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    Processless direct write printing plate having heat sensitive crosslinked vinyl polymer with organoonium group and methods of imaging and printing
    1.
    发明授权
    Processless direct write printing plate having heat sensitive crosslinked vinyl polymer with organoonium group and methods of imaging and printing 有权
    具有热敏性交联乙烯基聚合物与无机组的无过程直写式印版和成像和印刷方法

    公开(公告)号：US06190830B1

    公开(公告)日：2001-02-20

    申请号：US09309999

    申请日：1999-05-11

    申请人： Jeffrey W. Leon ,  Gary M. Underwood ,  James C. Fleming

    发明人： Jeffrey W. Leon ,  Gary M. Underwood ,  James C. Fleming

    IPC分类号： G03F7004

    CPC分类号： B41C1/1041 ,  B41M5/368

    摘要： An imaging member, such as a negative-working printing plate, can be prepared using a hydrophilic heat-sensitive imaging layer comprised of a hydrophilic heat-sensitive, crosslinked vinyl polymer containing recurring organoonium groups. The imaging member can also include a photothermal conversion material such as carbon black or an infrared radiation absorbing dye. The heat-sensitive polymer has recurring units containing an organoammonium, organophosphonium or organosulfonium group that reacts to provide increased oleophilicity (ink receptivity) in response to heat. Heat is preferably generated by laser irradiation in the IR region of the electromagnetic spectrum. The heat-sensitive polymer is considered “switchable” in response to heat. The imaging member can be used in printing methods without the usual wet processing steps.

    摘要翻译： 可以使用由含有重复有机基团的亲水性热敏交联乙烯基聚合物构成的亲水性热敏成像层来制备成像构件，例如负性印刷版。 成像构件还可以包括光热转换材料，例如炭黑或红外辐射吸收染料。 热敏聚合物具有含有有机铵，有机鏻或有机锍基团的重复单元，其响应于热而反应以提供增加的亲油性（吸墨性）。 热量优选通过激光照射在电磁光谱的IR区域中产生。 热敏聚合物因热而被认为是“可切换的”。 成像构件可以用于印刷方法，而不需要通常的湿法处理步骤。

    Imaging member containing heat switchable polymer and method of use
    2.
    发明授权
    Imaging member containing heat switchable polymer and method of use 失效
    含有热可切换聚合物的成像构件及其使用方法

    公开(公告)号：US06447978B1

    公开(公告)日：2002-09-10

    申请号：US09454151

    申请日：1999-12-03

    申请人： Jeffrey W. Leon ,  James C. Fleming

    发明人： Jeffrey W. Leon ,  James C. Fleming

    IPC分类号： G03F7038

    CPC分类号： B41M5/368 ,  B41C1/1041

    摘要： An imaging member, such as a negative-working printing plate or on-press cylinder, can be prepared using a hydrophilic imaging layer comprised of a heat-sensitive hydrophilic polymer that comprises recurring units comprising quaternary ammonium carboxylate groups. The imaging member can also include an infrared radiation sensitive material to provide added sensitivity to heat that can be supplied by laser irradiation in the IR region. The heat-sensitive polymer is considered “switchable” in response to heat, and provides a lithographic image without wet processing.

    摘要翻译： 可以使用包含热敏亲水性聚合物的亲水性成像层来制备成像构件，例如负性印刷板或压印滚筒，所述亲水性成像层包含包含季铵羧酸盐基团的重复单元。 成像构件还可以包括红外辐射敏感材料，以便通过激光照射在IR区域中提供的热量提供增加的灵敏度。 热敏聚合物被认为是响应于热可“切换”，并提供平版印刷图像而不进行湿法处理。

    Thermal imaging composition and member containing sulfonated IR dye and methods of imaging and printing
    3.
    发明授权
    Thermal imaging composition and member containing sulfonated IR dye and methods of imaging and printing 失效
    热成像组合物和含有磺化红外染料的成分和成像和印刷方法

    公开(公告)号：US06537730B1

    公开(公告)日：2003-03-25

    申请号：US09652344

    申请日：2000-08-31

    申请人： James C. Fleming ,  Jeffrey W. Leon ,  David A. Stegman ,  Kevin W. Williams

    发明人： James C. Fleming ,  Jeffrey W. Leon ,  David A. Stegman ,  Kevin W. Williams

    IPC分类号： G03F7038

    CPC分类号： B41M5/368 ,  B41C1/1041 ,  B41M5/465 ,  Y10S430/106 ,  Y10S430/108 ,  Y10S430/127 ,  Y10S430/145 ,  Y10S430/146 ,  Y10S430/165

    摘要： An imaging member, such as a negative-working printing plate or on-press cylinder, can be prepared with a hydrophilic imaging layer comprised of a heat-sensitive hydrophilic polymer having ionic moieties and an infrared radiation sensitive dye having multiple sulfo groups. The heat-sensitive polymer and IR dye can be formulated in water or water-miscible solvents to provide highly thermal sensitive imaging compositions. In the imaging member, the polymer reacts to provide increased hydrophobicity in areas exposed to energy that provides or generates heat. For example, heat can be supplied by laser irradiation in the IR region of the electromagnetic spectrum. The heat-sensitive polymer is considered “switchable” in response to heat, and provides a lithographic image without wet processing.

    摘要翻译： 可以用由具有离子部分的热敏性亲水性聚合物和具有多个磺基的红外线辐射敏感染料组成的亲水成像层来制备成像部件，例如负性印刷板或压印滚筒。 热敏聚合物和IR染料可以配制在水或水混溶性溶剂中以提供高度热敏成像组合物。 在成像构件中，聚合物在暴露于提供或产生热量的能量的区域中反应以提供增加的疏水性。 例如，可以通过激光照射在电磁光谱的IR区域中提供热量。 热敏聚合物被认为是响应于热可“切换”，并提供平版印刷图像而不进行湿法处理。

    Thermal switchable composition and imaging member containing cationic IR dye and methods of imaging and printing
    4.
    发明授权
    Thermal switchable composition and imaging member containing cationic IR dye and methods of imaging and printing 失效
    含有阳离子IR染料的热可切换组合物和成像构件以及成像和印刷方法

    公开(公告)号：US06410202B1

    公开(公告)日：2002-06-25

    申请号：US09387116

    申请日：1999-08-31

    申请人： James C. Fleming ,  Jeffrey W. Leon ,  David A. Stegman ,  Kevin W. Williams

    发明人： James C. Fleming ,  Jeffrey W. Leon ,  David A. Stegman ,  Kevin W. Williams

    IPC分类号： G03F7038

    CPC分类号： B41M5/465 ,  B41C1/1041 ,  B41M5/368

    摘要： An imaging member, such as a negative-working printing plate or on-press cylinder, can be prepared with a hydrophilic imaging layer comprised of a heat-sensitive hydrophilic polymer having ionic moieties and an infrared radiation sensitive dye having multiple quaternary ammonium groups. The heat-sensitive polymer and IR dye can be formulated in water or water-miscible solvents to provide highly thermal sensitive imaging compositions. In the imaging member, the polymer reacts to provide increased hydrophobicity in areas exposed to energy that provides or generates heat. For example, heat can be supplied by laser irradiation in the IR region of the electromagnetic spectrum. The heat-sensitive polymer is considered “switchable” in response to heat, and provides a lithographic image without wet processing.

    摘要翻译： 可以用由具有离子部分的热敏亲水性聚合物和具有多个季铵基团的红外线辐射敏感染料组成的亲水成像层来制备成像构件，例如负性印刷版或压印滚筒。 热敏聚合物和IR染料可以配制在水或水混溶性溶剂中以提供高度热敏成像组合物。 在成像构件中，聚合物在暴露于提供或产生热量的能量的区域中反应以提供增加的疏水性。 例如，可以通过激光照射在电磁光谱的IR区域中提供热量。 热敏聚合物被认为是响应于热可“切换”，并提供平版印刷图像而不进行湿法处理。

    Processless direct write imaging member containing polymer grafted carbon and methods of imaging and printing
    5.
    发明授权
    Processless direct write imaging member containing polymer grafted carbon and methods of imaging and printing 失效
    含有聚合物接枝碳的无过程直写式成像构件和成像和印刷方法

    公开(公告)号：US06399268B1

    公开(公告)日：2002-06-04

    申请号：US09293389

    申请日：1999-04-16

    申请人： James C. Fleming ,  Jeffrey W. Leon

    发明人： James C. Fleming ,  Jeffrey W. Leon

    IPC分类号： G03C176

    CPC分类号： B41C1/1041 ,  B41M5/368

    摘要： An imaging member, such as a negative-working printing plate or on-press cylinder, can be prepared with a hydrophilic imaging layer comprised of a heat-sensitive hydrophilic polymer having ionic moieties and a polymer grafted carbon as a photothermal conversion material. The heat-sensitive polymer and polymer grafted carbon can be formulated in water or water-miscible solvents without agglomeration. In the imaging member, the polymer reacts to provide increased hydrophobicity in areas exposed to energy that provides or generates heat. For example, heat can be supplied by laser irradiation in the IR region of the electromagnetic spectrum. The heat-sensitive polymer is considered “switchable” in response to heat, and provides a lithographic image without wet processing.

    摘要翻译： 可以由亲水性成像层制备成像构件，例如负性印刷版或压印滚筒，所述亲水成像层由具有离子部分的热敏亲水性聚合物和作为光热转换材料的聚合物接枝碳构成。 热敏聚合物和聚合物接枝碳可以配制成水或水混溶性溶剂而不凝聚。 在成像构件中，聚合物在暴露于提供或产生热量的能量的区域中反应以提供增加的疏水性。 例如，可以通过激光照射在电磁光谱的IR区域中提供热量。 热敏聚合物被认为是响应于热可“切换”，并提供平版印刷图像而不进行湿法处理。

    Processless direct write printing plate having heat sensitive positively-charged polymers and methods of imaging and printing
    6.
    发明授权
    Processless direct write printing plate having heat sensitive positively-charged polymers and methods of imaging and printing 失效
    具有热敏正电聚合物的无过程直写式印版和成像和印刷方法

    公开(公告)号：US06190831B1

    公开(公告)日：2001-02-20

    申请号：US09310038

    申请日：1999-05-11

    申请人： Jeffrey W. Leon ,  Gary M. Underwood ,  James C. Fleming ,  Charles D. Deboer

    发明人： Jeffrey W. Leon ,  Gary M. Underwood ,  James C. Fleming ,  Charles D. Deboer

    IPC分类号： G03F7004

    CPC分类号： B41C1/1041

    摘要： An imaging member, such as a negative-working printing plate, can be prepared using a hydrophilic imaging layer comprised of a heat-sensitive hydrophilic polymer having a positively charged moiety, and optionally a photothermal conversion material. The heat-sensitive polymer has recurring units containing an N-alkylated aromatic heterocyclic group or an organoonium group that reacts to provide increased oleophilicity in areas exposed to energy that provides or generates heat. For example, heat can be supplied by laser irradiation in the IR region of the electromagnetic spectrum. Thus, the heat-sensitive polymer is considered “switchable” in response to heat, and provides an imaging means without wet processing.

    摘要翻译： 可以使用由具有带正电荷的部分的热敏亲水性聚合物和任选的光热转换材料构成的亲水性成像层来制备成像构件，例如负性印刷版。 热敏聚合物具有包含N-烷基化芳族杂环基团或有机基团的重复单元，其在暴露于提供或产生热量的能量的区域中反应以提供增加的亲油性。 例如，可以通过激光照射在电磁光谱的IR区域中提供热量。 因此，热敏聚合物被认为是响应热可“切换”的，并且提供了一种没有湿法处理的成像装置。

    Polymer particle stabilized by dispersant and method of preparation
    10.
    发明授权
    Polymer particle stabilized by dispersant and method of preparation 有权
    通过分散剂稳定的聚合物颗粒和制备方法

    公开(公告)号：US07390844B2

    公开(公告)日：2008-06-24

    申请号：US11080040

    申请日：2005-03-15

    申请人： Jeffrey W. Leon ,  Jeanne E. Kaeding ,  Dennis E. Smith ,  Trevor J. Wear ,  Alan R. Pitt ,  Peter J. Ghyzel

    发明人： Jeffrey W. Leon ,  Jeanne E. Kaeding ,  Dennis E. Smith ,  Trevor J. Wear ,  Alan R. Pitt ,  Peter J. Ghyzel

    IPC分类号： C08J9/00 ,  C08F2/44 ,  C08F2/20 ,  C08F2/24 ,  C08F220/56

    CPC分类号： C08F2/24 ,  C08F2/20

    摘要： The present invention discloses a water dispersible polymer particle stabilized by a hydrophobically capped oligomeric acrylamide dispersant. The present invention also discloses a heterogeneous method for forming polymer particles comprising providing a water immiscible organic phase comprising at least one monomer dispersed in a continuous water phase and a hydrophobically capped oligomeric acrylamide, and polymerizing said organic phase to yield polymer particles stabilized with hydrophobically capped oligomeric acrylamide. Also disclosed in the present invention is a heterogeneous method for forming polymer particles comprising providing a water immiscible organic dispersed in a continuous water phase, polymerizing said organic phase, and adding bydrophobically capped oligomeric acrylamide to yield polymer particles stabilized with hydrophobically capped oligomeric acrylamide.

    摘要翻译： 本发明公开了一种由疏水封端的低聚丙烯酰胺分散剂稳定的水分散性聚合物颗粒。 本发明还公开了一种用于形成聚合物颗粒的非均相方法，其包括提供包含分散在连续水相中的至少一种单体的水不混溶的有机相和疏水封端的低聚丙烯酰胺，并聚合所述有机相以产生用疏水封端稳定的聚合物颗粒 低聚丙烯酰胺。 本发明还公开了一种用于形成聚合物颗粒的非均相方法，包括提供分散在连续水相中的水不混溶的有机相，使所述有机相聚合，并加入疏水性封端的低聚丙烯酰胺，以产生用疏水封端的低聚丙烯酰胺稳定的聚合物颗粒。