Linear polyurethane elastomer compositions based on mixed polycarbonate
and polyether polyols
    5.
    发明授权
    Linear polyurethane elastomer compositions based on mixed polycarbonate and polyether polyols 失效
    基于混合聚碳酸酯和聚醚多元醇的线性聚氨酯弹性体组合物

    公开(公告)号:US5001208A

    公开(公告)日:1991-03-19

    申请号:US326865

    申请日:1989-03-20

    摘要: New linear polyurethane elastomers have been developed by combining a polycarbonate polyol, a polyether polyol, at least two extenders, and a solid diisocyanate compound. Preferably, the diisocyanate compound is modified by reaction with one of the extenders to form a modified diisocyanate component which is a liquid at room temperature prior to reaction with the polyols and other extender. These new elastomers possess a unique combination of hydrolytic stability, toughness, flexibility, and relatively low temperature processability.

    摘要翻译: 已经通过组合聚碳酸酯多元醇,聚醚多元醇,至少两种增量剂和固体二异氰酸酯化合物来开发新的线型聚氨酯弹性体。 优选地,通过与一种增量剂反应来改性二异氰酸酯化合物,以在与多元醇和其它增量剂反应之前在室温下形成一种液体的改性二异氰酸酯组分。 这些新型弹性体具有水解稳定性,韧性,柔韧性和相对低温加工性的独特组合。

    Use of modified diisocyanates for preparing linear thermoplastic
polyurethane elastomers having improved properties
    7.
    发明授权
    Use of modified diisocyanates for preparing linear thermoplastic polyurethane elastomers having improved properties 失效
    使用改性二异氰酸酯制备具有改进性能的线性热塑性聚氨酯弹性体

    公开(公告)号:US5013811A

    公开(公告)日:1991-05-07

    申请号:US326183

    申请日:1989-03-20

    申请人: Bert A. Ross

    发明人: Bert A. Ross

    摘要: Linear polyurethane elastomers of a polyol component, at least two extender components, and a diisocyanate compound are prepared by reacting the diisocyanate compound with one of the extender components to form a modified diisocyanate component having a functionality of about 2 prior to reacting this modified component with the other components of the elastomer. These new elastomers can be processed at lower temperatures compared to elastomers prepared from similar compositions wherein the isocyanate compound is not modified.

    摘要翻译: 多元醇组分,至少两种增量组分和二异氰酸酯化合物的线性聚氨酯弹性体通过使二异氰酸酯化合物与其中一种增量剂组分反应,以使该改性组分与 弹性体的其他组分。 与其中异构化合物未被改性的类似组合物制备的弹性体相比,这些新的弹性体可以在较低的温度下进行处理。

    Polymer compositions containing salicylic acid chelates as oxygen
scavengers
    8.
    发明授权
    Polymer compositions containing salicylic acid chelates as oxygen scavengers 失效
    包含水杨酸螯合物作为除氧剂的聚合物组合物

    公开(公告)号:US5364555A

    公开(公告)日:1994-11-15

    申请号:US124993

    申请日:1993-09-21

    摘要: An oxygen scavenging composition of a carrier, such as a polymer, which is permeable to both oxygen and water or water vapor and an oxygen scavenging compound of an organic compound or salt thereof dispersed relatively uniformly throughout the polymer in an amount effective to act as an oxygen scavenger. The oxygen scavenging compound is a salicylic acid chelate or complex of a transition metal or a salt thereof. The oxygen scavenging composition is activated for scavenging oxygen by contact with water or water vapor which permeates into or through the carrier. A reducing agent of an ascorbate compound may be added to enhance the performance of the salicylic acid chelate or complex. The oxygen scavenging compound may be added to the composition in a dry state, and is inactive until activated for oxygen scavenging by contact with water or water vapor.

    摘要翻译: 可透过氧气和水或水蒸气的载体如聚合物的氧气清除组合物和有机化合物或其盐的氧清除化合物相对均匀地分散在整个聚合物中,其量有效地用作 除氧剂 除氧化合物是过渡金属或其盐的水杨酸螯合物或络合物。 氧清除组合物通过与渗透到载体中或通过载体的水或水蒸汽接触来活化以清除氧。 可以加入抗坏血酸盐化合物的还原剂以增强水杨酸螯合物或络合物的性能。 氧清除化合物可以在干燥状态下加入到组合物中,并且通过与水或水蒸汽接触而活化,直到被氧气清除为止。

    Amino polycarboxylic acid compounds as oxygen scavengers
    9.
    发明授权
    Amino polycarboxylic acid compounds as oxygen scavengers 失效
    氨基多羧酸化合物作为除氧剂

    公开(公告)号:US5202052A

    公开(公告)日:1993-04-13

    申请号:US581507

    申请日:1990-09-12

    摘要: An oxygen scavenging composition of a polymer which is permeable to both oxygen and water or water vapor, and an oxygen scavenging material of an amino polycarboxylic acid chelate or complex of a transition metal, or salt thereof, dispersed relatively uniformly throughout the polymer in an amount effective to act as an oxygen scavenger when activated for scavenging oxygen by contact with water or water vapor which permeates the polymer. A preferred oxygen scavenging compound is ferrous EDTA or salts thereof. Also, an ascorbate compound may be used as a preservative or augmenter for the oxygen scavenging compound.

    摘要翻译: 能够透过氧气和水或水蒸汽的聚合物的氧气清除组合物以及过渡金属或其盐的氨基多羧酸螯合物或络合物的氧清除材料以相对均匀地分散在整个聚合物中的量 当通过与渗透聚合物的水或水蒸气接触而被氧化除氧时被有效地用作除氧剂。 优选的除氧化合物是亚铁EDTA或其盐。 此外,还可以使用抗坏血酸盐化合物作为除氧化合物的防腐剂或增强剂。

    Metal catalyzed ascorbate compounds as oxygen scavengers
    10.
    发明授权
    Metal catalyzed ascorbate compounds as oxygen scavengers 失效
    金属催化的抗坏血酸化合物作为除氧剂

    公开(公告)号:US06709724B1

    公开(公告)日:2004-03-23

    申请号:US08783714

    申请日:1997-01-16

    IPC分类号: C09K1500

    摘要: An oxygen scavenging composition of a carrier, such as a polymer, which is permeable to both oxygen and water or water vapor and an oxygen scavenging compound of an organic compound or salt thereof dispersed relatively uniformly throughout the polymer in an amount effective to act as an oxygen scavenger. The oxygen scavenging compound is activated for scavenging oxygen by contact with water or water vapor which permeates into or through the carrier. Also, a catalyzing agent is included in an amount sufficient to increase the rate of oxygen scavenging by the organic compound. The organic compound and catalyzing agent are preferably maintained in a dry state by freeze drying or microencapsulation until the organic compound is activated for oxygen scavenging by contact with water or water vapor.

    摘要翻译: 可透过氧气和水或水蒸气的载体如聚合物的氧气清除组合物和有机化合物或其盐的氧清除化合物相对均匀地分散在整个聚合物中,其量有效地用作 除氧剂 氧清除化合物通过与渗透到载体中或通过载体的水或水蒸汽接触来活化以清除氧。 而且,催化剂的含量足以提高有机化合物的氧清除速率。 有机化合物和催化剂优选通过冷冻干燥或微胶囊化将其保持在干燥状态,直到有机化合物通过与水或水蒸汽接触而被氧化除氧。