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公开(公告)号：US5637777A
公开(公告)日：1997-06-10
申请号：US302837
申请日：1994-09-16
申请人： Juhani Aittamaa , Isto Eilos , Juha Jakkula , Petri Lindqvist
发明人： Juhani Aittamaa , Isto Eilos , Juha Jakkula , Petri Lindqvist
CPC分类号： C07C41/42 , B01D3/009 , C07C41/06 , Y02P20/127 , Y10S203/06 , Y10S203/17 , Y10S203/20
摘要： The invention concerns a process and an apparatus for preparing tertiary ethers. According to the process, C.sub.4 to C.sub.6 isoolefins and possibly heavier olefins contained in the feedstock are reacted with lower aliphatic alcohols, in particular methanol or ethanol, in a catalytic distillation reactor system in order to produce the corresponding ethers. According to the invention, the reaction between the isoolefins and the alcohols is essentially carried out in at least one reactor (5-7) of the kind, which is combined with a distillation column (3) intended for product separation, by conducting at least a part of the liquid flow of the column through the reactor and returning it to a lower tray than the one from which it was taken. At least half of cation exchange resin is placed in the side reactor (5-7). In the process according to the invention, the catalyst can be rapidly changed without stopping the process. In order to improve conversion additional alcohol can be fed to at least one of the side reactors.
摘要翻译： PCT No.PCT / FI93 / 00097 Sec。 371日期1994年9月16日 102（e）日期1994年9月16日PCT 1993年3月18日PCT公布。 公开号WO93 / 19031 日期1993年9月30日本发明涉及一种制备叔醚的方法和装置。 根据该方法，原料中所含的C4至C6异烯烃和可能较重的烯烃在催化蒸馏反应器系统中与低级脂族醇，特别是甲醇或乙醇反应，以产生相应的醚。 根据本发明，异烯烃和醇之间的反应基本上在至少一个与用于产物分离的蒸馏塔（3）组合的反应器（5-7）中进行，至少通过至少 柱的液体流的一部分通过反应器并将其返回到比从其取出的塔的下部托盘。 将至少一半的阳离子交换树脂置于侧反应器（5-7）中。 在根据本发明的方法中，可以快速改变催化剂而不停止该方法。 为了改善转化率，另外的醇可以进料至至少一个侧反应器。
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公开(公告)号：US06613108B1
公开(公告)日：2003-09-02
申请号：US09343559
申请日：1999-06-30
申请人： Juhani Aittamaa , Juha Jakkula , Petri Lindqvist , Matti Koskinen , Juha Linnekoski , Outi Krause , Mauri Sourander , Jyrki Ignatius , Antti Pyhälahti
发明人： Juhani Aittamaa , Juha Jakkula , Petri Lindqvist , Matti Koskinen , Juha Linnekoski , Outi Krause , Mauri Sourander , Jyrki Ignatius , Antti Pyhälahti
IPC分类号： C10L118
摘要： The invention relates to process for dimerizing olefinic hydrocarbon feedstock, to hydrocarbon compositions and to fuel components produced by the process. According to the invention, fresh olefinic hydrocarbon feedstock is fed to a reaction zone of a system including at least one reaction zone and at least one distillation zone. The olefinic hydrocarbon feedstock is contacted with an acidic catalyst in the presence of an oxygenate at conditions in which at least a part of the olefins dimerizes. The effluent from the reaction zone is conducted to the distillation zone where dimerized reaction product is separated from effluent, and at least one flow comprising oxygenate is withdrawn from the side of at least one distillation column. The flow is circulated from distillation zone back to dimerization. The reaction mixture is recovered and optionally hydrogenated to form a parafinic reaction product.
摘要翻译： 本发明涉及二烯烃烯烃原料，烃类组合物和通过该方法生产的燃料组分的方法。 根据本发明，将新鲜的烯烃原料进料至包含至少一个反应区和至少一个蒸馏区的体系的反应区。 在至少部分烯烃二聚的条件下，烯烃原料在含氧化合物的存在下与酸性催化剂接触。 将来自反应区的流出物进入蒸馏区，其中二聚反应产物与流出物分离，并且至少一个包含含氧化合物的流从至少一个蒸馏塔的一侧排出。 流量从蒸馏区循环回二聚。 将反应混合物回收并任选地氢化以形成路旁反应产物。
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公开(公告)号：US5908964A
公开(公告)日：1999-06-01
申请号：US803177
申请日：1997-02-19
摘要： The invention concerns a process for preparing a tertiary alkyl ether product. The process comprises reacting the isoolefins of an olefinic hydrocarbon feedstock in a reaction zone (1-3) with an alkanol to form a reaction mixture, which is subjected to distillation in a first distillation zone (4). The bottoms product of the first distillation contains the ether(s), whereas the overhead stream contains unreacted alkanol and a mixture of light hydrocarbons. The overhead stream is subjected to a second distillation in a second distillation zone (15). The overhead product of the second distillation mainly contains the lightest hydrocarbons and a small amount of alkanol, and the bottoms product contains an essentially oxygenate-free hydrocarbon stream which can be used as such for alkylation. In order to increase the conversion of the process, a side drawoff is withdrawn from the second distillation zone (15) and recirculated to the reaction zone (1-3).
摘要翻译： 本发明涉及一种制备叔烷基醚产物的方法。 该方法包括使反应区（1-3）中的烯烃原料的异烯烃与烷醇反应以形成反应混合物，其在第一蒸馏区（4）中进行蒸馏。 第一次蒸馏的塔底产物含有醚，而顶部物流含有未反应的链烷醇和轻烃的混合物。 塔顶流在第二蒸馏区（15）中进行第二次蒸馏。 第二次蒸馏的塔顶产物主要含有最轻的烃和少量的链烷醇，底部产物含有基本上不含氧的烃流，可用于烷基化。 为了增加该方法的转化率，从第二蒸馏区（15）取出侧抽出物并再循环至反应区（1-3）。
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4.发明授权
公开(公告)号：US5689013A
公开(公告)日：1997-11-18
申请号：US527319
申请日：1995-09-12
申请人： Harri Jarvelin , Petri Lindqvist , Juha Jakkula
发明人： Harri Jarvelin , Petri Lindqvist , Juha Jakkula
CPC分类号： C07C41/42 , B01D3/009 , C07C41/06 , Y02P20/127
摘要： The present invention concerns a process for preparing tertiary alkyl ethers. The process comprises the steps of contacting in the presence of a catalyst a feedstock containing saturated hydrocarbons and dienes having 4 to 7 carbon atoms with an excess of hydrogen in relation to the amount of dienes in the feed in order selectively to hydrogenate at least a part of the dienes, feeding the treated hydrocarbon feedstock together with at least a part of the unreacted hydrogen to a catalytic distillation reactor system which includes at least one distillation column, reacting the C.sub.4-7 isoolefines of the feedstock with methanol or ethanol in the presence of a catalyst to form tertiary alkyl ethers, subjecting the reaction mixture to distillation in the distillation column, recovering the alkyl ethers and substantially all of the unreacted hydrocarbons with the bottoms product of the distillation, withdrawing an overhead product of the distillation, which mainly contains an azeotrope of saturated C.sub.4 hydrocarbons and the alkanol, and maintaining the pressure of the distillation column at least essentially constant by adjusting the amount of gaseous distillate containing hydrogen in the column. The selective hydrogenation operation of the present invention reduces the amount of dienes contained in the feed to below 0.5% and also causes isomerization of olefins to increase the amounts of reactive olefins.
摘要翻译： 本发明涉及一种制备叔烷基醚的方法。 该方法包括以下步骤：在催化剂存在下使含有饱和烃和具有4至7个碳原子的二烯的原料与过量的氢相对于进料中的二烯的量相接触，以选择性地氢化至少一部分 将经处理的烃原料与至少一部分未反应的氢一起进料至包含至少一个蒸馏塔的催化蒸馏反应器系统中，使原料的C4-7异烯烃与甲醇或乙醇在存在下反应， 用于形成叔烷基醚的催化剂，使反应混合物在蒸馏塔中进行蒸馏，用蒸馏塔底产物回收烷基醚和基本上所有未反应的烃，取出主要含有 饱和C4烃和链烷醇的共沸物，并保持dis的压力 通过调节柱中含有氢的气态馏出物的量，蒸馏塔至少基本上恒定。 本发明的选择性氢化操作将进料中所含的二烯烃的量减少到低于0.5％，并且还引起烯烃的异构化以增加反应性烯烃的量。
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公开(公告)号：US20120209017A1
公开(公告)日：2012-08-16
申请号：US13397236
申请日：2012-02-15
申请人： Tuomas Ouni , Väinö Sippola , Petri Lindqvist
发明人： Tuomas Ouni , Väinö Sippola , Petri Lindqvist
CPC分类号： C10G3/50 , A23D9/007 , C07C1/207 , C07C5/27 , C07C69/604 , C07C69/66 , C10G3/46 , C10G45/58 , C10G2300/1014 , C10G2300/1018 , C10G2300/205 , C10G2400/02 , C10G2400/04 , C10G2400/08 , C10G2400/10 , C10G2400/18 , C10G2400/28 , C11C3/126 , Y02P30/20
摘要： The use of bio oil from at least one renewable source in a hydrotreatment process, in which process hydrocarbons are formed from said glyceride oil in a catalytic reaction, and the iron content of said bio oil is less than 1 w-ppm calculated as elemental iron. A bio oil intermediate including bio oil from at least one renewable source and the iron content of said bio oil is less than 1 w-ppm calculated as elemental iron.
摘要翻译： 在加氢处理方法中使用来自至少一种可再生来源的生物油，其中在催化反应中由所述甘油酯油形成烃，并且所述生物油的铁含量小于作为元素铁计算的1W- ppm 。 包括来自至少一种可再生源的生物油和所述生物油的铁含量的生物油中间体小于作为元素铁计算的1W- ppm。
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公开(公告)号：US20080203034A1
公开(公告)日：2008-08-28
申请号：US11883947
申请日：2006-03-15
IPC分类号： C02F1/76
CPC分类号： C02F1/72 , C02F1/50 , C02F1/766 , C02F2103/023 , C02F2103/28 , C02F2303/04 , D21H21/04
摘要： The invention relates to a method of inhibiting the growth of microorganisms in fresh or circulating water by adding to the water, separately and essentially continuously, (1) an oxidant and (2) a bromine source.
摘要翻译： 本发明涉及通过向水中分别地和基本上连续地加入（1）氧化剂和（2）溴源来抑制新鲜或循环水中的微生物生长的方法。
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公开(公告)号：US5852220A
公开(公告)日：1998-12-22
申请号：US771417
申请日：1996-12-20
申请人： Harri Jarvelin , Petri Lindqvist , Esa Tamminen
发明人： Harri Jarvelin , Petri Lindqvist , Esa Tamminen
CPC分类号： C07C41/06
摘要： A process for producing tertiary alkyl ethers by reacting an olefinic hydrocarbon feedstock, which contains a mixture of reactive C.sub.4 -C.sub.7 isoolefins, with an alkanol in the presence of a catalyst that will enhance the reaction between the isoolefins and the alkanol. By adjusting the weight ratio of the isobutylene to the reactive C.sub.6 isoolefins of the feed to a value of about 0.2 to 10, it is possible to increase the conversion of reactive C.sub.4 's to over 95%, of reactive C.sub.5 's to over 85% and of reactive C.sub.6 's to over 57%.
摘要翻译： 在催化剂存在下，使含有活性C4-C7异烯烃的混合物的烯烃原料与烷醇反应生成叔烷基醚的方法，该催化剂将增强异烯烃和链烷醇之间的反应。 通过将异丁烯与进料的活性C 6异烯烃的重量比调节至约0.2至10的值，可以将反应性C4的转化率增加至超过95％，反应性C5的转化率超过85％，反应性 C6超过57％。
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公开(公告)号：US20060065574A1
公开(公告)日：2006-03-30
申请号：US10953293
申请日：2004-09-28
申请人： Matti Koskinen , Petri Lindqvist , Harri Jarvelin
发明人： Matti Koskinen , Petri Lindqvist , Harri Jarvelin
IPC分类号： C10G65/02
CPC分类号： C10G50/00 , C07C41/06 , C07C43/046
摘要： A process for producing alkyl ethers, by etherification of tertiary C4-7 olefins with an alkanol, comprising carrying out the etherification in reactor train system primarily configured for dimerization of isoolefins. In the etherification, the ratio of alkanol-to-olefin is 0.5 to 2, calculated from the amount of tertiary C4-7 olefins of the fresh feedstock. The invention makes it possible to change the product of the process from dimer to ether and vice versa merely by adjusting specific flows within the process. The present kind of process is therefore readily adaptable to fluctuating market demands for various gasoline octane-boosters (isooctane or MTBE).
摘要翻译： 通过叔烷基4-7-烯烃与烷醇醚化制备烷基醚的方法，包括在反应器系统中进行醚化，主要用于异烯烃的二聚。 在醚化中，由新鲜原料的叔C 4-7.7烯烃的量计算，链烷醇与烯烃的比例为0.5至2。 本发明使得可以通过调节该过程中的特定流量将过程的产物从二聚体改变为醚，反之亦然。 因此，目前的这种方法很容易适应各种汽油辛烷值增量剂（异辛烷或MTBE）对市场需求的波动。
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公开(公告)号：US07344632B2
公开(公告)日：2008-03-18
申请号：US10953293
申请日：2004-09-28
申请人： Matti Koskinen , Petri Lindqvist , Harri Jarvelin
发明人： Matti Koskinen , Petri Lindqvist , Harri Jarvelin
CPC分类号： C10G50/00 , C07C41/06 , C07C43/046
摘要： A process for producing alkyl ethers, by etherification of tertiary C4-7 olefins with an alkanol, comprising carrying out the etherification in reactor train system primarily configured for dimerization of isoolefins. In the etherification, the ratio of alkanol-to-olefin is 0.5 to 2, calculated from the amount of tertiary C4-7 olefins of the fresh feedstock. The invention makes it possible to change the product of the process from dimer to ether and vice versa merely by adjusting specific flows within the process. The present kind of process is therefore readily adaptable to fluctuating market demands for various gasoline octane-boosters (isooctane or MTBE).
摘要翻译： 通过叔烷基4-7-烯烃与烷醇醚化制备烷基醚的方法，包括在反应器系统中进行醚化，主要用于异烯烃的二聚。 在醚化中，由新鲜原料的叔C 4-7.7烯烃的量计算，链烷醇与烯烃的比例为0.5至2。 本发明使得可以通过调节该过程中的特定流量将过程的产物从二聚体改变为醚，反之亦然。 因此，目前的这种方法很容易适应各种汽油辛烷值增量剂（异辛烷或MTBE）对市场需求的波动。
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公开(公告)号：US09005429B2
公开(公告)日：2015-04-14
申请号：US12495263
申请日：2009-06-30
申请人： Varpu Markkanen , Petri Lindqvist , Elina Harlin , Pekka Aalto , Jukka Myllyoja , Ville Alopaeus
发明人： Varpu Markkanen , Petri Lindqvist , Elina Harlin , Pekka Aalto , Jukka Myllyoja , Ville Alopaeus
CPC分类号： C10G65/043 , C10G3/46 , C10G3/50 , C10G45/64 , C10G2300/1014 , C10G2300/1018 , C10G2300/1055 , C10G2300/4081 , C10G2400/02 , C10G2400/04 , C10G2400/08 , Y02P30/20
摘要： The present invention relates to hydrocarbons and particularly to the manufacture of hydrocarbon components suitable as aviation fuels or jet fuels and as blending stocks for aviation fuels. The process comprises the stages, wherein in the first stage an oil feed of biological origin and hydrogen gas are subjected to conditions sufficient to effect hydrodeoxygenation in the presence of a hydrodeoxygenation catalyst to yield n-paraffins; in the second stage the n-paraffins and hydrogen gas are subjected to conditions sufficient to effect isomerization in the presence of an isomerization catalyst to yield isoparaffins and separating fractions; and recycling the fraction boiling at a temperature above 200° C. under atmospheric pressure obtained from the second stage to reisomerization, where isomerization is effected in the presence of an isomerization catalyst.
摘要翻译： 本发明涉及碳氢化合物，特别涉及适用于航空燃料或喷气燃料的烃类组分的制造以及用于航空燃料的混合原料。 该方法包括以下阶段，其中在第一阶段中，在加氢脱氧催化剂存在下，生物来源和氢气的进料经受足以进行加氢脱氧的条件以产生正链烷烃; 在第二阶段中，正链烷烃和氢气在异构化催化剂存在下进行足以实现异构化的条件，得到异链烷烃和分离馏分; 并将在第二阶段获得的大气压下在高于200℃的温度下沸腾的馏分再循环进行再异构化，其中异构化在异构化催化剂存在下进行。
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