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公开(公告)号：US07718838B2
公开(公告)日：2010-05-18
申请号：US11637407
申请日：2006-12-12
申请人： William M. Woodard , Warren M. Ewert , Harvey D. Hensley , Mark E. Lashier , Glyndal D. Cowan , Jeffrey W. Freeman , Ralph V. Franklin , Ronald D. Knudsen , Richard L. Anderson , Lyle R. Kallenbach , Bruce E. Kreischer
发明人： William M. Woodard , Warren M. Ewert , Harvey D. Hensley , Mark E. Lashier , Glyndal D. Cowan , Jeffrey W. Freeman , Ralph V. Franklin , Ronald D. Knudsen , Richard L. Anderson , Lyle R. Kallenbach , Bruce E. Kreischer
IPC分类号： C07C2/26
CPC分类号： B01J31/122 , B01J31/0231 , B01J31/04 , B01J31/143 , B01J31/181 , B01J2231/20 , B01J2531/62 , C07C2/30 , C07C2527/08 , C07C2527/10 , C07C2527/126 , C07C2527/135 , C07C2531/02 , C07C2531/14 , C07C2531/22 , Y02P20/584 , C07C11/107
摘要： A process is provided to stabilize and/or reactivate an olefin production catalyst system which comprises contacting an olefin production catalyst system, either before or after use, with an aromatic compound.
摘要翻译： 提供了一种稳定和/或重新活化烯烃生产催化剂体系的方法，其包括将烯烃生产催化剂体系在使用前或使用后与芳族化合物接触。
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公开(公告)号：US07157612B2
公开(公告)日：2007-01-02
申请号：US10872250
申请日：2004-06-18
申请人： Warren M. Ewert , William M. Woodard , Harvey D. Hensley , Mark E. Lashier , Glyndal D. Cowan , Jeffrey W. Freeman , Ralph V. Franklin , Ronald D. Knudsen , Richard L. Anderson , Lyle R. Kallenbach , Bruce E. Kreischer
发明人： Warren M. Ewert , William M. Woodard , Harvey D. Hensley , Mark E. Lashier , Glyndal D. Cowan , Jeffrey W. Freeman , Ralph V. Franklin , Ronald D. Knudsen , Richard L. Anderson , Lyle R. Kallenbach , Bruce E. Kreischer
CPC分类号： B01J31/122 , B01J31/0231 , B01J31/04 , B01J31/143 , B01J31/181 , B01J2231/20 , B01J2531/62 , C07C2/30 , C07C2527/08 , C07C2527/10 , C07C2527/126 , C07C2527/135 , C07C2531/02 , C07C2531/14 , C07C2531/22 , Y02P20/584 , C07C11/107
摘要： A process is provided to stabilize and/or reactivate an olefin production catalyst system which comprises contacting an olefin production catalyst system, either before or after use, with an aromatic compound.
摘要翻译： 提供了一种稳定和/或重新活化烯烃生产催化剂体系的方法，其包括将烯烃生产催化剂体系在使用前或使用后与芳族化合物接触。
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公开(公告)号：US06455648B1
公开(公告)日：2002-09-24
申请号：US09474067
申请日：1999-12-29
申请人： Jeffrey W. Freeman , Warren M. Ewert , Bruce E. Kreischer , Ronald D. Knudsen , Glyndal D. Cowan
发明人： Jeffrey W. Freeman , Warren M. Ewert , Bruce E. Kreischer , Ronald D. Knudsen , Glyndal D. Cowan
IPC分类号： C08F478
CPC分类号： B01J31/04 , B01J31/0244 , B01J31/122 , B01J31/143 , B01J2231/20 , B01J2531/62 , C07C2/30 , C07C2/32 , C07C2527/132 , C07C2531/02 , C07C2531/04 , C07C2531/12 , C07C2531/22
摘要： A process is provided which comprises preparing an olefin oligomerization or trimerization catalyst system and producing olefins in the presence of the olefin oligomerization or trimerization catalyst system and a solvent, wherein said catalyst system preparation comprises the steps of first contacting a chromium source and a pyrrole-containing compound to form a chromium/pyrrole mixture; second, contacting said chromium/pyrrole mixture with a metal alkyl to form a catalyst system; and then contacting said catalyst system with an alpha-olefin, preferably ethylene.
摘要翻译： 提供了一种方法，其包括在烯烃低聚或三聚催化剂体系和溶剂的存在下制备烯烃低聚或三聚催化剂体系和生产烯烃，其中所述催化剂体系制备包括以下步骤：首先使铬源和吡咯 - 以形成铬/吡咯混合物; 第二，使所述铬/吡咯混合物与烷基金属接触以形成催化剂体系; 然后使所述催化剂体系与α-烯烃（优选乙烯）接触。
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公开(公告)号：US5919996A
公开(公告)日：1999-07-06
申请号：US170713
申请日：1998-10-13
CPC分类号： C07C2/30 , B01J31/122 , B01J31/128 , B01J31/143 , B01J31/181 , B01J2231/20 , B01J2531/62 , C07C2527/132 , C07C2531/04 , C07C2531/12 , C07C2531/14 , C07C2531/22
摘要： A process is provided to modify an olefin production catalyst system which comprises contacting an olefin production catalyst system with ethylene prior to use. A process also is provided to trimerize and/or oligomerize olefins with the novel, modified olefin catalyst production system. The modified olefin production catalyst system produces less solids, such as, for example, polymer.
摘要翻译： 提供了一种改进烯烃生产催化剂体系的方法，其包括使烯烃生产催化剂体系与乙烯接触。 提供了一种使用新的改性烯烃催化剂生产系统使烯烃三聚和/或低聚的方法。 改性烯烃生产催化剂体系产生较少的固体，例如聚合物。
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公开(公告)号：US5689028A
公开(公告)日：1997-11-18
申请号：US573655
申请日：1995-12-18
IPC分类号： C08F2/00 , B01J31/40 , C07C2/08 , C07C2/30 , C07C7/00 , C07C7/148 , C07C7/17 , C07C7/171 , C07C11/00 , C08F4/60 , C08F4/64 , C07C2/24 , B01J31/00
CPC分类号： B01J31/181 , B01J31/04 , B01J31/122 , B01J31/143 , B01J31/223 , B01J31/2234 , B01J31/4015 , C07C2/30 , C07C7/005 , C07C7/1485 , C07C7/17 , C07C7/171 , B01J2231/20 , B01J2531/62 , B01J31/0244 , B01J31/2208 , B01J31/34 , C07C2531/02 , C07C2531/14 , Y02P20/584
摘要： A process is provided to inhibit trimerization catalyst system activity which comprises the sequential steps of contacting a reactor effluent stream with alcohol; removing any desired olefin products; adding an aqueous base to the non-olefin portion; removing a precipitate; separating the aqueous and organic phases; and adding an acid to the aqueous phase.
摘要翻译： 提供了一种抑制三聚催化剂体系活性的方法，其包括使反应器流出物流与醇接触的顺序步骤; 去除任何所需的烯烃产物; 向所述非烯烃部分加入碱水溶液; 去除沉淀物; 分离水相和有机相; 并向水相中加入酸。
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公开(公告)号：US5856257A
公开(公告)日：1999-01-05
申请号：US857787
申请日：1997-05-16
CPC分类号： C07C2/30 , B01J31/122 , B01J31/128 , B01J31/143 , B01J31/181 , B01J2231/20 , B01J2531/62 , C07C2527/132 , C07C2531/04 , C07C2531/12 , C07C2531/14 , C07C2531/22
摘要： A process is provided to modify an olefin production catalyst system which comprises contacting an olefin production catalyst system with ethylene prior to use. A process also is provided to trimerize and/or oligomerize olefins with the novel, modified olefin catalyst production system. The modified olefin production catalyst system produces less solids, such as, for example, polymer.
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公开(公告)号：US5563312A
公开(公告)日：1996-10-08
申请号：US444479
申请日：1995-05-19
IPC分类号： C08F2/00 , B01J31/02 , B01J31/04 , B01J31/12 , B01J31/18 , B01J31/22 , B01J31/30 , C07C2/08 , C07C2/30 , C07C2/32 , C07C11/107 , C08F4/22 , C08F4/60 , C08F4/69 , C07C2/24
CPC分类号： B01J31/04 , B01J31/0244 , B01J31/122 , B01J31/128 , B01J31/143 , B01J31/223 , B01J31/4007 , B01J2231/20 , B01J2531/62
摘要： A process is provided to stabilize and/or reactivate an olefin production catalyst system which comprises contacting an olefin production catalyst system, either before or after use, with an aromatic compound.
摘要翻译： 提供了一种稳定和/或重新活化烯烃生产催化剂体系的方法，其包括将烯烃生产催化剂体系在使用前或使用后与芳族化合物接触。
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公开(公告)号：US5543375A
公开(公告)日：1996-08-06
申请号：US198331
申请日：1994-02-18
IPC分类号： C08F2/00 , B01J31/02 , B01J31/04 , B01J31/12 , B01J31/18 , B01J31/22 , B01J31/30 , C07C2/08 , C07C2/30 , C07C2/32 , C07C11/107 , C08F4/22 , C08F4/60 , C08F4/69 , B01J31/34
CPC分类号： B01J31/04 , B01J31/0244 , B01J31/122 , B01J31/128 , B01J31/143 , B01J31/223 , B01J31/4007 , B01J2231/20 , B01J2531/62
摘要： A process is provided to stabilize and/or reactivate an olefin production catalyst system which comprises contacting an olefin production catalyst system, either before or after use, with an aromatic compound.
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公开(公告)号：US5376612A
公开(公告)日：1994-12-27
申请号：US109858
申请日：1993-08-20
IPC分类号： B01J23/26 , B01J31/14 , B01J31/16 , B01J31/18 , B01J31/22 , B01J37/02 , C07C2/32 , C07F11/00 , C08F4/69 , C08F4/78 , C08F10/00
CPC分类号： B01J31/2208 , B01J23/26 , B01J31/1616 , B01J31/181 , B01J31/2213 , B01J37/0203 , C07C2/32 , C07F11/005 , C08F10/00 , B01J2231/20 , B01J2531/0205 , B01J2531/62 , B01J31/143 , B01J31/2234 , C07C2531/12 , C07C2531/22 , Y02P20/588
摘要： Novel chromium-containing compounds, such as, for example, chromium pyrrolides, are prepared by forming a mixture of a chromium salt, a metal amide, and an electron pair donor solvent, such as, for example, an ether. These novel chromium-containing, or chromium pyrrolide, compounds can be used either unsupported or supported on an inorganic oxide support, with a metal alkyl and an unsaturated hydrocarbon, to trimerize, oligomerize, and/or polymerize olefins.
摘要翻译： 通过形成铬盐，金属酰胺和电子对供体溶剂（例如醚）的混合物来制备新的含铬化合物，例如吡咯化铬。 这些新颖的含铬或铬吡咯化合物可以无支撑或负载在无机氧化物载体上，与金属烷基和不饱和烃一起使用以使烯烃三聚，低聚和/或聚合。
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公开(公告)号：US5786431A
公开(公告)日：1998-07-28
申请号：US478126
申请日：1995-06-07
IPC分类号： C07C2/32 , C08F4/69 , C08F10/00 , C08F110/02
CPC分类号： C08F10/00 , C07C2/32 , C07C2531/22 , C08F110/02
摘要： Novel chromium-containing compounds are prepared by forming a mixture of a chromium salt, a metal amide, and an ether. These novel chromium-containing, or chromium pyrrolide, compounds, with a metal alkyl and an unsaturated hydrocarbon, can be used as a cocatalyst system in the presence of an olefin polymerization catalyst system to produce a comonomer in-situ. The resultant polymer, although produced from predominately one monomer, has characteristics of a copolymer.
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