摘要:
A process capable of producing large metallic castings having lengths of one hundred centimeters or more and a unidirectional crystal structure substantially free of freckle defects. The process includes preheating a mold within a heating zone of a directional casting apparatus, pouring a molten metal alloy into a cavity of the mold, and then withdrawing the mold from the heating zone, through a heat shield, and into a cooling zone of the directional casting apparatus to directionally solidify the molten metal alloy within the cavity. The heating and cooling zones establish an axial thermal gradient that defines a solidification front in the molten metal alloy within the cavity. The mold is withdrawn at a withdrawal rate that, in combination with the axial thermal gradient, causes the solidification front to be substantially flat and perpendicular to the withdrawal direction.
摘要:
A process capable of producing large metallic castings having lengths of one hundred centimeters or more and a unidirectional crystal structure substantially free of freckle defects. The process includes pouring a molten metal alloy into a preheated mold within a heating zone, withdrawing the mold from the heating zone, through a heat shield, and into a cooling zone to directionally solidify the molten metal alloy, and then cooling the mold to produce the casting and the unidirectional crystal structure thereof. The heat shield operates as a barrier to thermal radiation between the heating zone and the cooling zone, and the mold is withdrawn at a rate that, in combination with the heat shield, maintains a thermal gradient to solidify the molten metal alloy and form primary dendrite arms having an average spacing therebetween of about 150 to about 500 micrometers.
摘要:
The invention is a class of nickel-base alloys for gas turbine applications, comprising, by weight, about 13.7 to about 14.3 percent chromium, about 5.0 to about 10.0 percent cobalt, about 3.5 to about 5.2 percent tungsten, about 2.8 to about 5.2 percent titanium, about 2.8 to about 4.6 percent aluminum, about 0.0 to about 3.5 percent tantalum, about 1.0 to about 1.7 percent molybdenum, about 0.08 to about 0.13 percent carbon, about 0.005 to about 0.02 percent boron, about 0.0 to about 1.5 percent niobium, about 0.0 to about 2.5 percent hafnium, about 0.0 to about 0.04 percent zirconium, and the balance substantially nickel. The nickel-base alloys may be provided in the form of useful articles of manufacture, and which possess a unique combination of mechanical properties, microstructural stability, resistance to localized pitting and hot corrosion in high temperature corrosive environments, and high yields during the initial forming process as well as post-forming manufacturing and repair processes.
摘要:
An apparatus and method for casting an alloy using a unidirectional casting technique. The apparatus includes a mold adapted to contain a molten quantity of an alloy, a primary heating zone adapted to heat the mold and the molten alloy therein to a temperature above the liquidus temperature of the alloy, a cooling zone adapted to cool the mold and molten alloy therein to a temperature below the solidus temperature of the alloy and thereby yield the unidirectionally-solidified casting, and an insulation zone between the primary heating zone and the cooling zone. The apparatus also has a secondary heating zone separated from the insulation zone by the primary heating zone. The secondary heating zone maintains the mold and the molten alloy therein at a temperature below the liquidus temperature of the alloy. The temperatures within the primary and secondary heating zones are individually set and controlled.
摘要:
An apparatus and method for casting an alloy using a unidirectional casting technique. The apparatus includes a mold adapted to contain a molten quantity of an alloy, a primary heating zone adapted to heat the mold and the molten alloy therein to a temperature above the liquidus temperature of the alloy, a cooling zone adapted to cool the mold and molten alloy therein to a temperature below the solidus temperature of the alloy and thereby yield the unidirectionally-solidified casting, and an insulation zone between the primary heating zone and the cooling zone. The apparatus also has a secondary heating zone separated from the insulation zone by the primary heating zone. The secondary heating zone maintains the mold and the molten alloy therein at a temperature below the liquidus temperature of the alloy. The temperatures within the primary and secondary heating zones are individually set and controlled.
摘要:
A cobalt-nickel base alloy is disclosed. The alloy includes, in weight percent: greater than about 4 % of Al, about 10 to about 20 % of W, about 10 to about 40 % Ni, about 5 to 20 % Cr and the balance Co and incidental impurities. The alloy has a microstructure that is substantially free of a CoAl phase having a B2 crystal structure and configured to form a continuous, adherent aluminum oxide layer on an alloy surface upon exposure to a high-temperature oxidizing environment. A method of making an article of the alloy includes: selecting the alloy; forming an article from the alloy; solution-treating the alloy; and aging the alloy to form an alloy microstructure that is substantially free of a CoAl phase having a B2 crystal structure, wherein the alloy is configured to form a continuous, adherent aluminum oxide layer on an alloy surface upon exposure to a high-temperature oxidizing environment.
摘要:
A process is provided for forming shaped air holes, such as for use in turbine blades. Aspects of the disclosure relate to forming shaped portions of air holes using a short pulse laser, forming a metered hole corresponding to each shaped portion, and separately finishing the shaped portion using a short-pulse laser. In other embodiments, the order of these operations may be varied, such as to form the shaped portions and to finish the shaped portions using the short-pulse laser prior to forming the corresponding metered holes.
摘要:
A precipitation-hardened stainless steel alloy comprises, by weight: about 14.0 to about 16.0 percent chromium; about 6.0 to about 8.0 percent nickel; about 1.25 to about 1.75 percent copper; greater than about 1.5 to about 2.0 percent molybdenum; about 0.001 to about 0.025 percent carbon; niobium in an amount greater than about twenty times that of carbon; and the balance iron and incidental impurities. The alloy has an aged microstructure and an ultimate tensile strength of at least about 1100 MPa and a Charpy V-notch toughness of at least about 69 J. In one embodiment, the aged microstructure includes martensite and not more than about 10% reverted austenite. In another embodiment, the alloy includes substantially all martensite and substantially no reverted austenite. The alloy is useful for making turbine airfoils.
摘要:
A precipitation-hardened stainless steel alloy comprises, by weight: about 14.0 to about 16.0 percent chromium; about 6.0 to about 7.0 percent nickel; about 1.25 to about 1.75 percent copper; about 0.5 to about 2.0 percent molybdenum; about 0.025 to about 0.05 percent carbon; niobium in an amount greater than about twenty times to about twenty-five times that of carbon; and the balance iron and incidental impurities. The alloy has an aged microstructure and an ultimate tensile strength of at least about 1100 MPa and a Charpy V-notch toughness of at least about 69 J. The aged microstructure includes martensite and not more than about 10% reverted austenite and is useful for making turbine airfoils.
摘要:
A corrosion inhibitor composition for a fuel, comprising a plurality of nanoparticles formed of an inorganic composition having an average longest dimension of 1 nanometer to 100 nanometers, wherein the inorganic active composition is insoluble in the fuel and is adapted to react with a corrosion causing contaminant.