公开(公告)号：US4418175A

公开(公告)日：1983-11-29

申请号：US329721

申请日：1981-12-11

申请人： Joachim Probst ,  Gunter Kolb ,  Friedhelm Muller ,  Heinz Baumgen

发明人： Joachim Probst ,  Gunter Kolb ,  Friedhelm Muller ,  Heinz Baumgen

IPC分类号： D21H19/20 ,  C08F8/44 ,  D21H17/35 ,  D21H17/37 ,  D21H17/45 ,  C08F220/46

CPC分类号： D21H17/455 ,  C08F8/44 ,  D21H17/35 ,  D21H17/37

摘要： The aqueous solution of a statistical terpolymer containing quaternized amino groups and having a regular chemical structure of(a) from 8 to 20%, by weight, of N,N-dimethylaminoethyl acrylate and/or N,N-dimethylaminoethyl methacrylate;(b) from 45 to 80%, by weight, of styrene; and(c) from 8 to 35%, by weight, of acrylonitrile;the sum of (a) to (c) being 100%, by weight, and at least 10% of the dimethylamino groups of the terpolymer being quaternized and the remainder protonated is suitable as cationic paper sizing agent.

摘要翻译： 具有季铵化氨基的统计三元共聚物的水溶液，其具有规则的化学结构（a）8至20重量％的丙烯酸N，N-二甲基氨基乙酯和/或甲基丙烯酸N，N-二甲基氨基乙酯; （b）45〜80重量％的苯乙烯; 和（c）8至35重量％的丙烯腈; （a）至（c）的总和为100重量％，并且至少10％的三元共聚物的二甲基氨基被季铵化，其余被质子化适合作为阳离子纸上胶剂。

公开(公告)号：US4481319A

公开(公告)日：1984-11-06

申请号：US410906

申请日：1982-08-24

申请人： Gunter Sackmann ,  Gunter Kolb ,  Joachim Probst ,  Friedhelm Muller ,  Heinz Baumgen

发明人： Gunter Sackmann ,  Gunter Kolb ,  Joachim Probst ,  Friedhelm Muller ,  Heinz Baumgen

IPC分类号： C08F8/32 ,  D21H17/35 ,  D21H17/43 ,  D21H17/45 ,  C08K5/21 ,  C08K5/05

CPC分类号： D21H17/45 ,  C08F8/32 ,  D21H17/35 ,  D21H17/43

摘要： Low-foam surface sizing agents for paper in the form of aqueous or aqueous-alcoholic alkali metal, amine or ammonium salt solutions of copolymers containing carboxylic acid semi-amide groups obtainable by reacting copolymers of maleic acid anhydride and diisobutylene and/or terpolymers of maleic acid anhydride, diisobutylene and a vinyl monomer copolymerizing with maleic acid anhydride, with from 5 to 50 mole percent, based on maleic acid anhydride groups, of a primary aliphatic or aromatic monoamine. The solutions may optionally contain urea or derivatives of urea.

摘要翻译： 水性或水性醇碱金属形式的纸的低泡表面施胶剂，含有羧酸半酰胺基团的共聚物的胺或铵盐溶液，可通过马来酸酐和二异丁烯的共聚物和/或马来酸三元共聚物 与马来酸酐共聚的酸酐，二异丁烯和乙烯基单体，基于马来酸酐基团的5-50摩尔％的伯脂肪族或芳族单胺。 溶液可以任选地含有脲或尿素衍生物。

公开(公告)号：US4806591A

公开(公告)日：1989-02-21

申请号：US921173

申请日：1986-10-20

申请人： Joachim Probst ,  Heinz Baumgen ,  Bruno Bomer ,  Joachim Konig ,  Renke Mottweiler

发明人： Joachim Probst ,  Heinz Baumgen ,  Bruno Bomer ,  Joachim Konig ,  Renke Mottweiler

IPC分类号： C08F2/28 ,  C08F2/24 ,  C08F257/02 ,  D21H17/35 ,  D21H17/37 ,  D21H17/45 ,  C08L33/20

CPC分类号： D21H17/455 ,  C08F2/24 ,  C08F257/02 ,  D21H17/35 ,  D21H17/37

摘要： Cationic sizing agents for paper, obtainable by a process in which a water-soluble cationic terpolymer compound, built up in a chemically uniform manner, of (a) 7 to 40% by weight of N,N-dimethylaminoethyl acrylate and/or methacrylate, (b) 40 to 80% by weight of styrene and (c) 4 to 50% by weight of acrylonitrile, the sum of components (a) to (c) always being 100% by weight and at least 10% of the dimethylamino groups of the terpolymer being quaternized with monoepoxides, with the exception of epihalogenohydrins, and the remainder being protonated, is dissolved in an aqueous medium and, in the presence of 10 to 70% by weight--based on the following monomer mixture--of this emulsifier, (d) 5 to 95% by weight of acrylonitrile, meth-acrylonitrile or styrene or mixtures thereof and (e) 5 to 95% by weight of acrylic acid ester and/or methacrylic acid ester with 1 to 12 C atoms in the alcohol radical--the sum of components (d) and (e) always being 100% by weight--are emulsified and the emulsion thus obtained is subjected to emulsion polymerization, initiated by free radicals, at temperatures of 20.degree. to 150.degree. C.

摘要翻译： 可通过以下方法获得的阳离子上胶剂：其中以（a）7〜40重量％的N，N-二甲基氨基乙基丙烯酸酯和/或甲基丙烯酸酯组成的以化学均匀的方式构成的水溶性阳离子三元共聚物， （b）40至80重量％的苯乙烯和（c）4至50重量％的丙烯腈，组分（a）至（c）的总和总是100重量％，并且至少10重量％的二甲基氨基 的三元共聚物被单过氧化物季铵化，除了表卤代醇，其余的被质子化，溶解在水性介质中，并且在该乳化剂的基于下列单体混合物的10至70重量％的存在下， （d）5至95重量％的丙烯腈，甲基丙烯腈或苯乙烯或其混合物，和（e）5至95重量％的醇基中具有1至12个C原子的丙烯酸酯和/或甲基丙烯酸酯 组分（d）和（e）总是为100重量％的总和被乳化和乳液 由此获得的乳液聚合在20℃至150℃的温度下由自由基引发。

公开(公告)号：US5314721A

公开(公告)日：1994-05-24

申请号：US000751

申请日：1993-01-05

申请人： Michael Muller ,  Joachim Probst ,  Heinrich Alberts ,  Joachim Konig ,  Heinz Baumgen ,  Fritz Puchner

发明人： Michael Muller ,  Joachim Probst ,  Heinrich Alberts ,  Joachim Konig ,  Heinz Baumgen ,  Fritz Puchner

IPC分类号： C08F2/22 ,  B01F17/52 ,  C08F2/28 ,  D21H17/56 ,  D21H21/16 ,  D21H27/00 ,  B05D3/02

CPC分类号： C08F2/28

摘要： The new vinyl polymer dispersions are obtainable by free radical polymerisation of olefinically unsaturated monomers in the presence of a cationic polyamidoamine which has been rendered hydrophobic, and can be used as sizing agents for paper which are distinguished, in particular, by their shear, electrolyte, heat and storage stability.

摘要翻译： 新的乙烯基聚合物分散体可以通过烯属不饱和单体的自由基聚合在阳离子聚酰胺胺存在下获得，该阳离子聚酰胺胺已经变得疏水，并且可以用作纸的上浆剂，特别是其剪切，电解质， 储热稳定。

公开(公告)号：US5288787A

公开(公告)日：1994-02-22

申请号：US714317

申请日：1991-06-10

申请人： Gunter Sackmann ,  Wolfgang Henning ,  Joachim Probst ,  Joachim Konig ,  Heinz Baumgen

发明人： Gunter Sackmann ,  Wolfgang Henning ,  Joachim Probst ,  Joachim Konig ,  Heinz Baumgen

IPC分类号： C08F2/26 ,  C08F220/12 ,  D21H17/34 ,  C08K3/20

CPC分类号： D21H17/34 ,  C08F2/26 ,  C08F220/12

摘要： Emulsion polymers obtainable by emulsifying a mixture consisting ofA) 5 to 95 % by weight of at least one monomer from the series consisting of acrylonitrile, methacrylonitrile, optionally substituted styrene, vinyl carboxylate andB) 5 to 95 % by weight of acrylic and/or methacrylic esters,the sum of components A)+B) being 100% by weight, in the presence of an aqueous solution or dispersion of an anionically modified polyurethane, preferably containing --SO.sub.3.sup.-Me.sup.+ and/or -COO.sup.- Me.sup.+ groups (Me.sup.+ =cation, preferably H.sup.+, Na.sup.+, K.sup.+, Li.sup.+, NH.sub.4.sup.+ or a substituted ammonium ion), and subjecting the resulting emulsion to a polymerization initiated by free radicals.The emulsion polymers produced are preferably used as surface sizing agents for paper.

摘要翻译： 通过乳化由A）5-95重量％的至少一种由丙烯腈，甲基丙烯腈，任选取代的苯乙烯，乙烯基羧酸酯组成的系列中的至少一种单体的混合物得到的乳液聚合物和B）5-95重量％的丙烯酸和/ 或甲基丙烯酸酯，组分A）+ B的总和）为100重量％，在阴离子改性聚氨酯的水溶液或分散体存在下，优选含有-SO 3 Me +和/或-COO-Me +基团（Me + =阳离子，优选H +，Na +，K +，Li +，NH 4 +或取代的铵离子），并将所得乳液进行由自由基引发的聚合。 所生产的乳液聚合物优选用作纸的表面施胶剂。

公开(公告)号：US4904727A

公开(公告)日：1990-02-27

申请号：US318045

申请日：1989-03-02

申请人： Joachim Probst ,  Wolfgang Henning ,  Heinz Baumgen ,  Joachim Konig

发明人： Joachim Probst ,  Wolfgang Henning ,  Heinz Baumgen ,  Joachim Konig

IPC分类号： B01F17/52 ,  C08F2/28 ,  D21H17/28 ,  D21H17/35 ,  D21H17/37 ,  D21H17/57

CPC分类号： D21H17/57 ,  C08F2/28 ,  D21H17/28 ,  D21H17/35 ,  D21H17/37

摘要： Emulsion polymers obtained by emulsifying a monomer mixture of(A) 5-95% by weight of acrylonitrile, methacrylonitrile and/or substituted or unsubstituted styrene and(B) 5-95% by weight of acrylic and/or methacrylic acid esters containing 1-12 carbon atoms in the alcohol group,the sum of components (A)+(B) amounting to 100% by weight, in the presence of an aqueous solution or dispersion of a water soluble or water dispersible, cationically modified polyurethane, and subjecting the resulting emulsion to a radically initiated polymerization. The emulsion polymers are preferably used as paper sizes or in paper sizes together with conventional additives.

摘要翻译： 通过将（A）5-95重量％的丙烯腈，甲基丙烯腈和/或取代或未取代的苯乙烯和（B）5-95重量％的丙烯酸和/或甲基丙烯酸酯的单体混合物乳化而得到的乳液聚合物， 醇基中的12个碳原子，在水溶液或水分散性阳离子改性聚氨酯的水溶液或分散体的存在下，组分（A）+（B）的总和为100重量％，并对 所得乳液进行自由基引发的聚合。 乳液聚合物优选与纸张尺寸或纸张尺寸一起用于常规添加剂。

公开(公告)号：US4784727A

公开(公告)日：1988-11-15

申请号：US459314

申请日：1983-01-20

申请人： Wolf-Dieter Schroer ,  Joachim Probst ,  Ingeborg Kolb ,  Ulrich Beck ,  Peter Mummenhoff ,  Heinz Baumgen

发明人： Wolf-Dieter Schroer ,  Joachim Probst ,  Ingeborg Kolb ,  Ulrich Beck ,  Peter Mummenhoff ,  Heinz Baumgen

IPC分类号： D21H17/08 ,  D21H17/15 ,  D21H17/17 ,  D21H17/35 ,  D21H17/36 ,  D21H17/37 ,  D21H17/45 ,  D21H3/02

CPC分类号： D21H17/08 ,  D21H17/15 ,  D21H17/17 ,  D21H17/35 ,  D21H17/36 ,  D21H17/37 ,  D21H17/455

摘要： A sizing agent which contains from 1 to 60 parts, by weight, of a fixing and sizing accelerating agent and from 0 to 80 parts, by weight, of conventional auxiliaries per 10 parts by weight of hydrophobic, cellulose-reactive sizing materials, the fixing and sizing accelerating agent being a polymer composed of linear or branched carbon chains, to which primary, secondary or tertiary amino and/or quaternary ammonium groups are bound directly or by side chains exhibits a thorough and rapid sizing effect, in particular in the better sizing of paper.

摘要翻译： 一种施胶剂，其含有1至60重量份的定影和施胶促进剂和0至80重量份的常规助剂，每10重量份疏水性纤维素反应性施胶材料，固定 和作为由直链或支链碳链构成的聚合物的定型促进剂，其中伯，仲或叔氨基和/或季铵基团直接或由侧链结合，表现出彻底和快速的施胶效果，特别是在更好的施胶 的纸。

公开(公告)号：US4659431A

公开(公告)日：1987-04-21

申请号：US691991

申请日：1985-01-16

申请人： Joachim Probst ,  Ulrich Beck ,  Heinz Baumgen

发明人： Joachim Probst ,  Ulrich Beck ,  Heinz Baumgen

IPC分类号： C08F2/00 ,  C08F2/24 ,  C08F2/28 ,  C08F212/00 ,  C08F212/08 ,  C08F220/00 ,  C08F220/10 ,  C08F220/12 ,  C08F257/02 ,  D21H17/35 ,  D21H17/37 ,  D21H17/45 ,  D21H19/20 ,  D21H21/16 ,  D21H3/38

CPC分类号： C08F257/02 ,  C08F2/24 ,  C08F212/08 ,  D21H17/35 ,  D21H17/37 ,  D21H17/455 ,  D21H21/16

摘要： New, highly effective cationic sizing agents for paper have been provided. They can be obtained by a method in which a water-soluble cationic chemically pure terpolymer compound consisting of(a) 7-40% by weight of N,N-dimethylaminoethyl acrylate and/or methacrylate,(b) 40-80% by weight of styrene and(c) 4-40% by weight of acrylonitrileis dissolved in an aqueous medium, the sum of the components (a) to (c) always being 100% by weight and at least 10% of the N,N-dimethylamino groups of the terpolymer being quaternized and the remainder being protonated, and, in the presence of 10 to 70% by weight, relative to the monomer mixture below, of this emulsifier,(d) 0 to 90% by weight of acrylonitrile and/or methacrylonitrile,(e) 5 to 95% by weight of styrene and(f) 5 to 95% by weight of acrylates and/or methacrylates having 1 to 12 C atoms in the alcohol radical,the sum of the components (d) to (f) always being 100% by weight, are emulsified, and the emulsion thus obtained is subjected to free radical-initiated emulsion polymerization at temperatures from 20.degree. to 150.degree. C.

摘要翻译： 已经提供了用于纸的新的高效阳离子上胶剂。 它们可以通过以下方法获得：其中由（a）7-40重量％的丙烯酸N，N-二甲基氨基乙酯和/或甲基丙烯酸酯组成的水溶性阳离子化学纯三元共聚物，（b）40-80重量％ 的苯乙烯和（c）4-40重量％的丙烯腈溶解在水性介质中，组分（a）至（c）的总和总是为100重量％，并且至少10重量％的N， 三元共聚物的二甲基氨基被季铵化，其余部分被质子化，并且在该乳化剂相对于单体混合物的10至70重量％的存在下，（d）0至90重量％的丙烯腈和/ 或甲基丙烯腈，（e）5至95重量％的苯乙烯和（f）5至95重量％的醇基中具有1至12个碳原子的丙烯酸酯和/或甲基丙烯酸酯，组分（d）至 （f）总是为100重量％，乳化，得到的乳液在20D的温度下进行自由基引发的乳液聚合 EG至150℃

公开(公告)号：US4614759A

公开(公告)日：1986-09-30

申请号：US762601

申请日：1985-08-05

申请人： Gunter Sackmann ,  Ulrich Beck ,  Heinz Baumgen

发明人： Gunter Sackmann ,  Ulrich Beck ,  Heinz Baumgen

IPC分类号： D21H17/37 ,  C08F8/14 ,  D21H17/43 ,  C08L35/02

CPC分类号： C08F8/14 ,  D21H17/43

摘要： Surface sizing agents for paper containing aqueous or aqueous-alcoholic alkali metal, amine or ammonium salt solutions of copolymers of maleic anhydride and diisobutylene and, if appropriate, a vinyl monomer of the formula ##STR1## in which R designates H, --CH.sub.3, --C.sub.2 H.sub.5, --OR.sub.2, --OCOCH.sub.3, ##STR2## or --CH.sub.2 --O--COCH.sub.3, R.sub.1 designates H or --CH.sub.3 andR.sub.2 designates alkyl, the anhydride groups of the copolymers being bis-esterified to the extent of 25-90 mol % with primary aliphatic monoalcohols with 1 to 12 C atoms.

摘要翻译： 含有水性或水性醇碱金属的纸的表面施胶剂，马来酸酐和二异丁烯的共聚物的胺或铵盐溶液，以及如果合适的话，其中R表示H，-CH 3， -C2H5，-OR2，-OCOCH3，...或-CH2-O-COCH3，R1表示H或-CH3，R2表示烷基，共聚物的酸酐基被双酯化至25〜90摩尔％ 具有1至12个C原子的伯脂族一元醇。

公开(公告)号：US4931510A

公开(公告)日：1990-06-05

申请号：US312089

申请日：1989-02-17

申请人： Gunter Sackmann ,  Joachim Konig ,  Heinz Baumgen

发明人： Gunter Sackmann ,  Joachim Konig ,  Heinz Baumgen

IPC分类号： C08F210/10 ,  B01F17/52 ,  C08F2/24 ,  C08F8/00 ,  C08F267/10 ,  D21H17/34 ,  D21H19/20 ,  D21H21/16

CPC分类号： D21H21/16 ,  C08F267/10 ,  D21H17/34

摘要： Polymers obtainable by subjecting at least one monomer, polymerizable by free radicals, to a free-radical emulsion polymerization in the presence of a polymer of the formulae I and/or II ##STR1## in which M, n, R, R.sup.1, R.sup.2, x and y have the meanings mentioned in the description, the use of the polymers obtained for surface-sizing of paper or paper-like materials and also novel polymers of the formulae I and/or II.

摘要翻译： 聚合物可以通过使至少一种可自由基聚合的单体在式I和/或II的聚合物存在下进行自由基乳液聚合，其中M，n，R R1，R2，x和y具有说明书中提到的含义，用于纸或纸状材料表面施胶的聚合物的用途，以及式I和/或II的新型聚合物。