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公开(公告)号:US07834215B2
公开(公告)日:2010-11-16
申请号:US11908343
申请日:2006-03-02
申请人: Jens Holz , Armin Boerner , Odalys Esperanza Zayas Vargas , Juan Jose Almena Perea , Axel Monsees , Renat Kadyrov , Thomas Riermeier
发明人: Jens Holz , Armin Boerner , Odalys Esperanza Zayas Vargas , Juan Jose Almena Perea , Axel Monsees , Renat Kadyrov , Thomas Riermeier
IPC分类号: C07F9/6568 , C07F9/572
CPC分类号: C07F9/65683 , B01J31/2409 , B01J31/2419
摘要: The present invention is based on new ligand systems of the general formula (I). These ligand systems can be used advantageously in transition metal-catalyzed asymmetric syntheses. Likewise encompassed are the transition metal complexes thus prepared, a process for preparing the ligands and the use of the complexes in asymmetric synthesis.
摘要翻译: 本发明基于通式(I)的新的配体体系。 这些配体体系可以有利地用于过渡金属催化的不对称合成。 同样包括如此制备的过渡金属络合物,制备配体的方法和配合物在不对称合成中的用途。
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公开(公告)号:US20080200695A1
公开(公告)日:2008-08-21
申请号:US11908343
申请日:2006-03-02
申请人: Jens Holz , Armin Boerner , Odalys Esperanza Zayas Vargas , Juan Jose Almena Perea , Axel Monsees , Renat Kadyrov , Thomas Riermeier
发明人: Jens Holz , Armin Boerner , Odalys Esperanza Zayas Vargas , Juan Jose Almena Perea , Axel Monsees , Renat Kadyrov , Thomas Riermeier
IPC分类号: C07F9/28 , C07D207/00
CPC分类号: C07F9/65683 , B01J31/2409 , B01J31/2419
摘要: The present invention is based on new ligand systems of the general formula (I). These ligand systems can be used advantageously in transition metal-catalysed asymmetric syntheses. Likewise encompassed are the transition metal complexes thus prepared, a process for preparing the ligands and the use of the complexes in asymmetric synthesis.
摘要翻译: 本发明基于通式(I)的新的配体体系。 这些配体体系可以有利地用于过渡金属催化的不对称合成。 同样包括如此制备的过渡金属络合物,制备配体的方法和配合物在不对称合成中的用途。
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公开(公告)号:US07015342B2
公开(公告)日:2006-03-21
申请号:US10511439
申请日:2003-04-17
申请人: Paul Knochel , Matthias Lotz , Axel Monsees , Thomas Riermeier , Renat Kadyrov , Juan Jose Almena Perea
发明人: Paul Knochel , Matthias Lotz , Axel Monsees , Thomas Riermeier , Renat Kadyrov , Juan Jose Almena Perea
CPC分类号: C07F17/02 , C07B53/00 , C07C67/303 , C07C231/18 , C07C233/47 , C07C69/67 , C07C69/34
摘要: The invention relates to ferrocenyl ligands of general formula (II), the Sfc,S-enantiomer or the Rfc,R-enantiomer of the ferrocenyl ligands of formula (II) being enriched, and a method for producing such ligands.
摘要翻译: 本发明涉及通式(II)的二茂铁基配体,式(II)的二茂铁基配体的S-对映异构体或RΨC, ),以及这种配体的制造方法。
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公开(公告)号:US07009065B2
公开(公告)日:2006-03-07
申请号:US10506255
申请日:2003-03-10
申请人: Paul Knochel , Matthias Lotz , Axel Monsees , Thomas Riermeier , Renat Kadyrov , Juan Jose Almena Perea
发明人: Paul Knochel , Matthias Lotz , Axel Monsees , Thomas Riermeier , Renat Kadyrov , Juan Jose Almena Perea
CPC分类号: C07F17/02
摘要: The invention relates to bidentate organophosphorous ferrocenyl ligands containing ligands of formula (I), to their complex compounds and to their utilization in catalytic processes.
摘要翻译: 本发明涉及含有式(I)配位体的双齿有机亚磷酸二茂铁基配体,其复合化合物及其在催化过程中的应用。
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公开(公告)号:US07531697B2
公开(公告)日:2009-05-12
申请号:US11908446
申请日:2006-03-02
申请人: Juan Jose Almena Perea , Axel Monsees , Renat Kadyrov , Thomas Riermeier , Kai Rossen , Wolf-Ruediger Krahnert , Matthias Beller , Stefan Klaus , Alexander Zapf
发明人: Juan Jose Almena Perea , Axel Monsees , Renat Kadyrov , Thomas Riermeier , Kai Rossen , Wolf-Ruediger Krahnert , Matthias Beller , Stefan Klaus , Alexander Zapf
IPC分类号: C07C45/50
CPC分类号: C07C47/55 , B01J31/24 , B01J2531/824 , C07C45/49 , C07C47/575
摘要: (Hetero)aromatic are prepared from halogen-substituted (hetero)aromatic compounds in the presence of a base and a palladium catalyst having a nonpyrophoric monodentate phosphane ligand. The phosphane ligand structure includes two radical groups having a tertiary carbon attached directly to phosphorous and one radical group having a primary carbon attached to the phosphorous.
摘要翻译: (杂芳基)芳族化合物由卤素取代的(杂)芳族化合物在碱和钯催化剂的存在下制备,所述催化剂具有非营养性单齿磷烷配体。 膦配体结构包括具有直接连接到磷上的叔碳原子的两个自由基基团和一个连接到磷上的伯原子的一个基团。
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公开(公告)号:US20080306264A1
公开(公告)日:2008-12-11
申请号:US11579626
申请日:2005-04-14
IPC分类号: C07F9/6553 , C07F9/50 , C07F9/58 , C07F9/655 , C07F9/572
CPC分类号: C07F9/655345 , B01J31/188 , B01J31/2414 , B01J2231/645 , B01J2531/822 , C07B2200/07 , C07C29/145 , C07C45/505 , C07C67/283 , C07C67/303 , C07C231/18 , C07D333/16 , C07D333/28 , C07F9/5027 , C07F9/5532 , C07F9/572 , C07F9/5728 , C07F9/59 , C07F9/60 , C07F9/65031 , C07F9/6506 , C07F9/65335 , C07F9/6547 , C07F9/65515 , C07F9/65517 , C07F9/655354 , C07F9/655372 , C07F9/6561 , C07F17/02 , C07C69/007 , C07C69/34 , C07C233/05 , C07C233/47 , C07C69/157 , C07C33/22
摘要: The present invention concerns novel bidentante optionally N-containing P-ligands of general Formula (I) embracing a two-ring-system and processes for synthesizing them, transition metal complexes of these compounds and their use as catalysts.
摘要翻译: 本发明涉及包含双环体系的通式(I)的任意含N的P-配位体及其合成方法,这些化合物的过渡金属配合物及其作为催化剂的用途的新颖特征。
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公开(公告)号:US20080188691A1
公开(公告)日:2008-08-07
申请号:US11908446
申请日:2006-03-02
申请人: Juan Jose Almena Perea , Axel Monsees , Renat Kadyrov , Thomas Riermeier , Kai Rossen , Wolf-Rudiger Krahnert , Matthias Beller , Stefan Klaus , Alexander Zapf
发明人: Juan Jose Almena Perea , Axel Monsees , Renat Kadyrov , Thomas Riermeier , Kai Rossen , Wolf-Rudiger Krahnert , Matthias Beller , Stefan Klaus , Alexander Zapf
IPC分类号: C07C45/00
CPC分类号: C07C47/55 , B01J31/24 , B01J2531/824 , C07C45/49 , C07C47/575
摘要: The present invention is aimed at a process for the preparation of (hetero)aromatic aldehydes. The aldehydes are obtained from corresponding Hal′-substituted (hetero)aromatics by palladium-catalysed reductive carbonylation in the presence of a specific monodentate phosphane-based ligand system.
摘要翻译: 本发明的目的在于制备(异)芳族醛的方法。 在特定的单齿膦基配体体系的存在下,通过钯催化还原羰基化从相应的Hal'取代的(杂)芳族化合物中获得醛。
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公开(公告)号:US20070123733A1
公开(公告)日:2007-05-31
申请号:US11609606
申请日:2006-12-12
申请人: Armin BOERNER , Jens Holz , Axel Monsees , Thomas Riermeier , Renat Kadyrov , Carsten Schneider , Uwe Dingerdissen , Karlheinz Drauz
发明人: Armin BOERNER , Jens Holz , Axel Monsees , Thomas Riermeier , Renat Kadyrov , Carsten Schneider , Uwe Dingerdissen , Karlheinz Drauz
CPC分类号: B01J31/1658 , B01J31/24 , B01J31/2433 , B01J31/2476 , B01J2231/321 , B01J2231/645 , B01J2531/16 , B01J2531/80 , B01J2531/822 , C07B53/00 , C07C45/505 , C07C45/72 , C07C67/303 , C07C231/18 , C07F9/5027 , C07F9/5537 , C07F9/6506 , C07F9/650994 , C07F9/65515 , C07F9/65683 , C07C69/34
摘要: The present invention relates to ligands of the general formula (I). In addition, a process for the production thereof and the use thereof are demonstrated.
摘要翻译: 本发明涉及通式(I)的配体。 另外,证明了其生产方法及其用途。
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公开(公告)号:US20050209455A1
公开(公告)日:2005-09-22
申请号:US10508537
申请日:2003-03-03
申请人: Armin Boerner , Jens Holz , Axel Monsees , Thomas Riermeier , Renat Kadyrov , Carsten Schneider , Uwe Dingerdissen , Karlheinz Drauz
发明人: Armin Boerner , Jens Holz , Axel Monsees , Thomas Riermeier , Renat Kadyrov , Carsten Schneider , Uwe Dingerdissen , Karlheinz Drauz
IPC分类号: B01J31/24 , C07B53/00 , C07B61/00 , C07C45/50 , C07C45/72 , C07C67/303 , C07C69/34 , C07C231/12 , C07C231/18 , C07C233/49 , C07F9/50 , C07F9/553 , C07F9/6506 , C07F9/6509 , C07F9/655 , C07F9/6568 , C07F15/00 , C07F9/02
CPC分类号: B01J31/1658 , B01J31/24 , B01J31/2433 , B01J31/2476 , B01J2231/321 , B01J2231/645 , B01J2531/16 , B01J2531/80 , B01J2531/822 , C07B53/00 , C07C45/505 , C07C45/72 , C07C67/303 , C07C231/18 , C07F9/5027 , C07F9/5537 , C07F9/6506 , C07F9/650994 , C07F9/65515 , C07F9/65683 , C07C69/34
摘要: The present invention relates to ligands of the general formula (I). In addition, a process for the production thereof and the use thereof are demonstrated.
摘要翻译: 本发明涉及通式(I)的配体。 另外,证明了其生产方法及其用途。
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公开(公告)号:US07589215B2
公开(公告)日:2009-09-15
申请号:US11609559
申请日:2006-12-12
申请人: Armin Boerner , Jens Holz , Axel Monsees , Thomas Riermeier , Renat Kadyrov , Carsten A. Schneider , Uwe Dingerdissen , Karlheinz Drauz
发明人: Armin Boerner , Jens Holz , Axel Monsees , Thomas Riermeier , Renat Kadyrov , Carsten A. Schneider , Uwe Dingerdissen , Karlheinz Drauz
CPC分类号: B01J31/1658 , B01J31/24 , B01J31/2433 , B01J31/2476 , B01J2231/321 , B01J2231/645 , B01J2531/16 , B01J2531/80 , B01J2531/822 , C07B53/00 , C07C45/505 , C07C45/72 , C07C67/303 , C07C231/18 , C07F9/5027 , C07F9/5537 , C07F9/6506 , C07F9/650994 , C07F9/65515 , C07F9/65683 , C07C69/34
摘要: The present invention relates to ligands of the general formula (I). In addition, a process for the production thereof and the use thereof are demonstrated.
摘要翻译: 本发明涉及通式(I)的配体。 另外,证明了其生产方法及其用途。
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