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公开(公告)号：US5233095A
公开(公告)日：1993-08-03
申请号：US730230
申请日：1991-07-16
申请人： Jere D. Fellmann , Robert J. Saxton , Paul Tung
发明人： Jere D. Fellmann , Robert J. Saxton , Paul Tung
CPC分类号： C07C37/07 , C07C45/006 , C07C45/64 , C07C45/65 , C07C2101/14 , C07C2101/16
摘要： A process for the manufacture of resorcinol is described which relies upon the intermediacy of a .alpha.,.beta.-unsaturated ketone which can be reacted with a hydroxy moiety-containing compound to obtain a resorcinol precursor which is subsequently converted to resorcinol. In a specific embodiment, 2-cyclohexenone is reacted with water to obtain 3-hydroxycyclohexanone which is dehydrogenated to resorcinol. In another embodiment, 2-cyclohexenone is oxidized to cyclohexane-1,3-dione which is dehydragenated obtain resorcinol.
摘要翻译： 描述了制备间苯二酚的方法，其依赖于可与含羟基部分的化合物反应的α，β-不饱和酮的中间体，以获得随后转化为间苯二酚的间苯二酚前体。 在具体实施方案中，将2-环己烯酮与水反应，得到3-羟基环己酮，将其脱氢为间苯二酚。 在另一个实施方案中，将2-环己烯酮氧化成环己烷-1,3-二酮，将其脱水得到间苯二酚。
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公开(公告)号：US4861921A
公开(公告)日：1989-08-29
申请号：US21219
申请日：1987-03-03
申请人： Jere D. Fellmann , Robert J. Saxton , Paul Tung
发明人： Jere D. Fellmann , Robert J. Saxton , Paul Tung
CPC分类号： C07C37/07
摘要： A process for the manufacture of resorcinol is described which relies upon the intermediacy of a .alpha.,.beta.-unsaturated ketone which can be reacted with a hydroxy moiety-containing compound to obtain a resorcinol precursor which is subsequently converted to resorcinol. In a specific embodiment, 2-cyclohexenone is reacted dehydrogenated to resorcinol. In antoher embodiment, 2-cyclohexenone is oxidized to cyclohexane-1,3-dione which is dehydragenated obtain resorcinol.
摘要翻译： 描述了制备间苯二酚的方法，其依赖于可与含羟基部分的化合物反应的α，β-不饱和酮的中间体，以获得随后转化为间苯二酚的间苯二酚前体。 在一个具体实施方案中，将2-环己烯酮反应脱氢至间苯二酚。 在另外的实施方案中，将2-环己烯酮氧化成脱水的环己烷-1,3-二酮，得到间苯二酚。
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3.发明授权Process for selective diisopropylation of naphthyl compounds using shape selective acidic crystalline molecular sieve catalysts 失效使用形状选择性酸性结晶分子筛催化剂的萘基化合物的选择性二异丙基化方法
公开(公告)号：US5026942A
公开(公告)日：1991-06-25
申请号：US438496
申请日：1989-12-12
CPC分类号： C07C15/24 , C07C2/66 , C07C6/126 , B01J2229/12 , B01J2229/14 , B01J2229/32 , B01J2229/34 , B01J29/18 , C07C2521/12 , C07C2529/18 , C07C2529/70 , C07C2529/85
摘要： The selective isopropylation of a naphthyl compound to diisopropylnaphthalene enhanced in the 2,6-diisopropylnaphthalene isomer is obtained in the presence of an acidic crystalline molecular sieve catalyst having twelve membered oxygen rings. The catalyst pore aperture dimension range from 5.5 .ANG. to 7.0 .ANG.. The user of these shape selective catalysts results in a diisopropylnephthalene stream which is enhanced in .beta. isomers and enhanced in the desired 2,6-diisopropylnaphthalene isomer. A particularly preferred catalyst is synthetic Mordenite having a specific Si/Al ratio and NMR characteristics. Specific catalyst modifications are also described to improve selectivity to the desired 2,6-diisopropylnaphthalene isomer.
摘要翻译： PCT No.PCT / US89 / 04485第 371日期1989年12月12日 102（e）1989年12月12日PCT PCT日本1989年10月5日。在2,6-二异丙基萘异构体中增强的萘基化合物对二异丙基萘的选择性异丙基化是在具有十二烷酸的酸性结晶分子筛催化剂 元氧环。 催化剂孔径尺寸范围为5.5 ANGSTROM至7.0 ANGSTROM。 这些形状选择性催化剂的用户产生二异丙基萘流，其在β异构体中增强，并增加所需的2,6-二异丙基萘异构体。 特别优选的催化剂是具有特定Si / Al比和NMR特性的合成丝光沸石。 还描述了具体的催化剂修饰以提高对所需2,6-二异丙基萘异构体的选择性。
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公开(公告)号：US4853357A
公开(公告)日：1989-08-01
申请号：US103442
申请日：1987-09-30
申请人： Janis Vasilevskis , Jacques C. De Deken , Robert J. Saxton , Paul R. Wentrcek , Jere D. Fellmann , Lyubov S. Kipnis
发明人： Janis Vasilevskis , Jacques C. De Deken , Robert J. Saxton , Paul R. Wentrcek , Jere D. Fellmann , Lyubov S. Kipnis
CPC分类号： C07C45/35 , B01J31/1805 , B01J31/4038 , C07C45/34 , B01J2231/70 , B01J2531/824 , Y02P20/584
摘要： The additional of redox-active metal components and ligands, alternatively or simultaneously, results in increased conversion and selectivity in the palladium-catalyzed oxidation of olefins to carbonyl products in the presence of polyoxoanions. In preferred modes, heteropolyoxoanions and Isopolyoxoanions containing tungsten, molybdenum and vanadium, individually or in combination, are described. The use of copper as the redox-active metal component shows reduced allylic reactivity. The elimination of chloride from the catalyst system provides substantial engineering advantages over the prior art, particularly, the reduction of corrosion and chloro-organic by-product formation. The use of redox-active metal components and/or ligands makes the palladium-polyoxoanion catalyst system industrially practicable.
摘要翻译： 备选或同时添加氧化还原活性金属组分和配体导致在聚氧乙烯存在下，将钯催化的烯烃氧化成羰基产物的转化率和选择性提高。 在优选的模式中，描述了单独或组合地含有钨，钼和钒的杂多氧阴离子和异聚氧阴离子。 使用铜作为氧化还原活性金属组分显示出降低的烯丙基反应性。 与现有技术相比，从催化剂体系中除去氯化物提供了显着的工程优点，特别是减少腐蚀和氯 - 有机副产物形成。 使用氧化还原活性金属组分和/或配体使得钯 - 聚氧阴离子催化剂体系在工业上是可行的。
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公开(公告)号：US4723041A
公开(公告)日：1988-02-02
申请号：US846554
申请日：1986-03-31
申请人： Janis Vasilevskis , Jacques C. De Deken , Robert J. Saxton , Paul R. Wentrcek , Jere D. Fellmann , Lyubov S. Kipnis
发明人： Janis Vasilevskis , Jacques C. De Deken , Robert J. Saxton , Paul R. Wentrcek , Jere D. Fellmann , Lyubov S. Kipnis
CPC分类号： C07C45/35 , B01J31/1805 , B01J31/28 , C07C45/34 , B01J2531/824
摘要： The addition of redox-active metal components and ligands, alternatively or simultaneously, results in increased conversion and selectivity in the palladium-catalyzed oxidation of olefins to carbonyl products in the presence of polyoxoanions. In preferred modes, heteropolyoxoanions and isopolyoxoanions containing tungsten, molybdenum and vanadium, individually or in combination, are described. The use of copper as the redox-active metal component shows reduced allylic reactivity. The elimination of chloride from the catalyst system provides substantial engineering advantages over the prior art, particularly, the reduction of corrosion and chloro-organic by-product formation. The use of redox-active metal components and/or ligands makes the palladium-polyoxoanion catalyst system industrially practicable.
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公开(公告)号：US4720474A
公开(公告)日：1988-01-19
申请号：US779501
申请日：1985-09-24
申请人： Janis Vasilevskis , Jacques C. De Deken , Robert J. Saxton , Paul R. Wentrcek , Jere D. Fellmann , Lyubov S. Kipnis
发明人： Janis Vasilevskis , Jacques C. De Deken , Robert J. Saxton , Paul R. Wentrcek , Jere D. Fellmann , Lyubov S. Kipnis
IPC分类号： B01J31/04 , B01J27/02 , B01J27/055 , B01J27/06 , B01J27/188 , B01J27/195 , B01J31/16 , B01J31/18 , B01J31/28 , C07C45/34 , C07C45/35 , B01J31/02
CPC分类号： C07C45/35 , B01J31/1805 , B01J31/28 , C07C45/34 , B01J2531/824
摘要： The addition of redox-active metal components and ligands, alternatively or simultaneously, results in increased conversion and selectivity in the palladium-catalyzed oxidation of olefins to carbonyl products in the presence of polyoxoanions. In preferred modes, heteropolyoxoanions and isopolyoxoanions containing tungsten, molybdenum and vanadium, individually or in combination, are described. The use of copper as the redox-active metal component shows reduced allylic reactivity. The elimination of chloride from the catalyst system provides substantial engineering advantages over the prior art, particularly, the reduction of corrosion and chloro-organic by-product formation. The use of redox-active metal components and/or ligands makes the palladium-polyoxoanion catalyst system industrially practicable.
摘要翻译： 或者或同时加入氧化还原活性金属组分和配体导致在聚氧乙烯存在下，钯催化的烯烃氧化成羰基产物的转化率和选择性提高。 在优选的模式中，描述了单独或组合地含有钨，钼和钒的杂多氧阴离子和异聚氧阴离子。 使用铜作为氧化还原活性金属组分显示出降低的烯丙基反应性。 与现有技术相比，从催化剂体系中除去氯化物提供了显着的工程优点，特别是减少腐蚀和氯 - 有机副产物形成。 使用氧化还原活性金属组分和/或配体使得钯 - 聚氧阴离子催化剂体系在工业上是可行的。
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7.发明申请INTEGRAL SYNTHESIS GAS CONVERSION CATALYST EXTRUDATES AND METHODS FOR PREPARING AND USING SAME 审中-公开一体化合成气转化催化剂挤出物及其制备方法和使用方法公开(公告)号：US20130158138A1
公开(公告)日：2013-06-20
申请号：US13327184
申请日：2011-12-15
IPC分类号： C07C27/00 , B01J37/00 , B01J29/072 , B01J29/076 , B01J29/06 , B01J29/70
CPC分类号： B01J29/7669 , B01J23/8913 , B01J29/043 , B01J29/044 , B01J29/045 , B01J29/7469 , B01J35/0006 , B01J37/0009 , B01J37/035 , B01J2229/186 , B01J2229/42 , C10G2/334 , C10G2/341 , Y02E60/324
摘要： Methods for preparing integral synthesis gas conversion catalyst extrudates including an oxide of a Fischer-Tropsch (FT) metal component and a zeolite component are disclosed. The oxide of the FT metal component is precipitated from a solution into crystallites having a particle size between about 2 nm and about 30 nm. The oxide of the FT metal component is combined with a zeolite powder and a binder material, and the combination is extruded to form integral catalyst extrudates. The oxide of the FT metal component in the resulting catalyst is in the form of reduced crystallites located outside the zeolite channels. No appreciable ion exchange of FT metal occurs within the zeolite channels. The acid site density of the integral catalyst extrudate is at least about 80% of the zeolite acid site density.
摘要翻译： 公开了制备包含费 - 托（FT）金属组分和沸石组分的氧化物的整体合成气转化催化剂挤出物的方法。 FT金属成分的氧化物从溶液中沉淀成粒径在约2nm至约30nm之间的微晶。 将FT金属成分的氧化物与沸石粉末和粘合剂材料组合，将其组合挤出成一体的催化剂挤出物。 所得催化剂中FT金属组分的氧化物为位于沸石通道外部的微晶形式。 在沸石通道内不发生明显的FT金属离子交换。 整体催化剂挤出物的酸性位点密度为沸石酸性位点密度的至少约80％。
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公开(公告)号：US06884916B1
公开(公告)日：2005-04-26
申请号：US09429295
申请日：1999-10-28
摘要： An oligomerization process in which hydrocarbon feedstocks are contacted with a hydrotreating catalyst in the absence of hydrogen and in the liquid phase. The catalyst is a heterogeneous catalyst selected from supported reduced metals, metals oxides, metal sulfides and combinations thereof. Preferred catalysts include mixed nickel and molybdenum oxides or mixed cobalt and molybdenum oxides. The process also oligomerizes sulfur compounds so that sulfur containing feedstocks can be treated without deactivating the catalysts.
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9.发明授权
公开(公告)号：US5241118A
公开(公告)日：1993-08-31
申请号：US796499
申请日：1991-11-22
IPC分类号： B01J23/40 , B01J23/74 , B01J27/045 , B01J27/128 , C07B61/00 , C07C261/02 , C07C273/00 , C07C273/18 , C07C275/28 , C07D295/215
CPC分类号： C07D295/215 , C07C273/1809
摘要： A process for preparing trisubstituted ureas is disclosed. A nitroarene is reacted with carbon monoxide and a secondary amine in the presence of a Group VIII transition metal catalyst and optionally one or more promoters selected from primary amines, halide ion-containing compounds, and chelating phosphorus and nitrogen compounds.
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10.发明授权Process for selective diisopropylation of naphthyl compounds using shape selective acidic crystalline molecular sieve catalysts 失效使用形状选择性酸性结晶分子筛催化剂的萘基化合物的选择性二异丙基化方法
公开(公告)号：US5003122A
公开(公告)日：1991-03-26
申请号：US254284
申请日：1988-10-05
IPC分类号： B01J29/84 , B01J29/04 , B01J29/06 , B01J29/18 , B01J29/85 , C07B61/00 , C07C2/66 , C07C2/70 , C07C6/12 , C07C15/24
CPC分类号： C07C15/24 , C07C2/66 , C07C6/126 , B01J2229/12 , B01J2229/14 , B01J2229/32 , B01J2229/34 , B01J29/18 , C07C2521/12 , C07C2529/18 , C07C2529/70 , C07C2529/85
摘要： The selective isopropylation of a naphthyl compound to diisopropylnaphthalene enhanced in the 2,6-diisopropylnaphthalene isomer is obtained in the presence of an acidic crystalline molecular sieve catalyst having twelve membered oxygen rings. The catalyst pore aperture dimension ranges from 5.5 .ANG. to 7.0 .ANG.. The use of these shape selective catalysts results in a diisopropylnaphthalene stream which is enhanced in .beta. isomers and enhanced in the desired 2,6-diisopropylnaphthalene isomer. A particularly preferred catalyst is synthetic Mordenite. Specific catalyst modifications are also described to improve selectivity to the desired 2,6-diisopropylnaphthalene isomer.
摘要翻译： 在具有12元氧环的酸性结晶分子筛催化剂的存在下，获得了2,6-二异丙基萘异构体中萘基化合物对二异丙基萘的选择性异丙基化。 催化剂孔径尺寸范围为5.5 ANGSTROM至7.0 ANGSTROM。 使用这些形状选择性催化剂导致二异丙基萘流，其增加了β异构体并且增加了所需的2,6-二异丙基萘异构体。 特别优选的催化剂是合成丝光沸石。 还描述了具体的催化剂修饰以提高对所需2,6-二异丙基萘异构体的选择性。
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