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公开(公告)号：US06268441B1
公开(公告)日：2001-07-31
申请号：US09308633
申请日：1999-05-27
IPC分类号： C08F216
摘要： Vinyl monomers are polymerized in the aqueous phase in the presence of at least one N-oxyl compound of a secondary amine, having no hydrogen atoms bonded to the &agr; carbon atoms. This process substantially eliminates deposits on reactor surfaces.
摘要翻译： 乙烯基单体在水相中在至少一种不具有与α碳原子键合的氢原子的仲胺的N-氧基化合物的存在下聚合。 该方法基本上消除了反应器表面上的沉积物。
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公开(公告)号：US06379588B1
公开(公告)日：2002-04-30
申请号：US09269165
申请日：1999-03-23
申请人： Heinz Friedrich Sutoris , Andreas Koch , Alexander Aumüller , Jacques Dupuis , Manfred Niessner
发明人： Heinz Friedrich Sutoris , Andreas Koch , Alexander Aumüller , Jacques Dupuis , Manfred Niessner
IPC分类号： C09K1516
CPC分类号： C07B63/04
摘要： A monomer composition, which contains A) vinyl-containing monomers in which a heteroatom selected from the group consisting of the halogens, nitrogen, oxygen, sulfur and silicon is present on the vinyl group, and B) a compound or a mixture of compounds of the formula II where R4 is methyl, ethyl, isopropyl, n-propyl, n-butyl, isobutyl, sec-butyl, tert-butyl or trimethylsilyl.
摘要翻译： 一种单体组合物，其含有A）含乙烯基的单体，其中选自卤素，氮，氧，硫和硅的杂原子存在于乙烯基上，B）化合物或式 其中R 4是甲基，乙基，异丙基，正丙基，正丁基，异丁基，仲丁基，叔丁基或三甲基甲硅烷基。
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3.发明授权Apparatus having a metallic surface protected from undesired deposition of polymer 失效具有金属表面的装置防止聚合物的不希望的沉积公开(公告)号：US06461440B1
公开(公告)日：2002-10-08
申请号：US09540199
申请日：2000-03-31
申请人： Heinz Friedrich Sutoris , Gerhard Wagenblast , Jürgen Schröder , Harald Keller , Rainer Rahm , Jürgen Decker , Thomas Jaworek , Volker Schliephake
发明人： Heinz Friedrich Sutoris , Gerhard Wagenblast , Jürgen Schröder , Harald Keller , Rainer Rahm , Jürgen Decker , Thomas Jaworek , Volker Schliephake
IPC分类号： C23G100
CPC分类号： C09D179/08 , B01J19/02 , B01J2219/0204 , B01J2219/0236 , B01J2219/0245 , C09D179/02
摘要： An article having a metallic surface treated with polymeric complexing agent is described. Particularly suitable polymeric complexing agents are phosphonoalkylated polyethyleneimines and/or carboxyalkylated polyethyleneimines and/or vinylimidazole polymers. As a rule, the treated metallic surface forms the total inner surface or a part of the inner surface of a process apparatus or of a container. The surface is protected by the treatment, in particular from the adhesion of polymer.
摘要翻译： 描述了用聚合物络合剂处理金属表面的制品。 特别合适的聚合物络合剂是膦酰基烷基化聚乙烯亚胺和/或羧基烷基化的聚乙烯亚胺和/或乙烯基咪唑聚合物。 通常，经处理的金属表面形成处理装置或容器的内表面或内表面的一部分。 表面被处理保护，特别是聚合物的粘合。
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公开(公告)号：US06350827B1
公开(公告)日：2002-02-26
申请号：US09452451
申请日：1999-12-02
IPC分类号： C08F240
摘要： Disclosed is a process for pressurizing ethylenically unsaturated monomers to 200-5000 bar in the absence of a polymerization initiator, which comprises effecting said pressurizing in the presence of nitroxyl compounds of the formula I where R1 and R2 are singly C1-C4-alkyl or combine with the joining carbon atom to form a 5- or 6-membered saturated hydrocarbon ring, R3 is C1-C4-alkyl, and R4 is hydrogen or C1-C12-alkyl. Also disclosed are a process for preparing copolymers by such pressurization and subsequent polymerization and copolymers obtainable thereby.
摘要翻译： 公开了一种在不存在聚合引发剂的情况下将烯属不饱和单体加压至200-5000巴的方法，其包括在式I的硝酰基化合物存在下进行所述加压，其中R 1和R 2是单C1-C4烷基或与 连接碳原子以形成5-或6-元饱和烃环，R 3为C 1 -C 4 - 烷基，R 4为氢或C 1 -C 12 - 烷基。还公开了通过这种加压和随后的聚合和共聚物制备共聚物的方法 从而获得。
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公开(公告)号：US06696533B1
公开(公告)日：2004-02-24
申请号：US09446121
申请日：1999-12-27
IPC分类号： C08F400
CPC分类号： C08F4/00
摘要： A process of free-radically initiated aqueous emulsion polymerization, in which monomers are polymerized in the presence of a N-oxyl radical and by means of special free-radical polymerization initiators at more than 100° C. and at pressures above the vapor pressure of the polymerization mixture.
摘要翻译： 一种自由基引发的水乳液聚合方法，其中单体在N-氧基自由基的存在下通过特殊的自由基聚合引发剂在超过100℃和高于蒸气压的压力下聚合 聚合混合物。
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6.发明授权Substance mixtures containing stabilizers and compounds containing vinyl groups 失效含有稳定剂的物质混合物和含有乙烯基的化合物公开(公告)号：US06200460B1
公开(公告)日：2001-03-13
申请号：US09147394
申请日：1998-12-16
申请人： Heinz Friedrich Sutoris , Hermann Uhr , Konrad Mitulla , Jürgen Schröder , Roland Merger , Knut Kessel
发明人： Heinz Friedrich Sutoris , Hermann Uhr , Konrad Mitulla , Jürgen Schröder , Roland Merger , Knut Kessel
IPC分类号： C07C720
摘要： Substance mixtures comprising (A) vinyl-containing compounds, (B) an active amount of a mixture inhibiting the premature polymerization of the vinyl-containing compounds, comprising (i) at least one N-oxyl compound of a secondary amine which carries no hydrogen atoms on the &agr;-C atoms, and (ii) at least one iron compound, (C) if appropriate nitro compounds, and (D) if appropriate costabilizers, a process for inhibiting the premature polymerization of vinyl-containing compounds (A) and the use of mixture (B), if appropriate as a mixture with nitro compounds (C) and/or costabilizers (D), for inhibiting the premature polymerization of free radical polymerizable compounds and for stabilizing organic materials against the damaging action of free radicals.
摘要翻译： 包含（A）含乙烯基化合物的物质混合物，（B）抑制含乙烯基化合物过早聚合的活性量的混合物，其包含（i）至少一种不携带氢的仲胺的N-氧基化合物 原子在α-C原子上，和（ii）至少一种铁化合物，（C）如果合适的硝基化合物，和（D）如果适当的稳定剂，一种抑制含乙烯基化合物（A）和 如果合适，使用混合物（B）作为与硝基化合物（C）和/或稳定剂（D）的混合物，用于抑制自由基可聚合化合物的过早聚合和稳定有机材料以抵抗自由基的破坏作用。
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公开(公告)号：US6143205A
公开(公告)日：2000-11-07
申请号：US117178
申请日：1998-08-03
IPC分类号： C07B63/04 , C07C7/20 , C07C11/02 , C07C15/44 , C07C15/46 , C07C51/50 , C09K15/16 , C09K15/08 , C09K15/22 , C10L7/20
摘要： Mixtures contain(A) vinyl-containing monomers, and(B) an effective amount of a mixture inhibiting the premature polymerization of the vinyl-containing monomers during the purification or distillation and containing(i) from 0.05 to 4.5% by weight, based on the total mixture (B), of at least one N-oxyl compound of a secondary amine which carries no hydrogen atoms on the .alpha.-carbon atoms and(ii)from 99.95 to 95.5% by weight, based on the total mixture (B), of at least one nitro compound,and a mixture (B) is used for inhibiting the premature polymerization of monomers.
摘要翻译： PCT No.PCT / EP97 / 02758 Sec。 371日期1998年8月3日 102（e）日期1998年8月3日PCT提交1997年5月28日PCT公布。 第WO97 / 46504号公报 日期1997年12月11日混合物含有（A）含乙烯基单体，和（B）有效量的混合物，其在纯化或蒸馏期间抑制含乙烯基单体的过早聚合，并含有（i）0.05至4.5％ 基于总混合物（B），至少一种在α-碳原子上不含氢原子的仲胺的至少一种N-氧基化合物，和（ii）基于所述α-烯烃的99.95至95.5重量％ 使用至少一种硝基化合物的总混合物（B）和（B）混合物来抑制单体的过早聚合。
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公开(公告)号：US5872252A
公开(公告)日：1999-02-16
申请号：US867041
申请日：1997-06-02
申请人： Heinz Friedrich Sutoris , Alexander Aumuller , Andreas Koch , Andreas Deckers , Eckard Schauss , Roger Klimesch , Arend Jouke Kingma , Wilhelm Weber
发明人： Heinz Friedrich Sutoris , Alexander Aumuller , Andreas Koch , Andreas Deckers , Eckard Schauss , Roger Klimesch , Arend Jouke Kingma , Wilhelm Weber
IPC分类号： C08F2/34 , C07B63/04 , C07C7/20 , C07C11/04 , C08F2/38 , C08F2/40 , C08F10/00 , C08F210/02 , C07D251/00
摘要： A process for compressing ethylenically unsaturated monomers at a pressure of 200-5000 bar in the absence of a polymerization initiator comprises carrying out compression in the presence of a sterically hindered amine derivative.
摘要翻译： 在不存在聚合引发剂的情况下，在200-5000巴的压力下压制烯属不饱和单体的方法包括在空间位阻胺衍生物的存在下进行压缩。
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公开(公告)号：US06639033B1
公开(公告)日：2003-10-28
申请号：US10048988
申请日：2002-02-19
申请人： Susanne Brinkmann-Rengel , Sylke Haremza , Heinz Friedrich Sutoris , David Christie , Roman Benedikt Raether , Jizhuang Cao
发明人： Susanne Brinkmann-Rengel , Sylke Haremza , Heinz Friedrich Sutoris , David Christie , Roman Benedikt Raether , Jizhuang Cao
IPC分类号： C08F200
CPC分类号： C07D265/30 , C07D241/04 , C07D265/34 , C07D279/12 , C07D279/14 , C08F4/00 , C08F12/08 , C08K5/34 , C08K5/3462 , C08K5/357 , C08K5/46 , C09K15/30
摘要： The present invention provides a process for the free radical polymerization of one or more ethylenically unsaturated monomers, said process comprising polymerizing one or more ethylenically unsaturated monomers in the presence of one or more N-oxyl radicals of formula II, wherein X is S, NR5, O, SO or SO2, R5 is C1-C20-alkyl or C5-C8-cycloalkyl and R3 and R4 independently of one another, are C1-C4-alkyl, phenyl, naphthyl or an aromatic five-membered ring, or R3 and R4 together are —(CH2)o— and p and o, independently of one another, are an integer from 2 to 7.
摘要翻译： 本发明提供了一种或多种烯键式不饱和单体的自由基聚合方法，所述方法包括在一种或多种式II的N-氧基存在下聚合一种或多种烯属不饱和单体，其中X是S， 5，O，SO或SO 2，R 5彼此独立地为C 1 -C 20 - 烷基或C 5 -C 8 - 环烷基且R 3和R 4为C 1 -C 4 - 烷基，苯基，萘基或 芳族五元环，或R 3和R 4一起为 - （CH 2）o - ，p和o彼此独立地为2至7的整数。
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公开(公告)号：US06518453B1
公开(公告)日：2003-02-11
申请号：US09856479
申请日：2001-07-03
申请人： Heinz Friedrich Sutoris , Gerhard Wagenblast , Volker Schliephake , Jürgen Schröder , Klaus Joachim Müller-Engel , Harald Keller , Thomas Jaworek
发明人： Heinz Friedrich Sutoris , Gerhard Wagenblast , Volker Schliephake , Jürgen Schröder , Klaus Joachim Müller-Engel , Harald Keller , Thomas Jaworek
IPC分类号： C07C6952
摘要： In a process for stabilizing chemical compounds having at least one ethylenically unsaturated bond to undesired free radical polymerization, a nitroxyl radical and a chemical compound containing phosphorus in chemically bonded form are added to the unsaturated compound present as pure substance or as a component of a mixture.
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