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公开(公告)号：US08771815B2
公开(公告)日：2014-07-08
申请号：US12971629
申请日：2010-12-17
CPC分类号： C07C67/08 , C08K5/0016 , C08K5/103 , C08L23/0853 , C08L91/00 , Y02P20/582 , Y10T428/1352 , Y10T428/139 , C07C69/30 , C08L27/06
摘要： Provided are processes for making, and processes for using triglycerides as plasticizers. The process for making the triglyceride plasticizer includes: (i) recovering at least one linear C4 to C10 aldehyde, one branched C4 to C10 aldehyde, or a combination thereof from a hydroformylation product; (ii) oxidizing the linear, branched or combination thereof C4 to C10 aldehyde to form a linear, branched or combination thereof C4 to C10 acid; (iii) esterifying the linear, branched or combination thereof C4 to C10 acid with a polyol to yield a linear alkyl triglyceride, a branched alkyl triglyceride, or a combination thereof, and reaction byproducts; (iv) purifying the linear, branched or combination thereof alkyl triglyceride to form a plasticizer stream, a reaction byproduct stream, and an unreacted input stream, wherein the total carbon number of the triester groups ranges from 20 to 25 for greater than or equal to 45 wt % of the plasticizer; and (v) recycling from the purifying step back to the esterifying step the unreacted input stream and the reaction byproduct stream.
摘要翻译： 提供了制备方法和使用甘油三酯作为增塑剂的方法。 制备甘油三酯增塑剂的方法包括：（i）从加氢甲酰化产物中回收至少一种线性C 4至C 10醛，一个支链C 4至C 10醛或其组合; （ii）将其直链，支链或其组合C4至C10醛氧化以形成其直链，支链或其组合C4至C10的酸; （iii）用多元醇酯化其直链，支链或其组合C4至C10酸，得到直链烷基甘油三酯，支链烷基甘油三酸酯或其组合，以及反应副产物; （iv）纯化其直链，支链或其组合的烷基甘油三酸酯以形成增塑剂流，反应副产物流和未反应的输入流，其中三酯基团的总碳数在20至25之间，大于或等于 45重量％的增塑剂; 和（v）从净化步骤回收到酯化步骤未反应的输入流和反应副产物流。
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公开(公告)号：US20140148569A1
公开(公告)日：2014-05-29
申请号：US13819951
申请日：2011-08-16
IPC分类号： C07C409/14 , C07C37/08 , C08G69/00 , C07D201/02 , C07C51/00 , C07C249/04 , C07C407/00 , C07C45/32
CPC分类号： C07C409/14 , C07C2/74 , C07C37/08 , C07C45/32 , C07C45/53 , C07C51/00 , C07C249/04 , C07C407/00 , C07C2601/14 , C07D201/02 , C08G69/00 , Y02P20/52 , C07C13/28 , C07C49/403 , C07C39/04
摘要： In a process for oxidizing a feed comprising cyclohexylbenzene, the feed is contacted with oxygen and an oxidation catalyst in a plurality of reaction zones connected in series, the contacting being conducted under conditions being effective to oxidize part of the cyclohexylbenzene in the feed to cyclohexylbenzene hydroperoxide in each reaction zone. At least one of the plurality of reaction zones has a reaction condition that is different from another of the plurality of reaction zones. The different reaction conditions may include one or more of (a) a progressively decreasing temperature and (b) a progressively increasing oxidation catalyst concentration as the feed flows from one reaction zone to subsequent reaction zones in the series.
摘要翻译： 在用于氧化包含环己基苯的进料的方法中，将进料与串联连接的多个反应区中的氧和氧化催化剂接触，在有效地将进料中的环己基苯的一部分氧化成环己基苯氢过氧化物的条件下进行 在每个反应区。 多个反应区中的至少一个具有与多个反应区中的另一个不同的反应条件。 不同的反应条件可以包括（a）逐渐降低的温度和（b）随着进料从一个反应区流向该系列中的后续反应区的逐渐增加的氧化催化剂浓度中的一个或多个。
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公开(公告)号：US08604110B2
公开(公告)日：2013-12-10
申请号：US13198851
申请日：2011-08-05
申请人： Jihad Mohammed Dakka , Stephen Zushma , Christine A. Costello , Edmund John Mozeleski , Diana S. Smirnova , Allen David Godwin , Pierre J. Osterrieth , Jörg Friedrich Wilhelm Weber , Paul Hamden Daniels , Thomas M. Larson , Catherine A. Faler
发明人： Jihad Mohammed Dakka , Stephen Zushma , Christine A. Costello , Edmund John Mozeleski , Diana S. Smirnova , Allen David Godwin , Pierre J. Osterrieth , Jörg Friedrich Wilhelm Weber , Paul Hamden Daniels , Thomas M. Larson , Catherine A. Faler
CPC分类号： C07C67/08 , C07C67/343 , C07C69/612 , C07C69/734 , C08K5/0016 , C08K5/11
摘要： Provided are compounds of the formula: wherein m=0-3 and n=0-3, and R1 represents CxH2x wherein x=0 to 4 or cyclohexane; R2 represents H, a C1-C6 alkyl group at any of the ortho-, meta- or para-positions, a residue including heteroatoms chosen from O, N, and S, or mixtures thereof; and R3 and R4 represent hydrocarbon residues of OXO-C5-C9 alcohols which are different isomers of equal carbon number or different in carbon number. Also provided are processes for making the compounds and plasticized polymer compositions containing said compounds.
摘要翻译： 提供下式的化合物：其中m = 0-3且n = 0-3，并且R1表示CxH2x，其中x = 0至4或环己烷; R 2表示H，任何邻位，间位或对位的C 1 -C 6烷基，包括选自O，N和S的杂原子的残基或其混合物; 并且R 3和R 4代表相同碳数或碳数不同的不同异构体的OXO-C5-C9醇的烃残基。 还提供了制备含有所述化合物的化合物和增塑聚合物组合物的方法。
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公开(公告)号：US20110184105A1
公开(公告)日：2011-07-28
申请号：US12892680
申请日：2010-09-28
申请人： Jihad Mohammed Dakka , Edmund John Mozeleski , Lisa Saunders Baugh , Francisco Manuel Benitez , Catherine Anne Faler , Allen David Godwin , Jörg Friedrich Wilhelm Weber , Diana S. Smirnova
发明人： Jihad Mohammed Dakka , Edmund John Mozeleski , Lisa Saunders Baugh , Francisco Manuel Benitez , Catherine Anne Faler , Allen David Godwin , Jörg Friedrich Wilhelm Weber , Diana S. Smirnova
CPC分类号： C07C69/612 , C07C69/76
摘要： A process for making non-phthalate, 1,2-phenylene oxo-diester plasticizers for polymer compositions, by selectively hydrogenating naphthalene to form a partially hydrogenated naphthalene, oxygenating said partially hydrogenated naphthalene to form phenylene diacids, and esterifying said phenylene diacids with oxo-alcohols to form 1,2-phenylene oxo-diesters. Also a process for making phenylene oxo-diester plasticizers by selectively brominating xylenes to form bisbromomethylbenzene, catalytic carboalkoxylation of the bromo-compound to form phenylene diacetate, followed by transesterification to form the phenylene oxo-diester.
摘要翻译： 通过选择性氢化萘以形成部分氢化的萘来制备用于聚合物组合物的非邻苯二甲酸酯，1,2-亚苯基氧代二酯增塑剂的方法，将所述部分氢化的萘氧化以形成亚苯基二酸，并用所述亚苯基二酸酯化所述亚苯基二酸， 醇形成1,2-亚苯基氧代二酯。 也是通过选择性溴化二甲苯以形成双溴甲苯制备亚苯基二氧代二酯增塑剂的方法，溴化合物的催化羰基烷氧基化形成亚苯基二乙酸酯，然后酯交换以形成亚苯基氧代二酯。
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公开(公告)号：US20110165355A1
公开(公告)日：2011-07-07
申请号：US12880586
申请日：2010-09-13
申请人： Jihad Mohammed Dakka , Edmund John Mozeleski , Lisa Saunders Baugh , Jon Edmond Randolph Stanat , Karla Schall Colle , Francisco Manuel Benitez , Peter Stokes James , Allen David Godwin , Carl Robert Beck
发明人： Jihad Mohammed Dakka , Edmund John Mozeleski , Lisa Saunders Baugh , Jon Edmond Randolph Stanat , Karla Schall Colle , Francisco Manuel Benitez , Peter Stokes James , Allen David Godwin , Carl Robert Beck
CPC分类号： C07C67/38 , C08K5/103 , Y10T428/139 , Y10T442/20 , C07C69/30
摘要： Provided are compositions, processes for making, and processes for using neoalkyl polyol esters and triglycerides as plasticizers. In one form, a neoalkylester triglyceride plasticizers can be produced by (i) drying a polyol feedstream; (ii) contacting in a reactor the dried polyol feedstream with a neoacid feedstream under effective temperature, pressure and time to form a neoalkylester plasticizer effluent stream, and (iii) purifying the neoalkylester plasticizer effluent stream to remove unreacted polyol and unreacted neoacid to form a neoalkylester plasticizer. Such plasticizers can be phthalate-free and provide outstanding properties including a suitable melting or pour point, glass transition temperature, low volatility, increased compatibility, increased hydrolytic stability, and excellent low temperature properties in a range of polymeric resins.
摘要翻译： 提供了组合物，制备方法和使用新烷基多元醇酯和甘油三酸酯作为增塑剂的方法。 在一种形式中，新烷基酯甘油三酯增塑剂可以通过（i）干燥多元醇进料流来制备; （ii）在有效温度，压力和时间下在干燥的多元醇原料流中与干燥的多元醇原料流接触以形成新的烷基酯增塑剂流出物流，和（iii）纯化新烷基酯增塑剂流出物流以除去未反应的多元醇和未反应的新酸，形成 新烷基酯增塑剂。 这种增塑剂可以是无邻苯二甲酸酯，并且提供突出的性能，包括合适的熔点或倾点，玻璃化转变温度，低挥发性，增加的相容性，增加的水解稳定性和在一系列聚合物树脂中的优异的低温性能。
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公开(公告)号：US08476350B2
公开(公告)日：2013-07-02
申请号：US12653744
申请日：2009-12-17
CPC分类号： C08L91/00 , C08K5/103 , Y10T428/139 , Y10T442/20 , C08L27/06 , C08L67/00 , C08L75/04 , C08L31/04 , C08L33/00
摘要： Provided are compositions, processes for making, and processes for using triglycerides as plasticizers. Triglyceride plasticizers can be produced by recovery of linear or branched C4 to C10 aldehydes from a hydroformylation product, oxidation to the acid with oxygen and/or air, recovery of the resulting acid, and esterification with glycerol, wherein the total carbon number of the triester groups is from 20 to 25 for greater than or equal to 45 wt % of the plasticizer. Such plasticizers can be phthalate-free and provide outstanding properties including a suitable melting or glass transition or pour point, low volatility, increased compatibility, and excellent low temperature properties in a range of polymeric resins.
摘要翻译： 提供组合物，制备方法和使用甘油三酯作为增塑剂的方法。 甘油三酯增塑剂可以通过从加氢甲酰化产物中回收线性或分支的C 4至C 10醛，用氧和/或空气氧化成酸，回收所得酸，并用甘油进行酯化来制备，其中三酯的总碳数 对于大于或等于45重量％的增塑剂，基团为20至25。 这种增塑剂可以是无邻苯二甲酸酯，并提供突出的性能，包括合适的熔融或玻璃化转变或倾点，低挥发性，增加的相容性和在一系列聚合物树脂中的优异的低温性能。
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7.发明授权Oil based polyols or diacids esterified with oxo-acids or oxo-alcohols for producing plasticizers 有权用含氧酸或羰基醇酯化的油基多元醇或二酸用于生产增塑剂公开(公告)号：US08329795B2
公开(公告)日：2012-12-11
申请号：US12830606
申请日：2010-07-06
申请人： Jihad Mohammed Dakka , Edmund John Mozeleski , Lisa Saunders Baugh , Allen David Godwin , Diana S. Smirnova
发明人： Jihad Mohammed Dakka , Edmund John Mozeleski , Lisa Saunders Baugh , Allen David Godwin , Diana S. Smirnova
IPC分类号： C08K5/00
CPC分类号： C07C67/08 , C07C5/32 , C07C29/147 , C07C45/50 , C07C51/16 , C07C67/26 , C07C69/28 , C07C69/75 , C07C2601/14 , C07C2603/68 , C08K5/10 , C07C35/08 , C07C47/32 , C07C61/08
摘要： Oxo-diesters of cyclic olefins, methods of making them and their use as plasticizers in polymer compositions are disclosed.
摘要翻译： 公开了环烯烃的氧代二酯，其制备方法及其作为增塑剂在聚合物组合物中的用途。
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公开(公告)号：US20110151162A1
公开(公告)日：2011-06-23
申请号：US12971629
申请日：2010-12-17
CPC分类号： C07C67/08 , C08K5/0016 , C08K5/103 , C08L23/0853 , C08L91/00 , Y02P20/582 , Y10T428/1352 , Y10T428/139 , C07C69/30 , C08L27/06
摘要： Provided are processes for making, and processes for using triglycerides as plasticizers. The process for making the triglyceride plasticizer includes: (i) recovering at least one linear C4 to C10 aldehyde, one branched C4 to C10 aldehyde, or a combination thereof from a hydroformylation product; (ii) oxidizing the linear, branched or combination thereof C4 to C10 aldehyde to form a linear, branched or combination thereof C4 to C10 acid; (iii) esterifying the linear, branched or combination thereof C4 to C10 acid with a polyol to yield a linear alkyl triglyceride, a branched alkyl triglyceride, or a combination thereof, and reaction byproducts; (iv) purifying the linear, branched or combination thereof alkyl triglyceride to form a plasticizer stream, a reaction byproduct stream, and an unreacted input stream, wherein the total carbon number of the triester groups ranges from 20 to 25 for greater than or equal to 45 wt % of the plasticizer; and (v) recycling from the purifying step back to the esterifying step the unreacted input stream and the reaction byproduct stream.
摘要翻译： 提供了制备方法和使用甘油三酯作为增塑剂的方法。 制备甘油三酯增塑剂的方法包括：（i）从加氢甲酰化产物中回收至少一种线性C 4至C 10醛，一个支链C 4至C 10醛或其组合; （ii）将其直链，支链或其组合C4至C10醛氧化以形成其直链，支链或其组合C4至C10的酸; （iii）用多元醇酯化其直链，支链或其组合C4至C10酸，得到直链烷基甘油三酯，支链烷基甘油三酸酯或其组合，以及反应副产物; （iv）纯化其直链，支链或其组合的烷基甘油三酸酯以形成增塑剂流，反应副产物流和未反应的输入流，其中三酯基团的总碳数在20至25之间，大于或等于 45重量％的增塑剂; 和（v）从净化步骤回收到酯化步骤未反应的输入流和反应副产物流。
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公开(公告)号：US20140316166A1
公开(公告)日：2014-10-23
申请号：US14007281
申请日：2011-11-28
IPC分类号： C07C37/08 , C07C45/53 , C07C407/00
CPC分类号： C07C37/08 , C07C45/53 , C07C407/00 , C07C407/003 , C07C2601/14 , C07C409/14 , C07C39/04 , C07C49/403
摘要： In a process for producing cyclohexylbenzene hydroperoxide, cyclohexylbenzene is contacted with oxygen to produce a reaction product comprising cyclohexylbenzene hydroperoxide and unreacted cyclohexylbenzene. The reaction product is then maintained under conditions such that crystals of cyclohexylbenzene hydroperoxide form and separate from the reaction product. The cyclohexylbenzene hydroperoxide crystals are then recovered from the reaction product.
摘要翻译： 在制备环己基苯氢过氧化物的方法中，使环己基苯与氧气接触以产生包含环己基苯氢过氧化物和未反应的环己基苯的反应产物。 然后将反应产物保持在使得环己基苯氢过氧化物的晶体形成并与反应产物分离的条件下。 然后从反应产物中回收环己基苯氢过氧化物晶体。
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公开(公告)号：US08568846B2
公开(公告)日：2013-10-29
申请号：US12880586
申请日：2010-09-13
申请人： Jihad Mohammed Dakka , Edmund John Mozeleski , Lisa Saunders Baugh , Jon Edmond Randolph Stanat , Karla Schall Colle , Francisco Manuel Benitez , Peter Stokes James , Allen David Godwin , Carl Robert Beck
发明人： Jihad Mohammed Dakka , Edmund John Mozeleski , Lisa Saunders Baugh , Jon Edmond Randolph Stanat , Karla Schall Colle , Francisco Manuel Benitez , Peter Stokes James , Allen David Godwin , Carl Robert Beck
CPC分类号： C07C67/38 , C08K5/103 , Y10T428/139 , Y10T442/20 , C07C69/30
摘要： Provided are compositions, processes for making, and processes for using neoalkyl polyol esters and triglycerides as plasticizers. In one form, a neoalkylester triglyceride plasticizers can be produced by (i) drying a polyol feedstream; (ii) contacting in a reactor the dried polyol feedstream with a neoacid feedstream under effective temperature, pressure and time to form a neoalkylester plasticizer effluent stream, and (iii) purifying the neoalkylester plasticizer effluent stream to remove unreacted polyol and unreacted neoacid to form a neoalkylester plasticizer. Such plasticizers can be phthalate-free and provide outstanding properties including a suitable melting or pour point, glass transition temperature, low volatility, increased compatibility, increased hydrolytic stability, and excellent low temperature properties in a range of polymeric resins.
摘要翻译： 提供了组合物，制备方法和使用新烷基多元醇酯和甘油三酸酯作为增塑剂的方法。 在一种形式中，新烷基酯甘油三酯增塑剂可以通过（i）干燥多元醇进料流来制备; （ii）在有效温度，压力和时间下在干燥的多元醇原料流中与干燥的多元醇原料流接触以形成新的烷基酯增塑剂流出物流，和（iii）纯化新烷基酯增塑剂流出物流以除去未反应的多元醇和未反应的新酸，形成 新烷基酯增塑剂。 这种增塑剂可以是无邻苯二甲酸酯，并且提供突出的性能，包括合适的熔点或倾点，玻璃化转变温度，低挥发性，增加的相容性，增加的水解稳定性和在一系列聚合物树脂中的优异的低温性能。
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