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公开(公告)号：US20100047356A1
公开(公告)日：2010-02-25
申请号：US12440715
申请日：2007-09-11
IPC分类号： A61K9/50 , A61K31/403 , A61K31/404 , A61K31/655 , A61K31/473 , A61K31/122 , A61K31/4184 , A61K31/535 , A61P35/00 , A61P17/00
CPC分类号： A61K9/5089
摘要： Novel phototherapeutic methods and compositions are described herein. Nanoparticle-assembled microcapsules as a new type of delivery vehicle for photosensitive compounds may be synthesized through a two-step assembly process. Charged polymer chains and counterions may be combined with a photosensitive compound to form photosensitive aggregates, and then nanoparticles may be combined with the aggregates to form the microcapsules. The shell may be composed of nanoparticles and/or polymer, and the core interior may contain the photosensitive compound. Formation occurs rapidly (on the order of seconds) and the conditions are very mild (at room temperature, in aqueous solution, and at neutral pH). The microcapsule synthesis is highly suitable as an encapsulation method, particularly for a charged photosensitive molecule like ICG.
摘要翻译： 本文描述了新的光疗法和组合物。 作为光敏化合物的新型载体的纳米颗粒组装微胶囊可以通过两步组装方法合成。 带电的聚合物链和抗衡离子可以与光敏化合物组合以形成光敏聚集体，然后将纳米颗粒与聚集体组合以形成微胶囊。 壳可以由纳米颗粒和/或聚合物组成，并且核心内部可以含有光敏化合物。 形成迅速（秒数），条件非常温和（室温下，水溶液中，中性pH值）。 微胶囊合成作为包封方法是非常适合的，特别是对于带电感光分子如ICG。
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公开(公告)号：US08337809B2
公开(公告)日：2012-12-25
申请号：US12440715
申请日：2007-09-11
CPC分类号： A61K9/5089
摘要： Novel phototherapeutic methods and compositions are described herein. Nanoparticle-assembled microcapsules as a new type of delivery vehicle for photosensitive compounds may be synthesized through a two-step assembly process. Charged polymer chains and counterions may be combined with a photosensitive compound to form photosensitive aggregates, and then nanoparticles may be combined with the aggregates to form the microcapsules. The shell may be composed of nanoparticles and/or polymer, and the core interior may contain the photosensitive compound. Formation occurs rapidly (on the order of seconds) and the conditions are very mild (at room temperature, in aqueous solution, and at neutral pH). The microcapsule synthesis is highly suitable as an encapsulation method, particularly for a charged photosensitive molecule like ICG.
摘要翻译： 本文描述了新的光疗法和组合物。 作为光敏化合物的新型载体的纳米颗粒组装微胶囊可以通过两步组装方法合成。 带电的聚合物链和抗衡离子可以与光敏化合物组合以形成光敏聚集体，然后将纳米颗粒与聚集体组合以形成微胶囊。 壳可以由纳米颗粒和/或聚合物组成，并且核心内部可以含有光敏化合物。 形成迅速（秒数），条件非常温和（室温下，水溶液中，中性pH值）。 微胶囊合成作为包封方法是非常适合的，特别是对于带电感光分子如ICG。
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公开(公告)号：US20110059842A1
公开(公告)日：2011-03-10
申请号：US12665692
申请日：2008-06-20
CPC分类号： C01G41/00 , B01J23/30 , B01J35/002 , B01J35/10 , B01J37/0203 , B01J37/0205 , B82Y30/00 , C01G25/02 , C01G41/02 , C01P2002/82 , C01P2002/84 , C01P2004/04 , C01P2004/64 , C01P2004/84 , C01P2006/12
摘要： A new type of solid acid catalyst, which promises better catalytic performance than conventionally prepared supported metal oxides due to its precisely synthesized nanostructure has been described. The catalyst is nanoparticulate in form and is comprised of monolayers of tungstated zirconia of the formula, WOxZryO4-2y made by impregnating a support with zirconium and tungsten. The support catalyst is further characterized in having a tugsten monolayer between greater than 0001 W/nm2 to about 30 W/nm2.
摘要翻译： 已经描述了一种新型的固体酸催化剂，其由于其精确合成的纳米结构而具有比常规制备的负载型金属氧化物更好的催化性能。 该催化剂是纳米颗粒形式，并且由下式的钨酸氧化锆单层组成：WOxZryO4-2y，其通过用锆和钨浸渍载体而制得。 载体催化剂的特征还在于具有大于0001W / nm 2至约30W / nm 2之间的钨单层。
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公开(公告)号：US20100025637A1
公开(公告)日：2010-02-04
申请号：US12442382
申请日：2008-04-11
CPC分类号： H01B1/02 , B82Y30/00 , C01B17/20 , C01B19/007 , C01P2002/72 , C01P2002/84 , C01P2004/04 , C01P2004/30 , C01P2004/64 , C09K11/565 , C09K11/883 , H01B1/16 , Y10T428/2982
摘要： Embodiments of the invention provide a method of making non-spherical nanoparticles that includes (a) combining a source of a Group 12, 13, 14, or 15 metal or metalloid; a source of a Group 15 or 16 element; and a source of a quaternary ammonium compound or phosphonium compound; and (b) isolating non-spherical nanoparticles from the resulting reaction mixture. Other embodiments of the invention provide non-spherical nanoparticle compositions, that are the reaction product of a source of a Group 12, 13, 14, or 15 metal or metalloid; a source of a Group 15 or 16 element; and a source of a quaternary ammonium compound or phosphonium compound; wherein nanoparticle tetrapods comprise 75-100 number percent of the nanoparticle products.
摘要翻译： 本发明的实施方案提供了制备非球形纳米颗粒的方法，其包括（a）组合第12,13,14或15族金属或准金属的源; 15或16组元素的来源; 和季铵化合物或鏻化合物的来源; 和（b）从所得反应混合物中分离非球形纳米颗粒。 本发明的其它实施方案提供非球形纳米颗粒组合物，即第12,13,14或15族金属或准金属的源的反应产物; 15或16组元素的来源; 和季铵化合物或鏻化合物的来源; 其中纳米颗粒四足体包含75-100％的纳米颗粒产物。
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公开(公告)号：US08455392B2
公开(公告)日：2013-06-04
申请号：US12665692
申请日：2008-06-20
CPC分类号： C01G41/00 , B01J23/30 , B01J35/002 , B01J35/10 , B01J37/0203 , B01J37/0205 , B82Y30/00 , C01G25/02 , C01G41/02 , C01P2002/82 , C01P2002/84 , C01P2004/04 , C01P2004/64 , C01P2004/84 , C01P2006/12
摘要： A new type of solid acid catalyst, which promises better catalytic performance than conventionally prepared supported metal oxides due to its precisely synthesized nanostructure has been described. The catalyst is nanoparticulate in form and is comprised of monolayers of tungstated zirconia of the formula, WOxZryO4-2y made by impregnating a support with zirconium and tungsten. The support catalyst is further characterized in having a tugsten monolayer between greater than 0001 W/nm2 to about 30 W/nm2.
摘要翻译： 已经描述了一种新型的固体酸催化剂，其由于其精确合成的纳米结构而具有比常规制备的负载型金属氧化物更好的催化性能。 该催化剂是纳米颗粒形式，并且由下式的钨酸氧化锆单层组成：WOxZryO4-2y，其通过用锆和钨浸渍载体而制得。 载体催化剂的特征还在于具有大于0001W / nm 2至约30W / nm 2之间的钨单层。
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公开(公告)号：US08313714B2
公开(公告)日：2012-11-20
申请号：US12442382
申请日：2008-04-11
CPC分类号： H01B1/02 , B82Y30/00 , C01B17/20 , C01B19/007 , C01P2002/72 , C01P2002/84 , C01P2004/04 , C01P2004/30 , C01P2004/64 , C09K11/565 , C09K11/883 , H01B1/16 , Y10T428/2982
摘要： Embodiments of the invention provide a method of making non-spherical nanoparticles that includes (a) combining a source of a Group 12, 13, 14, or 15 metal or metalloid; a source of a Group 15 or 16 element; and a source of a quaternary ammonium compound or phosphonium compound; and (b) isolating non-spherical nanoparticles from the resulting reaction mixture. Other embodiments of the invention provide non-spherical nanoparticle compositions, that are the reaction product of a source of a Group 12, 13, 14, or 15 metal or metalloid; a source of a Group 15 or 16 element; and a source of a quaternary ammonium compound or phosphonium compound; wherein nanoparticle tetrapods comprise 75-100 number percent of the nanoparticle products.
摘要翻译： 本发明的实施方案提供了制备非球形纳米颗粒的方法，其包括（a）组合第12,13,14或15族金属或准金属的源; 15或16组元素的来源; 和季铵化合物或鏻化合物的来源; 和（b）从所得反应混合物中分离非球形纳米颗粒。 本发明的其它实施方案提供非球形纳米颗粒组合物，即第12,13,14或15族金属或准金属的源的反应产物; 15或16组元素的来源; 和季铵化合物或鏻化合物的来源; 其中纳米颗粒四足体包含75-100％的纳米颗粒产物。
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