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    Carbon nanotube stripping solutions and methods
    1.
    发明申请
    Carbon nanotube stripping solutions and methods 审中-公开
    碳纳米管剥离溶液及方法

    公开(公告)号：US20050266162A1

    公开(公告)日：2005-12-01

    申请号：US11079012

    申请日：2005-03-14

    申请人： Jiazhong Luo ,  Philip Wallis ,  David Arthur ,  Paul Glatkowski

    发明人： Jiazhong Luo ,  Philip Wallis ,  David Arthur ,  Paul Glatkowski

    IPC分类号： B05D1/12 ,  C01B31/02 ,  C09D9/00 ,  H01B1/24

    CPC分类号： B82Y30/00 ,  B82Y40/00 ,  C01B32/174 ,  C09D9/005 ,  H01B1/24

    摘要： The invention is directed to compositions and methods for forming conductive patterned coatings of carbon nanotubes. Patterns are electrically conductive coatings/films made by exploiting self patterning nanostructures composed of electrically conductive materials. The resulting layer is suitable for conducting electricity in applications where a transparent electrode is required. Typical applications include, but are not limited to; LC displays, touch screens, EMI shielding windows, and architectural windows. Films may be highly transparent. In one embodiment, carbon nanotubes are applied to an insulating substrate to form an electrically conductive network of nanotubes with controlled porosity in the network. The open area between the networks of nanotubes, increases the optical transparency in the visible spectrum while the continuous nanotube phase provides electrical conductivity across the entire surface or patterned area. Through the controlled application of this self assembled network of nanotubes by means of printing or spraying, patterned areas can be formed to function as electrodes in devices. The use of printing technology to form these electrodes obviates the need for more expensive process such as vacuum deposition and photolithography typically employed today during the formation of ITO coatings.

    摘要翻译： 本发明涉及用于形成碳纳米管的导电图案化涂层的组合物和方法。 图案是通过利用由导电材料构成的自组装纳米结构制成的导电涂层/薄膜。 所得的层适用于在需要透明电极的应用中导电。 典型应用包括但不限于： LC显示屏，触摸屏，EMI屏蔽窗和建筑窗口。 电影可能非常透明。 在一个实施例中，将碳纳米管施加到绝缘基板上以形成网络中具有受控多孔性的纳米管的导电网络。 纳米管网络之间的开放区域增加了可见光谱中的光学透明度，而连续的纳米管相位提供整个表面或图案区域的导电性。 通过这种通过印刷或喷涂的纳米管自组装网络的受控应用，可以形成图案化的区域以用作器件中的电极。 使用印刷技术形成这些电极消除了在ITO涂层形成期间通常使用的更昂贵的工艺，例如真空沉积和光刻的需要。

    Polymer binders for flexible and transparent conductive coatings containing carbon nanotubes
    2.
    发明申请
    Polymer binders for flexible and transparent conductive coatings containing carbon nanotubes 审中-公开
    用于含有碳纳米管的柔性和透明导电涂层的聚合物粘合剂

    公开(公告)号：US20050209392A1

    公开(公告)日：2005-09-22

    申请号：US11014233

    申请日：2004-12-17

    申请人： Jiazhong Luo ,  Paul Glatkowski ,  Philip Wallis

    发明人： Jiazhong Luo ,  Paul Glatkowski ,  Philip Wallis

    IPC分类号： C08K3/04 ,  C08K7/24

    CPC分类号： B82Y30/00 ,  C08J7/047 ,  C08J2367/02 ,  C08K3/041 ,  C08K2201/011 ,  C09D5/24 ,  C09D7/67 ,  C09D7/70 ,  C09D127/16 ,  C09D127/18

    摘要： This invention relates to flexible, transparent and conductive coatings and films formed using single wall carbon nanotubes and polymer binders. Preferably, coatings and films are formed from carbon nanotubes (CNT) applied to transparent substrates forming one or multiple conductive layers at nanometer level of thickness. Polymer binders are applied to the CNT network coating having an open structure to provide protection through infiltration. This provides for the enhancement of properties such as moisture resistance, thermal resistance, abrasion resistance and interfacial adhesion. Polymers may be thermoplastics or thermosets, or any combination of both. Polymers may also be insulative or inherently electrical conductive, or any combination of both. Polymers may comprise single or multiple layers as a basecoat underneath a CNT coating, or a topcoat above a CNT coating, or combination of the basecoat and the topcoat forming a sandwich structure. Binder coating thickness can be adjusted by changing binder concentration, coating speed and/or other process conditions. Resulting films and articles can be used as transparent conductors for flat panel display, touch screen and other electronic devices.

    摘要翻译： 本发明涉及使用单壁碳纳米管和聚合物粘合剂形成的柔性，透明和导电涂层和膜。 优选地，涂层和膜由应用于形成纳米级厚度的一个或多个导电层的透明衬底的碳纳米管（CNT）形成。 将聚合物粘合剂施加到具有开放结构的CNT网络涂层，以通过渗透提供保护。 这提供了诸如耐湿性，耐热性，耐磨性和界面粘合性等的增强。 聚合物可以是热塑性塑料或热固性材料，或两者的任何组合。 聚合物也可以是绝缘的或固有的导电的，或两者的任何组合。 聚合物可以包含单层或多层作为CNT涂层下的底涂层，或CNT涂层上面的顶涂层，或者底涂层和顶涂层的组合形成夹层结构。 粘合剂涂层厚度可以通过改变粘合剂浓度，涂布速度和/或其他工艺条件来调节。 所得薄膜和制品可用作平板显示器，触摸屏和其他电子设备的透明导体。

    Fluoropolymer binders for carbon nanotube-based transparent conductive coatings
    3.
    发明申请
    Fluoropolymer binders for carbon nanotube-based transparent conductive coatings 失效
    用于碳纳米管基透明导电涂料的含氟聚合物粘合剂

    公开(公告)号：US20060113510A1

    公开(公告)日：2006-06-01

    申请号：US11201275

    申请日：2005-08-11

    申请人： Jiazhong Luo ,  David Arthur ,  Paul Glatkowski

    发明人： Jiazhong Luo ,  David Arthur ,  Paul Glatkowski

    IPC分类号： H01B1/12

    CPC分类号： H01B1/24 ,  B82Y10/00 ,  C08J7/045 ,  C08J2367/02 ,  C08J2427/12 ,  Y10T156/10

    摘要： This invention relates to flexible, transparent and conductive coatings and films formed using carbon nanotubes (CNT) and, in particular, single wall carbon nanotubes, with polymer binders. Preferably, coatings and films are formed from carbon nanotubes applied to transparent substrates forming one or multiple conductive layers at nanometer level of thickness. Polymer binders are applied to the CNT network coating having an open structure to provide protection through infiltration. This provides for enhancement of properties such as moisture resistance, thermal resistance, abrasion resistance and interfacial adhesion. Polymers may be thermoplastics or thermosets, or a combination thereof. Polymers may also be insulative or inherently electrical conductive, or any combination of both. Polymers may comprise single or multiple layers as a basecoat underneath a CNT coating, or a topcoat above a CNT coating, or combination of the basecoat and the topcoat forming a sandwich structure. A fluoropolymer containing binder, which is a solution of one fluoropolymer or a blend of fluoropolymers, which may be formulated with additives, is applied onto a carbon nanotube-based transparent conductive coating at nanometer level of thickness on a clear substrate such as PET and glass. The fluoropolymers or blend can be either semi-crystalline (with low level of crystallinity) or amorphous, preferably to be amorphous with low refraction index. Binder coating thickness can be adjusted by changing binder concentration, coating speed and/or other process conditions. This binder coating significantly improves optical transparency, and also maintain or increases conductivity of the CNT-based coating. With other benefits such as abrasion, thermal and moisture resistance, this binder coating and the resulting products is used for display and electronic applications.

    摘要翻译： 本发明涉及柔性，透明和导电的涂层和使用碳纳米管（CNT），特别是单壁碳纳米管与聚合物粘合剂形成的膜。 优选地，涂层和膜由应用于形成纳米级厚度的一个或多个导电层的透明基板上的碳纳米管形成。 将聚合物粘合剂施加到具有开放结构的CNT网络涂层，以通过渗透提供保护。 这提供了诸如耐湿性，耐热性，耐磨性和界面粘附性的增强。 聚合物可以是热塑性塑料或热固性材料，或其组合。 聚合物也可以是绝缘的或固有的导电的，或两者的任何组合。 聚合物可以包含单层或多层作为CNT涂层下的底涂层，或CNT涂层上面的顶涂层，或者底涂层和顶涂层的组合形成夹层结构。 将含氟聚合物的含氟聚合物或可与添加剂一起配制的含氟聚合物的混合物的溶液施加到碳纳米管基透明导电涂层上，该透明导电涂层在透明基材如PET和玻璃上以纳米级 。 含氟聚合物或共混物可以是半结晶（具有低结晶度）或无定形，优选为具有低折射率的无定形。 粘合剂涂层厚度可以通过改变粘合剂浓度，涂布速度和/或其他工艺条件来调节。 该粘合剂涂层显着地改善了光学透明性，并且还维持或增加了基于CNT的涂层的导电性。 具有耐磨，耐热和防潮等其他优点，该粘合剂涂层和所得产品用于显示和电子应用。

    Electromagnetic shielding composite comprising nanotubes
    5.
    发明授权
    Electromagnetic shielding composite comprising nanotubes 失效
    包含纳米管的电磁屏蔽复合材料

    公开(公告)号：US06265466B1

    公开(公告)日：2001-07-24

    申请号：US09250047

    申请日：1999-02-12

    申请人： Paul Glatkowski ,  Patrick Mack ,  Jeffrey L. Conroy ,  Joseph W. Piche ,  Paul Winsor

    发明人： Paul Glatkowski ,  Patrick Mack ,  Jeffrey L. Conroy ,  Joseph W. Piche ,  Paul Winsor

    IPC分类号： G21F110

    CPC分类号： G21F1/10 ,  Y10S977/734 ,  Y10S977/742 ,  Y10S977/753 ,  Y10S977/788 ,  Y10S977/847 ,  Y10S977/902

    摘要： An electromagnetic shielding composite having nanotubes and a method of making the same are disclosed. According to one embodiment of the present invention, the composite for providing electromagnetic shielding includes a polymeric material and an effective amount of oriented nanotubes for EM shielding, the nanotubes being oriented when a shearing force is applied to the composite. According to another embodiment of the present invention, the method for making an electromagnetic shielding includes the steps of (1) providing a polymer with an amount of nanotubes, and (2) imparting a shearing force to the polymer and nanotubes to orient the nanotubes.

    摘要翻译： 公开了一种具有纳米管的电磁屏蔽复合体及其制造方法。 根据本发明的一个实施方案，用于提供电磁屏蔽的复合材料包括聚合材料和有效量的用于EM屏蔽的定向纳米管，当剪切力施加到复合材料时，纳米管是取向的。 根据本发明的另一个实施例，制造电磁屏蔽的方法包括以下步骤：（1）提供具有一定量纳米管的聚合物，和（2）向聚合物和纳米管施加剪切力以取向纳米管。

    Articles with dispersed conductive coatings
    7.
    发明申请
    Articles with dispersed conductive coatings 审中-公开
    具有分散导电涂层的物品

    公开(公告)号：US20060257638A1

    公开(公告)日：2006-11-16

    申请号：US10542785

    申请日：2004-01-29

    申请人： Paul Glatkowski ,  Joseph Piche ,  Masato Sakai ,  Hidemi Ito

    发明人： Paul Glatkowski ,  Joseph Piche ,  Masato Sakai ,  Hidemi Ito

    IPC分类号： D04H1/00

    CPC分类号： C09D5/24 ,  H01B1/24 ,  Y10T428/249924

    摘要： A conductive article includes a substrate made of a thermoplastic resin, and a transparent and conductive layer comprising carbon nanotubes and formed on at least one face of the substrate. The carbon nanotubes are electrical in contact with each other and dispersed so that each of the carbon nanotubes is separated form other carbon nanotubes, or that each of bundles of the carbon nanotubes is separated from other bundles.

    摘要翻译： 导电制品包括由热塑性树脂制成的基底，以及包含碳纳米管并形成在基底的至少一个面上的透明导电层。 碳纳米管彼此电接触并分散，使得每个碳纳米管与其他碳纳米管分离，或者碳纳米管的束与其他束分离。

    Electrically conductive coatings with high thermal oxidative stability and low thermal conduction
    8.
    发明申请
    Electrically conductive coatings with high thermal oxidative stability and low thermal conduction 审中-公开
    具有高热氧化稳定性和低热传导性的导电涂层

    公开(公告)号：US20050191493A1

    公开(公告)日：2005-09-01

    申请号：US10978212

    申请日：2004-11-01

    申请人： Paul Glatkowski

    发明人： Paul Glatkowski

    IPC分类号： B05D1/36 ,  B32B9/00 ,  H01L51/00

    CPC分类号： H01B1/18 ,  B82Y10/00 ,  B82Y30/00 ,  C08K3/04 ,  C08K3/041 ,  C08K3/046 ,  C09D5/24 ,  C09D7/70 ,  C09D163/00 ,  C09D175/04 ,  C09D179/08 ,  H01B1/24 ,  H01L51/0048 ,  Y10T428/30

    摘要： The present invention is directed to electrically conductive coatings of carbon that have high thermal oxidative stability and low thermal conduction. Coatings of the invention provide a surface resistivity to the coated substrate of 102 ohms/square, and preferably 10−2 ohms/square. Coatings also provide the coated article increased thermal oxidative stability as compared to the uncoated article and articles coated with convention materials like carbon black and metals, as well as low thermal conduction. The invention is also directed to substrates possessing conductive coatings, methods of utilizing the coated substrates, and to methods of forming the coatings of the invention.

    摘要翻译： 本发明涉及具有高热氧化稳定性和低热传导性的碳的导电涂层。 本发明的涂层提供涂覆的基材的表面电阻率为10欧姆/平方，优选为10 -2欧姆/平方。 与未涂覆的制品和涂覆有常规材料如炭黑和金属的制品以及低热传导相比，涂层还提供涂层制品增加的热氧化稳定性。 本发明还涉及具有导电涂层的基底，利用涂覆的基底的方法以及形成本发明的涂层的方法。

    Articles with protruding conductive coatings
    10.
    发明申请
    Articles with protruding conductive coatings 审中-公开
    具有突出导电涂层的物品

    公开(公告)号：US20070065651A1

    公开(公告)日：2007-03-22

    申请号：US10542786

    申请日：2004-01-29

    申请人： Paul Glatkowski ,  Joseph Piche ,  Masato Sakai ,  Hidemi Ito

    发明人： Paul Glatkowski ,  Joseph Piche ,  Masato Sakai ,  Hidemi Ito

    IPC分类号： B32B27/04 ,  B32B18/00 ,  B05D1/12

    CPC分类号： H01B1/24 ,  B82Y30/00 ,  C09D5/24 ,  Y10T428/24994 ,  Y10T428/249945

    摘要： A conductive article includes a substrate and a conductive layer that is formed on the surface of the substrate and contains fine conductive fibers that are dispersed in the conductive layer. One end of the fibers is fixed to the substrate and other end of the fibers protrude from the top surface of the conductive layer. Alternatively, a middle portion of the fibers may protrude from the top surface or fixed to the substrate. Even though the fibers are dispersed well enough to avoid the aggregation of the fibers, portions of the fibers are located close to each other enough to provide electrical contact.

    摘要翻译： 导电性物品包括基板和导电层，该导电层形成在基板的表面上并且包含分散在导电层中的细导电纤维。 纤维的一端固定在基材上，纤维的另一端从导电层的上表面突出。 或者，纤维的中间部分可以从顶表面突出或固定到基底。 即使纤维分散得足够好以避免纤维聚集，纤维的一部分彼此靠近以提供电接触。