摘要:
Emulsion polymers obtainable by emulsifying a mixture consisting ofA) 5 to 95 % by weight of at least one monomer from the series consisting of acrylonitrile, methacrylonitrile, optionally substituted styrene, vinyl carboxylate andB) 5 to 95 % by weight of acrylic and/or methacrylic esters,the sum of components A)+B) being 100% by weight, in the presence of an aqueous solution or dispersion of an anionically modified polyurethane, preferably containing --SO.sub.3.sup.-Me.sup.+ and/or -COO.sup.- Me.sup.+ groups (Me.sup.+ =cation, preferably H.sup.+, Na.sup.+, K.sup.+, Li.sup.+, NH.sub.4.sup.+ or a substituted ammonium ion), and subjecting the resulting emulsion to a polymerization initiated by free radicals.The emulsion polymers produced are preferably used as surface sizing agents for paper.
摘要:
Emulsion polymers obtained by emulsifying a monomer mixture of(A) 5-95% by weight of acrylonitrile, methacrylonitrile and/or substituted or unsubstituted styrene and(B) 5-95% by weight of acrylic and/or methacrylic acid esters containing 1-12 carbon atoms in the alcohol group,the sum of components (A)+(B) amounting to 100% by weight, in the presence of an aqueous solution or dispersion of a water soluble or water dispersible, cationically modified polyurethane, and subjecting the resulting emulsion to a radically initiated polymerization. The emulsion polymers are preferably used as paper sizes or in paper sizes together with conventional additives.
摘要:
The present invention relates to aqueous solutions or dispersions of polyisocyanate addition products which contain about 2 to 300 milliequivalents per 100 g of solids of chemically incorporated ternary or quaternary ammonium groups and up to about 25% by weight, based on solids, of chemically incorporated ethylene oxide units, --CH.sub.2 --CH.sub.2 --O--, present within a polyether chain, the ternary or quaternary ammonium groups and the ethylene oxide units being present in an amount sufficient to guarantee the solubility or dispersibility of the polyisocyanate addition products in water, characterized in that the polyisocyanate addition products have segments incorporated in the polymer chain which correspond to the following general formula ##STR1## in an amount of about 0.1 to 20% by weight based on the above formula, but excluding the weight of R.The present invention also relates to a process for the production of polyisocyanate addition products and to their use as coating agents for flexible or inflexible substrates and as sizing agents for paper or for the production sizing agents for paper.
摘要:
The present invention relates to aqueous solutions or dispersions of polyisocyanate addition products, which contain a quantity of incorporated sulphonate and/or carboxylate groups and optionally ethylene oxide units, --CH.sub.2 --CH.sub.2 --O--, incorporated in a polyether chain to guarantee the solubility or dispersibility thereof in water, the content of sulphonate and/or carboxylate groups being about 2 to 300 milliequivalents per 100 g of solids and the content of the aforementioned ethylene oxide units being up to about 25% by weight, based on solids, characterized in that the polyisocyanate addition products have segments incorporated in the polymer chain which correspond to the following general formula: ##STR1## in an amount of about 0.1 to 20% by weight based on the above formulas, but excluding the weight of R.The present invention also relates to a process for the production of the polyisocyanate addition products and to their use as coating agents for flexible or inflexible substrates and as sizing agents for paper or for the production of sizing agents for paper.
摘要:
The invention relates to adhesives based on aqueous dispersions and surface-deactivated isocyanate particles and to latently reactive coatings, films and powders produced from such dispersions. The adhesives are prepared from aqueous compositions containing a) dispersed polymers with isocyanate-reactive groups; b) at least one dispersed surface-deactivated aliphatic solid polyisocyanate with a softening temperature of ≧40° C.; c) one or more compounds of elements from subgroups 5 and 6 of the periodic system of elements, in which the particular element has an oxidation number of at least +4 and, d) optionally further additives and auxiliaries.
摘要:
The present invention relates to a coating composition which is suitable for coating plastics and contains a one- or two-component binder and, as an adhesion promoter, a chemically modified crystalline, chlorine-free polyolefin, which has an average molecular weight of 1,000 to 8,000, a non-uniformity of 1.0 to 6.5 and a content of nitrogen, oxygen, sulphur and/or silicon in the form of chemically incorporated functional groups of 1.5 to 17.5 wt % in total. The present invention also relates to a process for coating plastics using this coating composition and to the resulting coated plastics.
摘要:
Sensor with polycrystalline silicon resistors which are applied to a substrate and are covered with a dielectric passivating layer, characterized by the feature that the resistors are thermally adapted by targeted adjustment of their dopings and by suitable healing, and are balanced by laser trimming.
摘要:
A magnetic flux leakage method and apparatus for inspecting magnetizable test objects such as pipelines are disclosed. Magnetic diodes are connected to give temperature-independent readings of flux leakage and are spaced apart according to the size of the flaws sought to be detected. Groups of diodes are overlapped to provide complete coverage of the area sought to be inspected. Certain of the largest signals received at any one time from the groups of diodes are transmitted to recording means to reduce the number of signals recorded. Diode signals are subtracted from each other to determine relative differences in detected fluxes. For inspecting pipelines, the diodes and magnets are mounted on the apparatus by mounting assemblies which pivot about three axes and the diodes and magnets are urged yieldingly toward the pipeline wall by members formed of open cell foam polyurethane. To aid in locating the flaws along the pipeline, signals from magnetic markers placed along the pipeline are detected and recorded with signals from flaws. This abstract is not to be construed in any way to define or limit the invention set forth below.
摘要:
The present invention relates to an aqueous polyurethane or polyurethane-urea dispersion comprising a polyurethane or a polyurethane polyurea dispersed therein, wherein the polyurethane or polyurethane polyurea comprises terminal carboxyl groups and lateral sulfonate and/or carboxylate groups.
摘要:
Preparations of surface-deactivated solid isocyanates which are dispersed in finely particulate manner, with aqueous isocyanate-reactive polymer dispersions that include a) dispersed polymers having isocyanate-reactive groups, b) dispersed surface-deactivated oligomeric solid polyisocyanates, and c) at least one catalyst, where the catalyst or the totality of catalysts accelerates the reaction of the monomeric polyisocyanates which form by the thermal cleavage of the oligomeric polyisocyanates more strongly than the thermal cleavage itself. The preparations are prepared by mixing aqueous dispersions of at least one isocyanate-reactive polymer with at least one dispersed surface-deactivated oligomreric solid polyisocyanate and at least one catalyst. The preparations can be used in binders, films and powders for bonded joints, or coatings and to make a latently cross-linking adhesive layer. Substrates can be coated with layers obtainable with the above-described preparations.