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1.发明授权Process for selective diisopropylation of naphthyl compounds using shape selective acidic crystalline molecular sieve catalysts 失效使用形状选择性酸性结晶分子筛催化剂的萘基化合物的选择性二异丙基化方法
公开(公告)号：US5026942A
公开(公告)日：1991-06-25
申请号：US438496
申请日：1989-12-12
CPC分类号： C07C15/24 , C07C2/66 , C07C6/126 , B01J2229/12 , B01J2229/14 , B01J2229/32 , B01J2229/34 , B01J29/18 , C07C2521/12 , C07C2529/18 , C07C2529/70 , C07C2529/85
摘要： The selective isopropylation of a naphthyl compound to diisopropylnaphthalene enhanced in the 2,6-diisopropylnaphthalene isomer is obtained in the presence of an acidic crystalline molecular sieve catalyst having twelve membered oxygen rings. The catalyst pore aperture dimension range from 5.5 .ANG. to 7.0 .ANG.. The user of these shape selective catalysts results in a diisopropylnephthalene stream which is enhanced in .beta. isomers and enhanced in the desired 2,6-diisopropylnaphthalene isomer. A particularly preferred catalyst is synthetic Mordenite having a specific Si/Al ratio and NMR characteristics. Specific catalyst modifications are also described to improve selectivity to the desired 2,6-diisopropylnaphthalene isomer.
摘要翻译： PCT No.PCT / US89 / 04485第 371日期1989年12月12日 102（e）1989年12月12日PCT PCT日本1989年10月5日。在2,6-二异丙基萘异构体中增强的萘基化合物对二异丙基萘的选择性异丙基化是在具有十二烷酸的酸性结晶分子筛催化剂 元氧环。 催化剂孔径尺寸范围为5.5 ANGSTROM至7.0 ANGSTROM。 这些形状选择性催化剂的用户产生二异丙基萘流，其在β异构体中增强，并增加所需的2,6-二异丙基萘异构体。 特别优选的催化剂是具有特定Si / Al比和NMR特性的合成丝光沸石。 还描述了具体的催化剂修饰以提高对所需2,6-二异丙基萘异构体的选择性。
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2.发明授权Process for selective diisopropylation of naphthyl compounds using shape selective acidic crystalline molecular sieve catalysts 失效使用形状选择性酸性结晶分子筛催化剂的萘基化合物的选择性二异丙基化方法
公开(公告)号：US5003122A
公开(公告)日：1991-03-26
申请号：US254284
申请日：1988-10-05
IPC分类号： B01J29/84 , B01J29/04 , B01J29/06 , B01J29/18 , B01J29/85 , C07B61/00 , C07C2/66 , C07C2/70 , C07C6/12 , C07C15/24
CPC分类号： C07C15/24 , C07C2/66 , C07C6/126 , B01J2229/12 , B01J2229/14 , B01J2229/32 , B01J2229/34 , B01J29/18 , C07C2521/12 , C07C2529/18 , C07C2529/70 , C07C2529/85
摘要： The selective isopropylation of a naphthyl compound to diisopropylnaphthalene enhanced in the 2,6-diisopropylnaphthalene isomer is obtained in the presence of an acidic crystalline molecular sieve catalyst having twelve membered oxygen rings. The catalyst pore aperture dimension ranges from 5.5 .ANG. to 7.0 .ANG.. The use of these shape selective catalysts results in a diisopropylnaphthalene stream which is enhanced in .beta. isomers and enhanced in the desired 2,6-diisopropylnaphthalene isomer. A particularly preferred catalyst is synthetic Mordenite. Specific catalyst modifications are also described to improve selectivity to the desired 2,6-diisopropylnaphthalene isomer.
摘要翻译： 在具有12元氧环的酸性结晶分子筛催化剂的存在下，获得了2,6-二异丙基萘异构体中萘基化合物对二异丙基萘的选择性异丙基化。 催化剂孔径尺寸范围为5.5 ANGSTROM至7.0 ANGSTROM。 使用这些形状选择性催化剂导致二异丙基萘流，其增加了β异构体并且增加了所需的2,6-二异丙基萘异构体。 特别优选的催化剂是合成丝光沸石。 还描述了具体的催化剂修饰以提高对所需2,6-二异丙基萘异构体的选择性。
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公开(公告)号：US4898722A
公开(公告)日：1990-02-06
申请号：US683785
申请日：1984-12-19
IPC分类号： C07C5/27 , B01J29/00 , B01J29/85 , C01B37/08 , C01B39/04 , C01B39/06 , C01B39/20 , C07B61/00 , C07C1/00 , C07C7/13 , C07C15/08 , C07C67/00
CPC分类号： C01B37/08 , B01J29/85 , B01J2229/40 , Y10S423/30
摘要： An improved method for synthesis of improved silicoaluminophosphate SAPO-37 is provided. The method comprises (1) preparing a two-phase reaction mixture containing particular components and comprising both a liquid organic phase and a liquid aqueous phase; (2) heating the reaction mixture at a rate of from 5.degree. C. to 200.degree. C. per hour to a temperature of from 80.degree. C. to 200.degree. C.; agitating the reaction mixture in a manner sufficient to intimately admix said liquid organic and aqueous phases with each other; (4) once nucleation of the silicoaluminophosphate occurs, heating the agitated reaction mixture at rate of from 5.degree. C. to 200.degree. C. per hour to a temperature of from 100.degree. C. to 300.degree. C.; (5) maintaining the agitated reaction mixture at a temperature of from 100.degree. C. to 300.degree. C. and a pH of from 2 to 9 until crystals of the desired silicoaluminophosphate are formed; and (6) recovering silicoaluminophosphate material from the reaction mixture.
摘要翻译： 提供了改进的硅铝磷酸SAPO-37的合成方法。 该方法包括（1）制备含有特定成分并包含液态有机相和液态水相的两相反应混合物; （2）将反应混合物以每小时5℃至200℃的速度加热到80℃至200℃的温度; 以足以使所述液态有机相和水相彼此充分混合的方式搅拌反应混合物; （4）一旦发生硅铝磷酸盐的成核，将搅拌的反应混合物以每小时5℃至200℃的速度加热到100℃至300℃的温度; （5）将搅拌的反应混合物保持在100℃至300℃的温度和2至9℃的pH，直到形成所需硅磷酸铝的晶体; 和（6）从反应混合物中回收硅铝磷酸盐物质。
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公开(公告)号：US4891197A
公开(公告)日：1990-01-02
申请号：US878754
申请日：1986-06-26
IPC分类号： B01J20/18 , B01J23/04 , B01J29/82 , B01J29/84 , B01J29/85 , B01J39/12 , C01B37/06 , C01B37/08
CPC分类号： C01B37/08 , B01J20/18 , B01J23/04 , B01J29/82 , B01J29/84 , B01J29/85 , B01J39/12 , C01B33/28 , C01B37/06 , B01J2229/26 , B01J2229/42
摘要： A method for synthesizing a crystalline silicophosphoaluminate is provided. The composition has ion-exchange properties and is readily convertible to catalytically active material. The synthesis method requires an organic phase, and an aqueous phase. The silicon, phosphorus and aluminum components of the silicophosphoaluminate may, optionally, be replaced with other elements in the plus 4, 5 and 3 valence states, respectively.
摘要翻译： 提供了一种合成硅磷硅铝酸盐的方法。 该组合物具有离子交换性质并且易于转化为催化活性材料。 合成方法需要有机相和水相。 硅磷硅铝酸盐的硅，磷和铝组分可以任选地分别以加号4,5和3价态的其它元素代替。
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公开(公告)号：US4639357A
公开(公告)日：1987-01-27
申请号：US685172
申请日：1984-12-21
CPC分类号： B01J20/18 , B01J29/85 , B01J39/12 , C01B33/28 , C01B37/08 , B01J2229/26 , B01J2229/42 , Y10S423/30
摘要： A new crystalline silicophosphoaluminate designated MCM-5 and having a particular crystal structure is provided. This crystalline material has ion-exchange properties and is readily convertible to catalytically active material.
摘要翻译： 提供了称为MCM-5并具有特定晶体结构的新的结晶硅磷硅铝酸盐。 该结晶材料具有离子交换性质并易于转化为催化活性材料。
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公开(公告)号：US5326464A
公开(公告)日：1994-07-05
申请号：US397076
申请日：1989-08-22
IPC分类号： B01J20/18 , B01J23/04 , B01J29/82 , B01J29/84 , B01J29/85 , B01J39/12 , C01B37/04 , C01B37/06 , C01B37/08 , C01B39/48 , C10G11/02 , C07C4/06 , C10G47/04
CPC分类号： C01B37/08 , B01J20/18 , B01J23/04 , B01J29/82 , B01J29/84 , B01J29/85 , B01J39/12 , C01B33/28 , C01B37/04 , C01B37/06
摘要： A process for converting feedstock comprising hydrocarbon compounds to product comprising hydrocarbon compounds of lower molecular weight than said feedstock hydrocarbon compounds which comprises contacting said feedstock at conditions for said conversion with catalyst comprising crystals having a framework topology after heating at 110.degree. C. or higher giving an X-ray diffraction pattern with interplanar d-spacings at 16.4.+-.0.2 Angstroms, 8.2.+-.0.1 Angstroms, 6.21.+-.0.05 Angstroms, 6.17.+-.0.05 Angstroms, 5.48.+-.0.05 Angstroms and 4.74.+-.0.05 Angstroms, and without a significant interplanar d-spacing at 13.6-13.3 Angstroms.
摘要翻译： 将包含烃化合物的原料转化成包含比所述原料烃化合物低分子量烃化合物的产物的方法，该方法包括在所述转化条件下将所述原料与包含在110℃或更高温度下加热后具有骨架拓扑结构的催化剂接触， 具有16.4 +/- 0.2埃，8.2 +/- 0.1埃，6.21 +/- 0.05埃，6.17 +/- 0.05埃，5.48 +/- 0.05埃和4.74克/升的平面d间距的X射线衍射图， -0.05埃，并且在13.6-13.3埃处没有显着的晶面d间距。
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公开(公告)号：US4673559A
公开(公告)日：1987-06-16
申请号：US685171
申请日：1984-12-21
摘要： Silicophosphoaluminates are crystallized from a two-phase reaction mixture comprising sources of silicon oxide, aluminum oxide and phosphorus oxide and a suitable directing agent. The silicophosphoaluminates produced have ion exchange properties and are readily convertible to catalytically active material.
摘要翻译： 硅磷光铝酸盐从包含氧化硅，氧化铝和氧化磷源以及合适的导向剂的两相反应混合物中结晶。 所生产的硅磷硅铝酸盐具有离子交换性能，并且易于转化为催化活性材料。
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公开(公告)号：US4639358A
公开(公告)日：1987-01-27
申请号：US685173
申请日：1984-12-21
摘要： A new crystalline silicophosphoaluminate designated MCM-1 and having a particular crystal structure is provided. This crystalline material has ion-exchange properties and is readily convertible to catalytically active material.
摘要翻译： 提供了称为MCM-1并具有特定晶体结构的新的结晶硅磷硅铝酸盐。 该结晶材料具有离子交换性质并易于转化为催化活性材料。
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公开(公告)号：US4632811A
公开(公告)日：1986-12-30
申请号：US685185
申请日：1984-12-21
摘要： A new crystalline silicophosphoaluminate designated MCM-3 and having a particular crystal structure is provided. This crystalline material has ion-exchange properties and is readily convertible to catalytically active material.
摘要翻译： 提供了称为MCM-3并具有特定晶体结构的新的结晶硅磷硅铝酸盐。 该结晶材料具有离子交换性质并易于转化为催化活性材料。
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公开(公告)号：US4313853A
公开(公告)日：1982-02-02
申请号：US215514
申请日：1980-12-11
CPC分类号： B01J21/18 , B01J23/755 , B01J35/002 , B01J35/0026 , B01J35/023
摘要： A process for forming a dispersion of metal selected from the group consisting essentially of Ni, Co, Mo and mixtures thereof on graphite comprising heating a composite of said metal on graphite at a temperature between about 800.degree.-975.degree. C. in an inert, hydrogen-containing atmosphere to form metal-containing channels in the graphite, raising the temperature to at least about 975.degree. C. so that the metal in the channels spreads out and chemically wets the surface of the channels as a film of metal phase, followed by contacting the so-formed metal-wetted, channeled composite with an oxidizing atmosphere to break up the film of metal phase into discrete metal particles. The average diameter of the particles is generally below about 25 A and the preferred metal is nickel.
摘要翻译： 一种在石墨上形成选自Ni，Co，Mo及其混合物的金属分散体的方法，包括在约800-975℃的温度下在惰性气氛中加热所述金属在石墨上的复合物， 含氢气氛，在石墨中形成含金属的通道，将温度升高至至少约975℃，使得通道中的金属扩散并化学润湿通道表面作为金属相膜，随后 通过使如此形成的金属湿润的沟道复合材料与氧化气氛接触，将金属相的膜分解成离散的金属颗粒。 颗粒的平均直径通常低于约25，优选的金属是镍。
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