2-Hydroxy,alkoxy,methylolbenzophenone intermediate compounds for the
manufacture of improved copolymerizable ultraviolet light absorber
compounds
    8.
    发明授权
    2-Hydroxy,alkoxy,methylolbenzophenone intermediate compounds for the manufacture of improved copolymerizable ultraviolet light absorber compounds 失效
    2-羟基,烷氧基,羟甲基二苯甲酮中间体化合物,用于制备改进的可共聚紫外光吸收剂化合物

    公开(公告)号:US4302606A

    公开(公告)日:1981-11-24

    申请号:US153107

    申请日:1980-05-23

    摘要: This invention relates to 2-hydroxy,alkoxy,methylolbenzophenone intermediate compounds for the manufacture of copolymerizable ultraviolet light absorber compounds. The intermediates have the formula: ##STR1## where R is alkyl C.sub.1 -C.sub.8, andn is 1 or 2.The intermediate compounds herein are prepared by converting a 2-hydroxy,alkoxy,benzophenone to the corresponding methylol derivative by a formylation reaction.In the preferred embodiments of the invention, the alkoxy group is methoxy in the 4-position, and methylol is a monomethylol group located at the 3- or 5- position of the phenyl ring containing the hydroxy group.The intermediates of this invention can be transformed into useful copolymerizable ultraviolet light absorber compounds by monoesterification with an .alpha.,.beta.-unsaturated dicarboxylic acid anhydride to produce the corresponding polymerizable half-ester compound, or by esterification with an acryloyl halide to form corresponding acrylate compound. Copolymerization of such compounds with vinyl monomers provide improved ultraviolet light stable copolymers for industrial and commercial applications.

    摘要翻译: 本发明涉及用于制造可共聚紫外光吸收剂化合物的2-羟基,烷氧基,羟甲基二苯甲酮中间体化合物。 中间体具有下式:其中R是烷基C1-C8,n是1或2.这些中间体化合物是通过甲酰化反应将2-羟基,烷氧基,二苯甲酮转化成相应的羟甲基衍生物来制备的。 在本发明的优选实施方案中,烷氧基是4-位甲氧基,羟甲基是位于含有羟基的苯环的3-或5-位上的一羟甲基。 本发明的中间体可以通过与α,β-不饱和二羧酸酐的酯化反应转化成有用的可共聚的紫外线吸收剂化合物,以产生相应的可聚合的半酯化合物,或通过用丙烯酰卤酯化形成相应的丙烯酸酯化合物。 这些化合物与乙烯基单体的共聚提供了用于工业和商业应用的改进的紫外光稳定的共聚物。