摘要:
Process for the treatment by chemical conversion, within very short spaces of time of substrates of zinc or of one of its alloys especially of continuously zinc coated steel coils, wherein the bath employed in the phosphatization step proper comprises, besides the conventional constituents, a proportion of 0.3 to 2 g/l of Fe.sup.2+ ions, this bath comprising also from 0.2 to 1.5 g/l, preferably from 0.2 to 1.2 gl/ of Zn.sup.2+ ions and from 0.3 to 2 g/l, preferably from 0.3 to 1.2 g/l of Ni.sup.2+ ions, the weight ratiosZn/Ni and Zn Febeing comprised between 0.1 and 5, these ratios being preferably comprised respectively between 0.4 and 2 and between 0.25 and 4.
摘要:
Chemical conversion bath with zinc characterized by the fact that it comprises, besides the conventional constituents, an effective amount of fluorophosphate ion of the formula:F--PO.sub.3.sup.2-which can be introduced in the form of the corresponding acid, one of its alkali, alkaline-earth or ammonium salts or its zinc salt.
摘要:
Method of zinc phosphatization of substrates essentially based on iron, zinc or their alloys, comprising successively:(1) one or several alkaline degreasing steps,(2) one or several rinsing steps with running city water,(3) an activating and refining step,(4) the zinc phosphatization step proper,(5) one or several rinsing steps with water,(6) preferably, a passivating final rinsing step, particularly by means of salts of hexavalent chromium or mixtures of hexavalent chromium and trivalent chromiumcharacterized by the fact that, to carry out the activating and refining step, recourse is had to a bath comprising, besides the conventional constituents among which are particularly at least one Jernstedt salt in a proportion corresponding to about 1 to 100 ppm of titanium, a proportion of 10 to 700 ppm, preferably from 50 to 200 ppm, of at least one alkane-phosphonic acid of formula ##STR1## or at least one of the alkali or ammonium salts corresponding to the abovesaid alkane-phosphonic acids, the pH of the bath being from 7 to 9.5, preferably from 7.5 to 9.
摘要:
The invention relates to a process of phosphating surfaces of iron and of steel with manganese.The abovesaid process is characterized by the fact on the one hand, that it does not include a refining treatment preceding the proper phosphating, and on the other hand, that the alkali degreasing bath has a pH of 9 to 12 and includes in suspension bivalent manganese in orthophosphate form.
摘要:
The invention relates to a composition and a process for the treatment, more precisely the "post-treatment" of phosphatized metal surfaces, particularly when the surfaces must be subsequently covered with a coat of paint. It relates also to a process for the preparation of the composition and a concentrate useful for this preparation. The composition comprises an effective proportion of trivalent titanium compound and it is presented with an acid pH, the proportion of said compound being sufficient for the corresponding composition to confer on the treated metal surface a protection equivalent to that obtained with known chromatizing solutions. More particularly, the composition contains trivalent titanium at a concentration of 0.01 to 2 g/l, preferably from 0.2 to 0.6 g/l and has a pH of 2 to 7. Reducing means can be arranged to regenerate the trivalent titanium in the treatment solution continuously.
摘要:
The invention concerns the use of a composition or premix based on volatile corrosion inhibitors comprising, in order to limit to a maximum the release and/or degradation of the volatile corrosion inhibitors when the composition or premix is being formed, either an efficient amount of a structuring agent consisting of at least one solid or pasty substance whereof the melting point ranges from 40 to 110° C. preferably from 50 to 90° C., or a liquid substance capable of forming, mixed with a mineral filler, a solid or pasty combination. The invention also concerns a composition based on volatile corrosion inhibitors comprising a composition based on volatile corrosion inhibitors comprising an efficient amount which contains an efficient amount of a solid structuring agent. The invention further concerns polymer based articles having as constituent said composition or premix; said article are useful for protecting metal parts against corrosion.
摘要:
Stable aqueous or aqueous alcoholic dispersion, or aqueous flow, based on at least one oxynil derivative, wherein the oxynil derivative is an ester of melting point higher than 65.degree. C. and herbicidal composition comprising the said dispersion.
摘要:
Preparation process for 3,4-disubstituted dinitroanilines of formula ##STR1## in which, R.sub.1 and R.sub.2, which are identical to or different from one another, represent a hydrogen atom, a C.sub.1 to C.sub.6 saturated, linear or branched alkyl radical, a C.sub.2 to C.sub.6 linear or branched alkylene radical, a cyclopropyl radical or a chloroethyl radical,R.sub.3 and R.sub.4, which are identical to or different from one another are chosen from the group containing the chlorine atom, the amino group, the C.sub.1 to C.sub.3 lower alkyl radicals and the trifluoromethyl radical,comprising successively a dinitration stage of a 3,4-disubstituted phenol, an alkylation stage of the dinitrated derivative thus obtained and an amination stage of the 3,4-disubstituted 2,6-dinitro-alkoxybenzene thus obtained.
摘要:
Preparation process for 4-substituted dinitroanilines of formula ##STR1## in which R.sub.1 is chosen from the group containing the tert-butyl, sulphonamido, trifluoromethyl, methyl-sulphonyl and isopropyl radicals,R.sub.2 and R.sub.3, which are identical to or different from one another, represent a hydrogen atom, a linear or branched alkyl, cycloalkyl, haloalkyl or alkenyl radical containing less than 6 carbon atoms, characterized in that that it comprises successively:a dinitration stage of the 4-substituted phenol corresponding to the sought 4-substituted dinitro-aniline, this dinitration stage being carried out in a reaction medium containing a slight excess of nitrating agent, a sufficient quantity of protons and a catalyst chosen from the group containing the soluble salts of the transition metals of columns IV to XII of the Periodic Table, preferably the soluble salts of Fe.sub.III, Fe.sub.II, Zn.sub.II and Cu.sub.II ions,an O-alkylation stage of the dinitrated 4-substituted phenol obtained in the preceding stage, by means of an alkylating agent, andan amination stage of the 4-substituted dinitrated phenoxy-ether obtained in the preceding stage by using a primary or secondary amine.
摘要:
A phytosanitary composition, characterized in that it contains a combination of an oxynil and at least one substance selected from the group consisting of herbicides, insecticides, fungicides, growth regulators and/or pesticides, this substance which is liquid at ambient temperature being intended to keep the oxynil in the liquid state at the application site, if necessary after it has been brought into the liquid state.