摘要:
This invention provides an anode for a fuel cell which can realize stable output for a long period of time, and a fuel cell using the anode for a fuel cell. The anode for a fuel cell comprises an electrode catalyst layer, the electrode catalyst layer comprising a supported catalyst comprising an electroconductive carrier material and catalyst fine particles supported on the electroconductive carrier material, a proton conductive inorganic oxide, and a proton conductive organic polymer binder, the weight ratio between the supported catalyst (C) and the proton conductive inorganic oxide (SA), WSA/WC, being 0.06 to 0.38, the weight ratio between the proton conductive inorganic oxide (SA) and the proton conductive organic polymer binder (P), WP/WSA, being 0.125 to 0.5.
摘要:
A catalyst is provided and includes fine catalyst particles of a composition represented by formula (1): PtuRuxTayTz, in which T is at least one element selected from the group consisting of Hf, W, Ni, and V; u, x, y, and z are 10 to 98.9 atm %, 0.1 to 50 atm %, 0.5 to 35 atm %, and 0.5 to 35 atm %, respectively, or formula (2): PtuRuxTayTz, in which T is at least one element selected from the group consisting of Ct, Mo, Nb, Zr, and T; u, x, y, and z are 40 to 70 atm %, 0.1 to 50 atm %, 0.5 to 15 atm %, and 0.5 to 15 atm %, respectively.
摘要:
A method for producing a catalyst-layer-supporting substrate includes a lamination step of forming a laminate of metal catalyst layers and mixture layers on a substrate by repeating a first step and a second step plural times alternatively; and an acid treatment step of subjecting the laminate to an acid treatment, wherein the first step is a step of sputtering or depositing the metal catalyst layer that comprises a catalyst, and the second step is a step of sputtering or depositing the mixture layer of carbon and metal, the metal of the mixture layer including at least one element M selected from the group consisting of Sn, Al, Cu and Zn.
摘要:
Catalysts contain noble metal-containing particles that has a composition except oxygen represented by a formula PtXRuYAZSnS and exhibits a mean particle diameter of from 0.5 nm to 10 nm, both inclusively. A is at least one element selected from a group consisting of Rh, Au, Pd, Ir and Os, and X, Y, Z and S are atomic ratios satisfying relations 30≦X ≦70, 30≦Y≦70, 0≦Z≦40, 0.5≦S≦8 and X+Y+Z+S=100.
摘要翻译:催化剂含有含有由式PtXRuYAZSnS表示的氧以外的组成的含贵金属的颗粒,其平均粒径均包含0.5nm至10nm。 A是选自Rh,Au,Pd,Ir和Os中的至少一种元素,X,Y,Z和S是满足关系式30 <= X <=70,30≤Y≤70的原子比 ,0 <= Z <= 40,0.5 <= S <= 8,X + Y + Z + S = 100。
摘要:
There is provided a catalyst for a fuel cell, which simultaneously realizes excellent catalytic activity and catalytic stability. The catalyst for a fuel cell comprises a fine particle of a metal represented by formula: PtxRuySizT1u wherein T1 represents at least one element selected from the group consisting of nickel (Ni), tungsten (W), vanadium (V), and molybdenum (Mo); x=30 to 90 atomic %; y=0 to 50 atomic %; z=0.5 to 20 atomic %; and u=0.5 to 40 atomic %, or comprises a fine particle of a metal represented by formula: PtxRuySizT2u wherein T2 represents at least one element selected from the group consisting of hafnium (Hf), tin (Sn), zirconium (Zr), niobium (Nb), titanium (Ti), tantalum (Ta), chromium (Cr), and aluminum (Al); x=30 to 90 atomic %; y=0 to 50 atomic %; z=0.5 to 20 atomic %; and u=0.5 to 40 atomic %.
摘要翻译:提供了一种用于燃料电池的催化剂,其同时实现优异的催化活性和催化稳定性。 用于燃料电池的催化剂包括由式PtxRuySizT1u表示的金属微粒,其中T1表示选自镍(Ni),钨(W),钒(V)和钼(Mo)中的至少一种元素 ); x = 30〜90原子% y = 0〜50原子% z = 0.5〜20原子% 并且u = 0.5〜40原子%,或者包含由式PtxRuySizT2u表示的金属微粒,其中,T2表示选自铪(Hf),锡(Sn),锆(Zr), 铌(Nb),钛(Ti),钽(Ta),铬(Cr)和铝(Al); x = 30〜90原子% y = 0〜50原子% z = 0.5〜20原子% u = 0.5〜40原子%。
摘要:
A catalyst is provided and includes fine catalyst particles of a composition represented by formula (1): PtuRuxTayTz, in which T is at least one element selected from the group consisting of Hf, W, Ni, and V; u, x, y, and z are 10 to 98.9 atm %, 0.1 to 50 atm %, 0.5 to 35 atm %, and 0.5 to 35 atm %, respectively, or formula (2): PtuRuxTayTz, in which T is at least one element selected from the group consisting of Ct, Mo, Nb, Zr, and T; u, x, y, and z are 40 to 70 atm %, 0.1 to 50 atm %, 0.5 to 15 atm %, and 0.5 to 15 atm %, respectively
摘要:
Disclosed is a catalyst, including a catalyst particle containing at least one component selected from the group consisting of gold, platinum and an gold alloy, the gold alloy containing gold and at least one element selected from transition metal elements of the fourth period, fifth period and sixth period of the Periodic Table, and a catalyst carrier carrying the catalyst particle and containing a perovskite type oxide represented by general formula (1) given below: A(1-x)BxTiOy (1) where the element A is at least one element selected from the group consisting of Ca, Sr and Ba, the element B is at least one element selected from the group consisting of La, Nd, Sm, Eu, Gd, Dy, Ho, Er, Tm, Yb, and Lu, the molar ratio x satisfies 0
摘要:
A methanol oxidation catalyst comprises a material of composition: PtxMzTau in which Pt is platinum, Ta is tantalum, M is an element includes at least one selected from the group consisting of V (vanadium), W (tungsten), Ni (nickel) and Mo (molybdenum), x is 40 to 98 at. %, z is 1.5 to 55 at. %, and u is 0.5 to 40 at. %. To maximize catalytic activity the material is preferably in the form of nanoparticles. The values of x, z and u are selected such that the element exhibits X-ray photoelectron spectroscopy peaks derived from an oxygen bond and a metal bond in which a peak area derived from the oxygen bond is twice or less of a peak area derived from the metal bond.
摘要:
A methanol oxidation catalyst is provided, which includes nanoparticles having a composition represented by the following formula 1: PtxRuyTzQu formula 1 In the formula 1, the T-element is at least one selected from a group consisting of Mo, W and V and the Q-element is at least one selected from a group consisting of Nb, Cr, Zr and Ti, x is 40 to 90 at. %, y is 0 to 9.9 at. %, z is 3 to 70 at. % and u is 0.5 to 40 at. %. The area of the peak derived from oxygen bond of T-element is 80% or less of the area of the peak derived from metal bond of T-element in a spectrum measured by an X-ray photoelectron spectral method.
摘要:
This invention provides a process for producing a membrane electrode assembly which has high and stable catalytic activity, and suppressed deterioration in catalytic activity during operation, and can prevent a deterioration in performance attributable to a structural factor of the membrane electrode assembly. The process comprises the step of, after the washing/removing step, drying the catalyst electrode in an atmosphere having a lower oxygen partial pressure than the air. The anode/cathode is a covered catalyst electrode having a structure formed by supporting/depositing a catalytically active material composed mainly of platinum/ruthenium subjected to the potential holding step, the washing/removing step, and the drying step, on a porous electroconductive carrier to cover at least a part of the porous electroconductive carrier with the ion conductive material.