摘要:
A novel light-sensitive heat-sensitive composition is disclosed, comprising a photohardenable composition, a dye which discolors upon reacting with a base, and a base precursor. A novel light-sensitive heat-sensitive recording material is also disclosed, comprising a support having provided thereon the above described light-sensitive heat-sensitive composition. In a preferred embodiment, the dye is a spectral sensitizing dye for the photohardenable composition. Furthermore, a novel image formation process is disclosed, comprising the steps of: (a) imagewise exposing the light-sensitive heat-sensitive recording material to light to cure the exposed portions of the recording material; and (b) uniformly heating the imagewise exposed recording material to discolor the dye in the unexposed portions thereof. A second image formation process is disclosed, comprising the steps of: (a) imagewise heating the light-sensitive heat-sensitive recording material to discolor the dye in the heated portions of the recording material; and (b) uniformly exposing the imagewise heated recording material to light to cure the unheated portions thereof.
摘要:
A positive-working light-sensitive composition comprises a diazonium salt represented by the following general formula (I) and an alkali-soluble polymer: ##STR1## wherein R.sup.1 represents a substituted or unsubstituted alkyl group having 3 to 18 carbon atoms; R.sup.2 represents a hydrogen atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted aryl group, a substituted or unsubstituted alkoxy group, a substituted or unsubstituted phenoxy group or a halogen atom; A represents an organic group; X.sup.-- represents a counterion or an anion; n is an integer ranging from 1 to 4 and m is an integer ranging from 1 to 3, provided that the sum of n and m is equal to 4. The positive-working light-sensitive composition has high sensitivity and can ensure the formation of clear images.
摘要翻译:正性工作感光性组合物包含由以下通式(I)表示的重氮盐和碱溶性聚合物:其中R 1表示取代或未取代的碳原子数为3〜18的烷基; R 2表示氢原子,取代或未取代的烷基,取代或未取代的芳基,取代或未取代的烷氧基,取代或未取代的苯氧基或卤素原子; A代表有机基团; X-表示抗衡离子或阴离子; n为1〜4的整数,m为1〜3的整数,n和m之和等于4.正性感光性组合物的灵敏度高,可以确保 清晰的图像。
摘要:
A novel diazo type recording material is provided comprising a recording layer containing at least one light-sensitive diazo compound incorporated in microcapsules and a coupling component which undergoes reaction with said diazo compound in a basic atmosphere to develop a color on a support, wherein said coupling component is a mixture of at least one compound represented by the following general formula [I] and at least one compound represented by the following general formula [II]: ##STR1## wherein A represents an alkylene group having from 1 to 22 carbon atoms containing an ether or thioether bond; B represents hydrogen atom, cyclohexyl group, morpholino group or piperidino group; and R.sub.1, R.sub.2, R.sub.3 and R.sub.4 each represent hydrogen atom, an alkyl group having from 1 to 5 carbon atoms, alkoxy group having from 1 to 5 carbon atoms or halogen atom.
摘要:
A light- and heat-sensitive recording material is disclosed which includes a support having thereon a recording layer containing a diazo compound, a coupling component, and an organic base compound, wherein the diazo compound is a 1-substituted amino-3-alkoxybenzene-4-diazonium salt and the coupling component is a compound prepared from any of cyclohexane-1,3-dione, 3-cyclohexenone, or 2-cyclohexenone. The light- and heat-sensitive recording material according to the present invention can develop an excellent magenta color hue and has excellent storage properties before recording use (shelf life).
摘要:
A heat-sensitive recording material comprising a support having provided thereon a heat-sensitive recording layer which comprises (a) a diazo compound, (b) a coupling component which forms a coloration by coupling with the diazo compound, and (c) a basic substance having a structural unit represented by Formula (I): ##STR1##
摘要:
A heat-sensitive recording material comprising a base and one or more heat-sensitive color-forming layers containing an electron donating colorless dye and an electron accepting organic compound is disclosed, wherein at least one of said color-forming layers contains a urea derivative having a least 7 carbon atoms or a urethane derivative having at least 8 carbon atoms.
摘要:
A heat-sensitive recording material and a recording method are disclosed, wherein the heat-sensitive recording material comprises a support having formed thereon plural heat-coloring elements each comprising a diazo compound and a coupling component capable of causing heat-coloring, the heat-coloring elements coloring in two or more different hues, and the coloring property in each heat-coloring element being capable of being stopped by the action of different radiations, and the recording method comprises first heat-coloring a heat-coloring element of the heat-sensitive recording material, stopping the heat-coloring property of the uncolored portions of the first heat-coloring element by radiation, and then heat-coloring another heat-coloring element; wherein the recording method comprises applying two or more heat-coloring procedures and one or more irradiations of radiation to form recorded images composed of two or more colors on the same sheet.
摘要:
A light- and heat-sensitive composition which contains a photo-hardenable composition and at least one dye, a light- and heat-sensitive recording material which contains a support having the composition provided on at least one side thereof, and an image-forming process using the recording material are disclosed.
摘要:
A print-out composition containing a leuco dye and a photooxidizing agent is described, said print-out composition containing at least one carbazomethane compound represented by formula (I) as the leuco dye ##STR1## wherein Y represents an amino group-substituted phenyl group represented by formula (Ia) ##STR2## or an indolyl group represented by formula (Ib) ##STR3## wherein X.sub.1 and X.sub.2 each represents a hydrogen atom, an unsubstituted alkyl group, or an alkyl group substituted by a halogen atom, a hydroxy group, a cyano group, or a lower alkoxy group, said alkyl group having up to 12 carbon atoms, a cycloalkyl group, a phenyl group, a benzyl group, or a phenyl or benzyl group substituted by a halogen atom, a lower alkyl group, or a lower alkoxy group, or said X.sub.1 and X.sub.2 together may form a 5-membered or 6-membered heterocyclic group together with the nitrogen atom bonded thereto; X.sub.3 represents a hydrogen atom, a halogen atom, a nitro group, a lower alkyl group, or a lower alkoxy group; R.sub.1 and Z.sub.1 each represents a hydrogen atom, an unsubstituted alkyl group or an alkyl group substituted by a halogen atom having up to 12 carbon atoms, a hydroxy group, a cyano group, or a lower alkoxy group, an alkenyl group having up to 12 carbon atoms, an acyl group having from 1 to 12 carbon atoms, a phenyl group, a benzyl group, or a phenyl or benzyl group substituted by a member selected from the group consisting of a halogen atom, a lower alkyl group, a lower alkoxy group, and a nitro group; Z.sub.2 represents a hydrogen atom, a lower alkyl group, or a phenyl group; and rings A, B, and D each may be further substituted by a cyano group, a nitro group, a halogen atom, a lower alkyl group, a lower alkoxy group, or a lower alkylcarbonyl group.
摘要:
Fluoran derivatives having an arylamino group at 2-position of the fluoran skeleton thereof and a halogen atom at 3-position of the flouran skeleton thereof, useful as a dye precursor in recording materials such as heat-sensitive, pressure-sensitive, energizable heat-sensitive, and light-sensitive recording sheets and the like.