02 ,  C09B1/00

    CPC分类号： A61K8/4966 ,  A61Q5/065 ,  C07C245/24 ,  C09B67/0079

    摘要： A method of colouring porous material, especially human hair, is described, which method comprises applying to the material being coloured, in any desired order successively, or simultaneously, a) at least one capped diazonium compound of Formula (1) and/or at least one compound of Formula (2) and/or at least one compound of Formula (3) wherein Q is an unsubstituted or substituted aromatic or heterocyclic residue, R is the radical of an unsubstituted or substituted, water-soluble aliphatic or aromatic amine, and T is an unsubstituted or substituted, water-soluble aliphatic or aromatic residue, wherein at least one of the groups must contain a radical imparting water solubility, and a) at least one water-soluble coupling component under conditions such that, initially, coupling does not take place, and then causing the capped diazonium compound present on the material to react with the coupling component.

    摘要翻译： 描述了一种着色多孔材料，特别是人发的方法，该方法包括以任何所需顺序依次或同时施用着色的材料，a）至少一种式（1）的封端重氮化合物和/或在 至少一种式（2）的化合物和/或至少一种式（3）的化合物，其中Q是未取代或取代的芳族或杂环残基，R是未取代或取代的水溶性脂族或芳族胺的基团， 并且T是未取代或取代的水溶性脂族或芳族残基，其中所述基团中的至少一个必须含有自由基赋予水溶性，和a）至少一种水溶性偶联组分， 不会发生，然后使存在于材料上的覆盖的重氮化合物与偶联组分反应。

    Method of coloring porous material
    5.
    发明授权
    Method of coloring porous material 失效
    多孔材料着色方法

    公开(公告)号：US07232467B2

    公开(公告)日：2007-06-19

    申请号：US10525300

    申请日：2003-08-26

    申请人： Jean-Marie Adam ,  Taher Yousaf ,  Beate Fröhling ,  Victor Paul Eliu

    发明人： Jean-Marie Adam ,  Taher Yousaf ,  Beate Fröhling ,  Victor Paul Eliu

    IPC分类号： A61K7/13

    CPC分类号： A61K8/4966 ,  A61Q5/065 ,  C07C245/24 ,  C09B67/0079

    摘要： A method of colouring porous material, especially human hair, is described, which method comprises applying to the material being coloured, in any desired order successively, or simultaneously, a) at least one capped diazonium compound of Formula (1) and/or at least one compound of Formula (2) and/or at least one compound of Formula (3) wherein Q is an unsubstituted or substituted aromatic or heterocyclic residue, R is the radical of an unsubstituted or substituted, water-soluble aliphatic or aromatic amine, and T is an unsubstituted or substituted, water-soluble aliphatic or aromatic residue, wherein at least one of the groups must contain a radical imparting water solubility, and a) at least one water-soluble coupling component under conditions such that, initially, coupling does not take place, and then causing the capped diazonium compound present on the material to react with the coupling component

    摘要翻译： 描述了一种着色多孔材料，特别是人发的方法，该方法包括以任何所需顺序依次或同时施用着色的材料，a）至少一种式（1）的封端重氮化合物和/或在 至少一种式（2）的化合物和/或至少一种式（3）的化合物，其中Q是未取代或取代的芳族或杂环残基，R是未取代或取代的水溶性脂族或芳族胺的基团， 并且T是未取代或取代的水溶性脂族或芳族残基，其中所述基团中的至少一个必须含有自由基赋予水溶性，和a）至少一种水溶性偶联组分， 不会发生，然后使存在于材料上的覆盖的重氮化合物与偶联组分反应

    Method of coloring keratin-containing fibres using diazonium salts
    6.
    发明授权
    Method of coloring keratin-containing fibres using diazonium salts 失效
    使用重氮盐对含角蛋白的纤维进行着色的方法

    公开(公告)号：US07192453B2

    公开(公告)日：2007-03-20

    申请号：US10492325

    申请日：2002-10-08

    申请人： Jean-Marie Adam ,  Taher Yousaf

    发明人： Jean-Marie Adam ,  Taher Yousaf

    IPC分类号： A61K7/13

    CPC分类号： A61K8/494 ,  A61K8/415 ,  A61Q5/065

    摘要： The present invention relates to a method of coloring keratin-containing fibres, especially human hair, in which method a compound of formula (I), wherein R is hydroxy or NHR1, R1 being hydrogen or C1–C4alkyl, and B is an aromatic or heterocyclic ring, is diazotised, and the resulting diazonium salt is applied at a pH of from 2 to 5 to the material being colored and then, by means of increasing the pH to from 7 to 12, is fixed on the material in the form of an oligomeric or polymeric colorant

    摘要翻译： 本发明涉及一种着色含角蛋白的纤维，特别是人类头发的方法，其中式（I）化合物，其中R是羟基或NHR 1，R 1， / SUB>为氢或C 1 -C 4烷基，B为芳族或杂环，被重氮化，所得重氮盐的pH为 从2至5对被着色的材料，然后通过将pH升高至7至12，以低聚或聚合着色剂的形式固定在材料上

    New compounds, a process for their preparation and their use as dyes and pigments
    8.
    发明申请
    New compounds, a process for their preparation and their use as dyes and pigments 审中-公开
    新化合物，其制备方法及其作为染料和颜料的用途

    公开(公告)号：US20060124017A1

    公开(公告)日：2006-06-15

    申请号：US10548360

    申请日：2004-03-10

    申请人： Jean-Marie Adam ,  Pramod Dalvi ,  Vadiraj Ekkundi ,  Jean-Pierre Bacher ,  Dandip Tiwari

    发明人： Jean-Marie Adam ,  Pramod Dalvi ,  Vadiraj Ekkundi ,  Jean-Pierre Bacher ,  Dandip Tiwari

    IPC分类号： G03G15/32

    CPC分类号： G03G9/0906 ,  B41M1/04 ,  B41M1/06 ,  B41M1/12 ,  B41M3/14 ,  B41M2205/06 ,  C07D233/96 ,  C07D263/42 ,  C07D307/34 ,  C09B23/04 ,  C09B23/102 ,  C09B55/003 ,  C09D7/41 ,  C09D11/037 ,  C09D11/328 ,  G03G9/0916 ,  G03G9/0924 ,  G11B7/246

    摘要： Compounds of formula (1) wherein R1 is hydrogen, hydroxy, halogen, nitro, cyano, amino, carboxy, carboxylic ester, sulfo, sulfonic ester, carboxylic amide, sulfonic amide, alkoxy, aryloxy, alkylthio or arylthio, X is —O—, —S—, —NH— or —N(alkyl)-, Y is hydrogen or carboxylic ester, Z is ═C— or ═N—, T is ═C— or ═N—, R2 is hydrogen, alkyl or CN, n is 0 or 1, when Z is ═N— then n is 0, m is 0 or 1, when T is ═N— then m is 0, A is a heterocyclic or linear or polycondensed aromatic group which is unsubstituted or substituted by hydroxy alkyl, halogen, nitro, cyano, amino, acylamino, carboxylic ester, sulfonic ester, carboxylic amide, sulfonic amide, alkoxy, aryloxy, alkylthio, arylthio or phenyl, or A together with T and R2 can form an allycyclic or heterocyclic ring, their preparation and their use in the production of coloured plastics or polymeric colour particles.

    摘要翻译： 式（1）的化合物，其中R 1是氢，羟基，卤素，硝基，氰基，氨基，羧基，羧酸酯，磺基，磺酸酯，羧酸酰胺，磺酰胺，烷氧基，芳氧基，烷硫基 或芳硫基，X是-O - ， - S-，-NH-或-N（烷基） - ，Y是氢或羧酸酯，Z是-C-或-N-，T是-C-或-N- R 2为氢，烷基或CN，n为0或1，当Z为-N-时，则n为0，m为0或1，当T为-N-时，m为0 A是未被取代或被羟基烷基，卤素，硝基，氰基，氨基，酰基氨基，羧酸酯，磺酸酯，羧酸酰胺，磺酰胺，烷氧基，芳氧基，烷硫基，芳硫基或芳氧基取代的杂环或直链或缩缩芳族基团 苯基或A与T和R 2一起可以形成烯丙基或杂环，它们的制备及其在生产有色塑料或聚合物着色颗粒中的用途。

    Dye mixtures and the use thereof
    9.
    发明授权
    Dye mixtures and the use thereof 失效
    染料混合物及其用途

    公开(公告)号：US6030420A

    公开(公告)日：2000-02-29

    申请号：US207540

    申请日：1998-12-08

    申请人： Jean-Marie Adam

    发明人： Jean-Marie Adam

    IPC分类号： C09B1/34 ,  C09B29/00 ,  C09B67/22 ,  D06P1/40 ,  D06P1/96 ,  D06P3/14 ,  D06P3/24 ,  D06P3/87 ,  D06P5/00

    CPC分类号： C09B67/0038 ,  D06P1/40 ,  D06P1/96 ,  Y10S8/924

    摘要： The invention relates to dye mixtures comprising at least one dye of formula (1) ##STR1## wherein R.sub.1 is hydrogen, C.sub.1 -C.sub.4 alkyl or C.sub.1 -C.sub.4 alkoxy and R.sub.2 is hydrogen or C.sub.1 -C.sub.4 alkyl, together with at least one dye of formula (2) ##STR2## wherein R.sub.3 is hydrogen, C.sub.1 -C.sub.4 alkyl or C.sub.1 -C.sub.4 alkoxy, R.sub.4 is hydrogen or C.sub.1 -C.sub.4 alkyl and R.sub.5 is C.sub.2 -C.sub.6 alkyl uninterrupted or interrupted by oxygen, with the proviso that R.sub.1 is not methyl when R.sub.2, R.sub.3 and R.sub.4 are hydrogen and R.sub.5 is ethyl.The dye mixtures are suitable for dyeing or printing natural or synthetic polyamide fibre materials, especially in combination with other dyes and especially from short liquors. The dye mixture is distinguished by generally good properties, especially good uptake and good solubility.

    摘要翻译： 本发明涉及包含至少一种式（1）的染料的染料混合物，其中R1是氢，C1-C4烷基或C1-C4烷氧基，R2是氢或C1-C4烷基，以及至少一种式（2）的染料，其中R3 是氢，C 1 -C 4烷基或C 1 -C 4烷氧基，R 4是氢或C 1 -C 4烷基，R 5是不间断或被中断的C 2 -C 6烷基，条件是当R 2，R 3和R 4是氢时，R 1不是甲基，R 5是乙基 。 染料混合物适用于染色或印刷天然或合成聚酰胺纤维材料，特别是与其他染料，尤其是短酒混合。 染料混合物通常具有良好的性能，特别是良好的吸收性和良好的溶解性。

    Process for trichromatic dyeing or printing
    10.
    发明授权
    Process for trichromatic dyeing or printing 失效
    三色染色或印刷方法

    公开(公告)号：US5630851A

    公开(公告)日：1997-05-20

    申请号：US609217

    申请日：1996-03-01

    申请人： Guido Jordine ,  Jean-Marie Adam

    发明人： Guido Jordine ,  Jean-Marie Adam

    IPC分类号： C09B29/01 ,  C09B29/30 ,  C09B67/22 ,  D06P3/16 ,  D06P3/24

    CPC分类号： C09B67/0051 ,  C09B29/0007 ,  C09B29/30 ,  D06P3/16 ,  D06P3/241 ,  Y10S8/917 ,  Y10S8/924

    摘要： A process for dyeing or printing polyamide material by the trichromatic technique using a dye mixture which contains least two yellow- or orange-dyeing dyes of formula (1) ##STR1## wherein R.sub.1 is hydrogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy or halogen, and X is hydrogen or C.sub.1 -C.sub.4 alkyl; together with at least one red-dyeing dye of formulae (2) and (3) ##STR2## wherein R.sub.2 is C.sub.1 -C.sub.6 alkyl, phenyl or cyclohexyl and R.sub.3 is C.sub.1 -C.sub.6 alkyl, or wherein R.sub.2 and R.sub.3, together with the linking nitrogen atom, form an azepinyl ring, and R.sub.4 is hydrogen, C.sub.2 -C.sub.4 alkanoylamino or halogen; and together with at least one of the blue-dyeing dyes of formulae (4) and (5) ##STR3## wherein R.sub.5 is hydrogen or C.sub.1 -C.sub.4 alkyl, R.sub.6 is C.sub.1 -C.sub.4 alkyl or amino, R.sub.7 is hydrogen or methyl, and R.sub.8 is a C.sub.2-4 hydroxyalkylsulfamoyl radical, is disclosed.

    摘要翻译： 一种通过三色技术使用含有至少两种式（1）的黄色或橙色染色染料（1）的染料混合物染色或印刷聚酰胺材料的方法，其中R1是氢，C1-C4烷基，C1-C4烷氧基 或卤素，X为氢或C 1 -C 4烷基; 连同至少一种式（2）和（3）的染色染料，烷基，苯基或环己基，R 3是C 1 -C 6烷基，或其中R 2和R 3与连接氮原子一起形成吖庚因环，R 4 是氢，C 2 -C 4烷酰基氨基或卤素; 并且与至少一种式（4）和（5）的染色染料中的至少一种（5）其中R 5是氢或C 1 -C 4烷基，R 6是C 1 -C 4烷基或氨基， R7是氢或甲基，R8是C2-4羟烷基氨磺酰基。