摘要:
Enol ethers of the formula (I) where R1 to R3 are each, independently of one another, hydrogen or a carbon-containing organic radical and R4 is an unsubstituted or substituted alkyl radical, are prepared by reacting alcohols of the formula (II) R4—OH (II), with alkynes of the formula (IlIa), alkadienes of the formula (IIIb) R1—C≡C—CHR2R3 (IIIa), R1—CH═C═CR2R3 (IIIb) or mixtures thereof, where R1 to R4 are as defined above, in the presence of an alkali metal alkoxide and a polar, aprotic solvent.
摘要:
In one aspect, a rechargeable lithium battery comprising a non-aqueous electrolyte including an organic solvent; a lithium salt and a substituted 2-fluoroalkoxy-1,3,2-dioxaphospholane 2-oxide is provided. The 2-fluoroalkoxy-1,3,2-dioxaphospholane 2-oxide can be a compound represented by the following Chemical Formula 1.
摘要:
Organic electrolytic solutions are provided. One solution includes a lithium salt, an organic solvent including a first solvent having high permittivity and a second solvent having a low boiling point, and a phosphate compound. By using the phosphate based compound, the organic electrolytic solution and the lithium battery including the organic electrolytic solution are flame resistant and have excellent charge/discharge properties. As a result, the lithium battery is highly stable and reliable and has good charge/discharge efficiency.
摘要:
In one aspect, a rechargeable lithium battery comprising a non-aqueous electrolyte including an organic solvent; a lithium salt and a substituted 2-fluoroalkoxy-1,3,2-dioxaphospholane 2-oxide is provided. The 2-fluoroalkoxy-1,3,2-dioxaphospholane 2-oxide can be a compound represented by the following Chemical Formula 1.
摘要:
An organic electrolytic solution is provided which includes a lithium salt, an organic solvent including a first solvent having high permittivity and a second solvent having a low boiling point, and a phosphine oxide compound The phosphine oxide compound imparts flame resistance and good charge/discharge properties, thereby producing a lithium battery that is highly stable and reliable and that has good charge/discharge efficiency.
摘要:
An organic electrolyte solution including: a lithium salt; an organic solvent including a high permittivity solvent and a low boiling solvent; and a silane-based compound represented by Formula 1 below: In Formula 1, m and n are each independently integers of from 1 to 30; and R1, R2, R3, R4, R5, R6, R7, and R8 are represented in the detailed description of the present invention. The organic electrolyte solution can be included in a lithium battery, so as to suppress the degradation of an electrolyte, and to improve cycle properties and life span of the battery.
摘要:
An organic electrolyte solution includes a lithium salt; an organic solvent including a high permittivity solvent and a low boiling solvent; and a vinyl-based compound represented by Formula 1 below, wherein m and n are each independently integers of 1 to 10; X1, X2, and X3 each independently represent O, S, or NR9; and R1, R2, R3, R4, R5, R6, R7, R8, and R9 are represented in the detailed description. The organic electrolyte solution of the present invention and a lithium battery using the same suppress degradation of an electrolyte, providing improved cycle properties and life span thereof.
摘要:
An organic electrolyte solution includes a lithium salt; an organic solvent including a high permittivity solvent and a low boiling solvent; and a vinyl-based compound represented by Formula 1 below, wherein m and n are each independently integers of 1 to 10; X1, X2, and X3 each independently represent O, S, or NR9; and R1, R2, R3, R4, R5, R6, R7, R8, and R9 are represented in the detailed description. The organic electrolyte solution of the present invention and a lithium battery using the same suppress degradation of an electrolyte, providing improved cycle properties and life span thereof.
摘要:
Provided is a lithium battery in which the cathode comprises an electroactive sulfur-containing material and the electrolyte comprises a lithium salt, a non-aqueous solvent, and one or more capacity-enhancing reactive components. Suitable reactive components include electron transfer mediators of the formula: wherein: R4 is the same or different at each occurrence and is selected from the group consisting of H, alkyl, alkenyl, aryl, or substituted derivatives thereof; E is the same or different at each occurrence and is selected from the group consisting of O, NR5, and S; where R5 is alkyl, aryl, or substituted derivatives thereof; a is an integer from 0 to 1; and r is an integer from 2 to 5. Also are provided methods for making the lithium battery.
摘要:
The present invention relates to novel electroactive energy storing polyacetylene-co-polysulfur (PAS) materials of general formula (C2Sx)n wherein x is greater than 1 to about 100, n is equal to or greater than 2, and the sulfur chain is bound to the polymer by both terminal sulfur atoms. This invention also relates to novel rechargeable electrochemical cells containing positive electrode materials comprised of said polyacetylene-co-polysulfur materials with improved storage capacity and cycle life at ambient and sub-ambient temperatures.