摘要:
The following describes a novel and alternative mechanism in regards to releasing reactive chemicals. Namely, utilizing shells containing multiple emulsions that can be blended with the base fluids, and then react with said base fluid upon exposure to a trigger e.g. high shear and/or elongation flow, therefore plugging even large fractures. Such gelling lost circulation material allows to obtain a reliable carrier and fast reaction when triggered.
摘要:
The following describes a novel and alternative mechanism in regards to releasing reactive chemicals. Namely, utilizing shells containing multiple emulsions that can be blended with the base fluids, and then react with said base fluid upon exposure to a trigger e.g. high shear and/or elongation flow, therefore plugging even large fractures. Such gelling lost circulation material allows to obtain a reliable carrier and fast reaction when triggered.
摘要:
Method for controlling lost circulation in a subterranean well using oil-dispersible lost-circulation materials which comprise fibers that are coated (or sized) with a lipophilic coupling agent, a lipophilic film-forming polymer or both. The fibers are preferably between about 6 mm and about 25 mm long, and between about 10 μm and about 200 μm in diameter. The fibers may be added to carrier fluids comprising oil-base fluids, synthetic-base fluids, invert-emulsion-base fluids and combinations thereof. The preferred fiber concentration in the carrier fluid is between about 0.55 g/L and about 28.5 g/L. The carrier fluid may be a drilling fluid, a spacer fluid or a lost-circulation pill.
摘要:
Method for controlling lost circulation in a subterranean well using oil-dispersible lost-circulation materials which comprise fibers that are coated (or sized) with a lipophilic coupling agent, a lipophilic film-forming polymer or both. The fibers are preferably between about 6 mm and about 25 mm long, and between about 10 μm and about 200 μm in diameter. The fibers may be added to carrier fluids comprising oil-base fluids, synthetic-base fluids, invert-emulsion-base fluids and combinations thereof. The preferred fiber concentration in the carrier fluid is between about 0.55 g/L and about 28.5 g/L. The carrier fluid may be a drilling fluid, a spacer fluid or a lost-circulation pill.
摘要:
Lipophilic fibers are effective media for cleaning non-aqueous fluids out of a subterranean wellbore. The fibers are preferably added to a drilling fluid, a spacer fluid, a chemical wash, a cement slurry or combinations thereof. Non-aqueous fluids, such as an oil-base mud or a water-in-oil emulsion mud, are attracted to the fibers as they circulate in the wellbore.
摘要:
Lipophilic fibers are effective media for cleaning non-aqueous fluids out of a subterranean wellbore. The fibers are preferably added to a drilling fluid, a spacer fluid, a chemical wash, a cement slurry or combinations thereof. Non-aqueous fluids, such as an oil-base mud or a water-in-oil emulsion mud, are attracted to the fibers as they circulate in the wellbore.
摘要:
A method is given for treating a subterranean formation penetrated by a wellbore with a viscosified fluid. The fluid contains a solid hydrolysable polyacid that upon dissolution and hydrolysis releases an acid that is a breaker for the viscosifying system. Suitable solid hydrolysable polyacids include polylactic acid and polyglycolic acid. The fluid also contains a pH control agent, present in an amount sufficient to neutralize any acid present in the solid hydrolysable polyacid before the injection and to neutralize any acid generated by the solid hydrolysable polyacid during the injection, so that the acid breaker is not available to break the fluid during the injection. In one embodiment the viscosifier is a viscoelastic surfactant fluid system and the solid hydrolysable polyacid is of a size selected to be a fluid loss additive, for example in fracturing or gravel packing. In another embodiment, the solid hydrolysable polyacid is used in particles sufficiently small that they enter the pores of the formation. In either case, the viscosifier is broken after the solid releases more acid than can be neutralized by the pH control agent.
摘要:
Methods of improving shear recovery time of viscoelastic surfactant fluid systems are described, one method involving providing a viscoelastic surfactant fluid system comprising a major portion of a surfactant and a rheology enhancer in a concentration sufficient to shorten shear recovery time of the fluid system compared to shear recovery time of the fluid system absent the rheology enhancer, the rheology enhancer selected from aromatic sulfonates having a molecular weight of at least 500; and injecting the fluid system down a well. The rheology enhancer may be a lignosulfonate derived from wood pulping. Viscoelastic surfactant systems including the rheology enhancer are also described.
摘要:
A method for shortening the shear recovery time of cationic, zwitterionic, and amphoteric viscoelastic surfactant fluid systems by adding an effective amount of a rheology enhancer selected from partially hydrolyzed polyvinyl ester and partially hydrolyzed polyacrylates. The rheology enhancer also increases fluid viscosity and very low rheology enhancer concentration is needed. Preferred surfactants are betaines and quaternary amines. The fluids are useful in oilfield treatments, for example fracturing and gravel packing.
摘要:
Compositions and methods are given for delayed breaking of viscoelastic surfactant gels inside formation pores, particularly for use in hydraulic fracturing. Breaking inside formation pores is accomplished without mechanical intervention or use of a second fluid. Oxidizing agents such as air, oxygen, persulfates, bromates, peroxides, and others are used. The break may be accelerated, for example with a free radical propagating species, or retarded, for example with an oxygen scavenger. In certain brines, for example bromide brines, certain zwitterionic viscoelastic fluid systems that can decarboxylate and that require an anion-containing co-surfactant undergo delayed degradation if oxygen is present, for example from fluid preparation or in a foam.