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1.发明授权Carbodiimide-modified polymethylene polyphenylene polyisocyanates for use in the preparation of polyisocyanurate-polyurethane foams 失效用于制备聚异氰脲酸酯 - 聚氨酯泡沫的碳二亚胺改性聚亚甲基多亚苯基多异氰酸酯
公开(公告)号：US4424288A
公开(公告)日：1984-01-03
申请号：US334158
申请日：1981-12-24
CPC分类号： C08G18/797 , C08G18/4829 , C08G2105/02 , Y10S521/901 , Y10S521/902
摘要： Liquid carbodiimide-modified organic polyisocyanates are prepared by reacting a crude polymethylene polyphenylene polyisocyanate containing no more than 70 weight percent diphenylmethane diisocyanate with an isomer mixture of 40 to 100 weight percent 4,4'-, 0 to 50 weight percent 2,4- and 0 to 10 weight percent 2,2'-diphenylmethane diisocyanate and having an average functionality of 2.1 to 2.7 and a free NCO content of at least 30 percent weight percent in the presence of an effective amount of carbodimidization catalyst. Polyisocyanurate-polyurethane foams prepared by reacting the modified polyisocyanates and polyols selected from the group consisting of diethylene glycol and ethylene oxide adducts of trimethylolpropane, trimethylolethane, glycerine, pentaerythritol, .alpha.-methylglucoside, sucrose, toluene diamine and methylene dianiline in the presence of trimerization catalysts exhibit improved compression strengths and K-factors with low friability and smoke density.
摘要翻译： 液体碳二亚胺改性的有机多异氰酸酯通过使含有不超过70重量％的二苯基甲烷二异氰酸酯的粗多亚甲基多亚苯基多异氰酸酯与40至100重量％的4,4'-，0至50重量％的2,4-和 0至10重量％的2,2'-二苯基甲烷二异氰酸酯，并且在有效量的碳二亚胺化催化剂存在下，其平均官能度为2.1至2.7，游离NCO含量为至少30重量％。 通过在三聚催化剂存在下，使改性多异氰酸酯和选自二甘醇和三羟甲基丙烷，三羟甲基乙烷，甘油，季戊四醇，α-甲基葡糖苷，蔗糖，甲苯二胺和亚甲基二苯胺的环氧乙烷加成物反应制备的聚异氰脲酸酯聚氨酯泡沫 表现出改善的压缩强度和具有低脆性和烟密度的K因子。
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2.发明授权Isocyanurate-modified polymethylene polyphenylene polyisocyanate compositions 失效异氰脲酸酯改性聚亚甲基多亚苯基多异氰酸酯组合物
公开(公告)号：US4382125A
公开(公告)日：1983-05-03
申请号：US325684
申请日：1981-11-30
CPC分类号： C08G18/794 , C08G18/3206 , C08G18/4833 , C08G18/7664 , Y10S521/902
摘要： A stable isocyanurate-modified polyisocyanate prepared by trimerizing an organic polyisocyanate mixture of 45 to 70 percent by weight of diphenylmethane diisocyanate having an isomer mixture of 40 to 100 weight percent, 4,4'-, 0 to 50 weight percent 2,4-, and 0 to 10 weight percent 2,2'-diphenylmethane diisocyanate and from 30 to 55 percent by weight polymethylene polyphenylene polyisocyanate with an isocyanurate content of 20 to 33 percent by weight. Polyurethane isocyanurate foams prepared from the reaction of these isocyanates with active hydrogen compounds selected from the group consisting of diethylene glycol and ethylene oxide adducts of trimethylolpropane, trimethylolethane, and glycerine exhibit good K- factors, low friability and low smoke density.
摘要翻译： 一种稳定的异氰脲酸酯改性的多异氰酸酯，它是通过将有机多异氰酸酯混合物的45-70％（重量比）的二异氰酸酯二异氰酸酯与40至100％（重量）的异构体混合物，4,4'-，0-50％（重量）的2,4- 和0至10重量％的2,2'-二苯基甲烷二异氰酸酯和30至55重量％的聚亚甲基聚亚苯基多异氰酸酯，异氰脲酸酯含量为20至33重量％。 由这些异氰酸酯与三羟甲基丙烷，三羟甲基乙烷和甘油的二甘醇和环氧乙烷加合物的活性氢化合物的反应制备的聚氨酯异氰脲酸酯泡沫显示出良好的K-因子，低脆性和低烟雾密度。
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3.发明授权Liquid carbodiimide- and uretonimine-isocyanurate-containing polyisocyanate compositions and microcellular foams made therefrom 失效含有碳二亚胺 - 和脲酮亚胺 - 异氰脲酸酯的多异氰酸酯组合物和由其制成的微孔泡沫体
公开(公告)号：US4284730A
公开(公告)日：1981-08-18
申请号：US119273
申请日：1980-02-07
申请人： Thirumurti Narayan , Peter T. Kan
发明人： Thirumurti Narayan , Peter T. Kan
IPC分类号： C07D229/00 , C07D251/34 , C08G18/79 , C08G18/14 , C08G18/16
CPC分类号： C08G18/79 , C07D229/00 , C07D251/34 , C08G2101/0008 , C08G2101/0025 , C08G2101/0066 , C08G2101/0083 , Y10S521/901 , Y10S521/902
摘要： The invention relates to carbodiimide- and/or uretonimine-isocyanurate-containing polyisocyanates, to the process for their preparation, and to microcellular foams prepared therefrom.These compositions may be prepared in the presence of the appropriate catalyst by(a) a partial trimerization of a mixture of polyisocyanate and carbodiimide and uretonimine containing polyisocyanate with trimer catalyst to the desired free isocyanate level,(b) sequential, partial carbodiimidization followed by partial trimerization of a polyisocyanate to the desired free isocyanate level(c) sequential partial trimerization of a polyisocyanate followed by partial carbodiimidization,(d) simultaneous conversion using the mixed catalyst system of carbodiimide and isocyanurate catalysts reacted to the desired free isocyanate level, and(e) blending liquid polyisocyanate with the carbodiimide and uretonimine containing polyisocyanate and isocyanurate containing polyisocyanate to the desired isocyanate level.
摘要翻译： 本发明涉及含碳二亚胺和/或脲酮亚胺 - 异氰脲酸酯的多异氰酸酯，其制备方法以及由其制备的微孔泡沫。 这些组合物可以在合适的催化剂存在下通过以下方法制备：（a）将多异氰酸酯和碳二亚胺与含脲醛亚胺的多异氰酸酯与三聚体催化剂的混合物部分三聚化为所需的游离异氰酸酯水平，（b）顺序的部分碳二亚胺化， 将多异氰酸酯三聚为所需的游离异氰酸酯水平（c）多异氰酸酯的顺序部分三聚化，然后进行部分碳二亚胺化，（d）使用碳二亚胺和异氰脲酸酯催化剂的混合催化剂体系同时转化反应至所需的游离异氰酸酯水平，（e ）将液体多异氰酸酯与含有碳二亚胺和含脲酮亚胺的多异氰酸酯和含异氰脲酸酯的多异氰酸酯混合至所需的异氰酸酯水平。
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4.发明授权Liquid isocyanurate-modified polymethylene bis(phenylisocyanate) compositions containing a high two-ring methylene bis(phenylisocyanate) content 失效含有高双环亚甲基双（异氰酸苯酯）含量的液体异氰脲酸酯改性的聚亚甲基双（异氰酸苯酯）组合物
公开(公告)号：US4743627A
公开(公告)日：1988-05-10
申请号：US95679
申请日：1987-09-14
申请人： Thirumurti Narayan , Peter T. Kan
发明人： Thirumurti Narayan , Peter T. Kan
CPC分类号： C08G18/022 , C08G18/794
摘要： A method for producing liquid isocyanurate modified Polymeric MDI composition containing a high two-ring MDI content, and foams made therefrom is described. The method comprises trimerizing a polymeric MDI in the presence of catalytically effective amount of a trimerization catalyst to form an isocyanurate containing polyisocyanate having a viscosity of about 100,000 mPas. The trimerization catalyst is thereafter deactivated and the isocyanurate-modified polyisocyanate is blended with a methylene bis(phenylisocyanate) (MDI) to form a final product having a two-ring content of about 60 percent of the total ring content and a viscosity comparable to polymeric MDI. Foams produced using this liquid isocyanurate modified polymeric MDI are of a substantially lighter color than those produced from standard polymeric MDI.
摘要翻译： 描述了含有高双环MDI含量的液体异氰脲酸酯改性聚合MDI组合物的方法和由其制成的泡沫体。 该方法包括在催化有效量的三聚催化剂存在下将聚合MDI三聚，以形成粘度为约100,000mPa·s的含异氰脲酸酯的多异氰酸酯。 然后，三聚催化剂失活，并将异氰脲酸酯改性的多异氰酸酯与亚甲基双（异氰酸苯酯）（MDI）共混以形成双环含量为总环含量的约60％的最终产物和与聚合物相当的粘度 MDI。 使用该液体异氰脲酸酯改性聚合MDI制备的泡沫的颜色比标准聚合MDI产生的泡沫要浅。
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5.发明授权Stabilizer package for polyurethane comprising a substituted cresol and another costabilizer 失效用于聚氨酯的稳定剂包，其包含取代的甲酚和另一种稳定剂
公开(公告)号：US4677154A
公开(公告)日：1987-06-30
申请号：US810238
申请日：1985-12-18
申请人： Thirumurti Narayan , Peter T. Kan
发明人： Thirumurti Narayan , Peter T. Kan
CPC分类号： C08K5/005
摘要： The invention relates to elimination of discoloration in polyurethanes, particularly thermoplastic polyurethanes, by the addition to the reaction mixture from 0.01 to 1 percent by weight, based on the isocyanate component, a stabilizer package characterized as BHT and a compound selected from tris(nonylphenyl) phosphite, tetrakis(2,4-di-t-butylphenyl)-4,4'-biphenylene diphosphonite, bis(2,4-di-t-butylphenyl)pentaerythritol diphosphite, 2,2'-oxamido-bis[ethyl-3(3,5-dit-butyl-4-hydroxyphenyl)]propionate, disteryl thiodipropionate, triisodecyl phosphite, trilauryl trithiophosphite, distearyl pentaerythritol, 2,2'-ethylene bis(4,6-di-tertiarylbutylphenol), octadecyl 3-(3',5'-di-t-butyl-4'-hydroxy phenyl) propionate, 4,4'-thio-bis(2-t-butyl-5-methylphenol), 4,4'-thio-bis(2-t-butyl-5-methylphenol), 2,2'-methylene-bis-(4-methyl-6-t-butylphenol), tris (3,5-di-t-butyl-4-hydroxybenzyl) isocyanurate, phenothiazine, tris(2,4-di-t-butylphenyl) phosphite, 4,4'-methylene bis(2,6-di-t-butylphenol), 2,6-di-t-butyldimethyl-aminomethylphenol and blends thereof.
摘要翻译： 本发明涉及消除聚氨酯，特别是热塑性聚氨酯中的变色，通过加入到反应混合物中，以异氰酸酯组分为基准，其量为0.01至1重量％，以BHT为特征的稳定剂包和选自三（壬基苯基） 亚磷酸酯，四（2,4-二叔丁基苯基）-4,4'-亚联苯基二亚膦酸酯，双（2,4-二叔丁基苯基）季戊四醇二亚磷酸酯，2,2'-氧代氨基 - 双[乙基-3 （3,5-二 - 丁基-4-羟基苯基）]丙酸酯，硫代二丙酸二十二烷酯，亚磷酸三异癸酯，三月桂基三硫代亚磷酸酯，二硬脂基季戊四醇，2,2'-亚乙基双（4,6-二叔丁基丁基酚），3- '，5'-二叔丁基-4'-羟基苯基）丙酸酯，4,4'-硫代 - 双（2-叔丁基-5-甲基苯酚），4,4'-硫代 - 双（2- 叔丁基-5-甲基苯酚），2,2'-亚甲基 - 双 - （4-甲基-6-叔丁基苯酚），三（3,5-二叔丁基-4-羟基苄基）异氰脲酸酯，吩噻嗪， 亚磷酸三（2,4-二叔丁基苯基）酯，4,4'-亚甲基双（2,6-二叔丁基苯酚） 6-二叔丁基二甲基氨基甲基苯酚及其混合物。
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6.发明授权Urethane modified carbodimide-isocyanurate foams from organic polyisocyanates and oxyalkylated mannich polyols 失效来自有机多异氰酸酯和烷氧基化甘露醇多元醇的聚氨酯改性的碳二亚胺 - 异氰脲酸酯泡沫
公开(公告)号：US3998766A
公开(公告)日：1976-12-21
申请号：US536605
申请日：1974-12-26
申请人： Peter T. Kan , Moses Cenker , John T. Patton, Jr.
发明人： Peter T. Kan , Moses Cenker , John T. Patton, Jr.
CPC分类号： C08G18/546 , C08G18/10 , C08G18/5033 , C08G2101/0025 , C08G2101/0041 , C08G2105/02 , C08G2105/06 , Y10S521/901 , Y10S521/902
摘要： Rigid cellular foam compositions characterized by carbodiimide, isocyanurate and urethane linkages are prepared by the reaction of an organic polyisocyanate with certain oxyalkylated Mannich polyols employing an NCO/OH equivalent ratio of from about 2:1 to 10:1. The use of the oxyalkylated Mannich polyols in the amounts stated eliminates the need for carbodiimide and isocyanurate promoting catalysts.
摘要翻译： 通过使用NCO / OH当量比为约2:1至10:1的有机多异氰酸酯与某些烷氧基化的曼尼期多元醇反应制备以碳二亚胺，异氰脲酸酯和氨基甲酸酯键为特征的刚性泡沫体组合物。 以所述量使用烷氧基化的曼尼希多元醇消除了碳二亚胺和异氰脲酸酯促进催化剂的需要。
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公开(公告)号：US4717774A
公开(公告)日：1988-01-05
申请号：US811480
申请日：1985-12-20
申请人： Thirumurti Narayan , Peter T. Kan
发明人： Thirumurti Narayan , Peter T. Kan
IPC分类号： C07C209/36 , C07C51/16
CPC分类号： C07C209/36
摘要： The invention relates to an improved process for the preparation of toluene diamine from dinitrotoluene involving hydrogenation of dinitrotoluene with hydrogen gas at elevated temperatures and super atmospheric pressure in the presence of a supported nickel catalyst and carbon monoxide ranging from 0.001 to 0.1 volume percent. The rate of hydrogenation, product quality and yield are improved when hydrogen spiked with small amounts of carbon monoxide was used.
摘要翻译： 本发明涉及一种从二硝基甲苯制备甲苯二胺的改进方法，包括在负载型镍催化剂和一氧化碳存在下，在高温和超常压下，用氢气氢化二硝基甲苯为0.001至0.1体积％。 当使用少量一氧化碳的氢气时，氢化速率，产品质量和产率都得到改善。
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8.发明授权Polyisocyanurate polymers, dispersions, and cellular and non-cellular polyurethane products prepared therefrom 失效聚异氰脲酸酯聚合物，分散体和由其制备的细胞和非细胞聚氨酯产品
公开(公告)号：US4359550A
公开(公告)日：1982-11-16
申请号：US225934
申请日：1981-01-19
CPC分类号： C08J9/0061 , C08G18/022 , C08G18/409 , C08G18/791 , C08L75/04 , C08J2375/04 , C08J2479/00 , Y10S521/902
摘要： Polyisocyanurate polymers are prepared by the polymerization of organic polyisocyanates in organic solvents employing trimerization catalysts. After deactivation of the catalysts and removal of the solvents, these polymers may be dispersed in polyols which are employed for the preparation of cellular and non-cellular polyurethane products displaying improved load bearing properties.
摘要翻译： 通过有机多异氰酸酯在使用三聚催化剂的有机溶剂中聚合来制备聚异氰脲酸酯聚合物。 在催化剂失活和除去溶剂之后，这些聚合物可以分散在多元醇中，所述多元醇用于制备显示改进的承载性能的细胞和非细胞聚氨酯产品。
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9.发明授权Alkylated vicinal toluenediamines and their use as chain extenders in the preparation of polyurethane-polyurea elastomers 失效烷基化邻位甲苯二胺及其在制备聚氨酯 - 聚脲弹性体中作为扩链剂的用途
公开(公告)号：US4529746A
公开(公告)日：1985-07-16
申请号：US569825
申请日：1984-01-11
CPC分类号： C08G18/324 , C08G18/6529
摘要： This invention relates to alkylated vicinal toluenediamines and their use as chain extenders in the preparation of polyurethane elastomers.
摘要翻译： 本发明涉及烷基化连位甲苯二胺及其在制备聚氨酯弹性体中作为扩链剂的用途。
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10.发明授权Polyurethanes produced from an adduct of an organic polyisocyanate and certain amines 失效由有机多异氰酸酯和某些胺的加合物生产的聚氨酯
公开(公告)号：US4384052A
公开(公告)日：1983-05-17
申请号：US271807
申请日：1981-06-08
CPC分类号： C08G18/8038 , Y10S521/904
摘要： Reaction products of an organic polyisocyanate with a reactive diamine such as bis(4-aminocyclohexyl)methane and isophorone diamine, prepared at a temperature of between 135.degree. C. and 200.degree. C., are used to prepare polyurethanes useful for comfort cushioning applications such as automotive seating, furniture, mattresses, and large automotive body panels.
摘要翻译： 使用有机多异氰酸酯与反应性二胺如双（4-氨基环己基）甲烷和异佛尔酮二胺的反应产物，其温度为135℃至200℃，制备用于舒适缓冲应用的聚氨酯， 作为汽车座椅，家具，床垫和大型汽车车身面板。
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