公开(公告)号：US10208256B2

公开(公告)日：2019-02-19

申请号：US15542264

申请日：2015-11-27

Applicant: KOREA RESEARCH INSTITUTE OF CHEMICAL TECHNOLOGY

Inventor： Ki Won Jun ,  Yun Jo Lee ,  Geun Jae Kwak ,  Hae Gu Park ,  Yong Tae Kim ,  Seok Chang Kang

IPC: C10G2/00 ,  C10G69/04 ,  C07C1/04 ,  C07C1/12 ,  C10G45/68 ,  C10G11/05

Abstract: Disclosed is a method for directly synthesizing monocyclic aromatic compounds and long-chain olefin compounds from a carbon dioxide-rich synthetic gas and, specifically, a method for directly synthesizing monocyclic aromatic compounds and long-chain olefin compounds from a carbon dioxide-rich synthetic gas, the method comprising a step of preparing a C1-C15 short-chain hydrocarbon by Fischer-Tropsch (FT) synthesis and a step of preparing monocyclic aromatic compounds and long-chain olefin compounds by dehydrogenating the short-chain hydrocarbon products, and maximizing the yield of the short-chain hydrocarbon by using, as a synthetic gas to be used in FT synthesis, a carbon dioxide-rich synthetic gas in which the molar ratio of hydrogen, carbon monoxide and carbon dioxide is delimited to a specific range, and maximizing the yield of the monocyclic aromatic compounds or the long-chain olefin compounds by specifying the composition of a catalyst to be used in the dehydrogenation and the temperature and pressure condition.

公开(公告)号：US09259717B2

公开(公告)日：2016-02-16

申请号：US14383478

申请日：2013-03-07

Applicant: KOREA RESEARCH INSTITUTE OF CHEMICAL TECHNOLOGY

Inventor： Kyoung Su Ha ,  Geun Jae Kwak ,  Jae Hoon Jung ,  Joo Young Cheon ,  Min Hee Woo ,  Yun Jo Lee ,  Ki Won Jun

IPC: C07C1/04 ,  B01J23/96 ,  B01J38/10 ,  B01J38/04 ,  B01J23/94 ,  B01J23/89 ,  C22B11/02 ,  C22B23/02 ,  C22B61/00 ,  C10G2/00 ,  B01J23/889

CPC classification number: B01J23/96 ,  B01J23/8896 ,  B01J23/8913 ,  B01J23/94 ,  B01J38/04 ,  B01J38/10 ,  C07C1/0435 ,  C07C1/045 ,  C07C2529/068 ,  C10G2/333 ,  C10G2/334 ,  C10G2300/4037 ,  C22B11/02 ,  C22B23/02 ,  C22B61/00

Abstract: The present invention relates to: a catalyst activation method for Fischer-Tropsch synthesis; a catalyst regeneration method for Fischer-Tropsch synthesis; and a method for producing a liquid or solid hydrocarbon by using the Fischer-Tropsch synthesis reaction. The temperatures required for a metal carbide producing and activating reaction is markedly lower than existing catalyst activation temperatures, and the catalyst can be activated under conditions that are the same as Fischer-Tropsch synthesis reaction conditions, and thus there is no need for separate reduction equipment in the reactor, and a Fischer-Tropsch synthesis catalyst which has been used for a long time can be regenerated within the reactor without the catalyst being isolated or extracted from the reactor.

Abstract translation: 本发明涉及：费 - 托合成的催化剂活化方法; 费 - 托合成催化剂再生方法; 以及通过使用费 - 托合成反应来制造液体或固体烃的方法。 金属碳化物生成和活化反应所需的温度明显低于现有的催化剂活化温度，催化剂可以在与费 - 托合成反应条件相同的条件下活化，因此不需要单独的还原装置 在反应器中，长时间使用的费 - 托合成催化剂可以在反应器内再生，而不需要从反应器中分离或提取催化剂。

公开(公告)号：US10307735B2

公开(公告)日：2019-06-04

申请号：US15649222

申请日：2017-07-13

Applicant: Korea Research Institute of Chemical Technology

Inventor： Sung Tak Kim ,  Geun Jae Kwak ,  Ki Won Jun ,  Ahron Hwang ,  Seok Chang Kang

IPC: B01J29/06 ,  B01J23/10 ,  B01J35/00 ,  B01J35/10 ,  C10G11/05

Abstract: The present invention relates to an anti-coking catalyst having a physical property of reducing coke formation, which comprises a solid acid catalyst containing gadolinium (Gd) on the surface, a preparation method thereof, and a use thereof. The preparation method includes a first step of determining the amount of gadolinium (Gd) or a Gd-providing precursor to be used relative to the total weight of the solid acid catalyst, which reducing the coking of a specific solid acid catalyst below a specific level under a specific reaction condition; and a second step of preparing a Gd-containing solid acid catalyst using the amount determined in the first step. The catalyst according to the present invention is a catalyst in which an appropriate weight ratio of gadolinium is supported on the surface of a pure solid acid substance or solid acid substance on which a specific metal is supported. Therefore, the production of coke on the catalyst surface is inhibited while maintaining the activity of the solid acid catalyst in a hydrocarbon conversion reaction, and as a result, the catalyst of the present invention exhibits an effect of improving its lifespan.

公开(公告)号：US09815046B2

公开(公告)日：2017-11-14

申请号：US14392244

申请日：2014-11-26

Applicant: KOREA RESEARCH INSTITUTE OF CHEMICAL TECHNOLOGY

Inventor： Kyoung Su Ha ,  Geun Jae Kwak ,  Min Hee Woo ,  Yun Jo Lee ,  Ki Won Jun

IPC: B01J23/89 ,  C10G2/00 ,  C07C1/04 ,  B01J37/16 ,  B01J37/02 ,  B01J23/88 ,  B01J21/12 ,  B01J31/02 ,  B01J31/26

CPC classification number: B01J23/8913 ,  B01J21/12 ,  B01J23/88 ,  B01J23/8896 ,  B01J23/8906 ,  B01J31/02 ,  B01J31/26 ,  B01J33/00 ,  B01J37/0219 ,  B01J37/16 ,  B01J37/18 ,  B01J2231/625 ,  B01J2531/005 ,  C07C1/04 ,  C07C1/0425 ,  C07C1/0435 ,  C07C1/0445 ,  C07C1/045 ,  C10G2/333 ,  C10G2400/20 ,  C10G2400/22 ,  Y02P30/40

Abstract: The present invention relates to a method for producing the activated catalyst for Fischer-Tropsch synthesis comprising: a first step of reducing a catalyst for Fischer-Tropsch synthesis; a second step of preparing liquid hydrocarbon in which a part or all of molecular oxygen is eliminated; and a third step of introducing the reduced catalyst prepared in the first step into the liquid hydrocarbon prepared in the second step while blocking its contact with air. Since the reduced catalyst used for Fischer-Tropsch synthesis is introduced into liquid hydrocarbon from which molecular oxygen is removed or coated by liquid hydrocarbon, the catalyst for Fischer-Tropsch synthesis activated based on the present invention maintains a high activity even if exposed to the air for a long time, thereby easily facilitating the long-term storage and long-distance transfer of the reduced catalyst.

公开(公告)号：US20150018438A1

公开(公告)日：2015-01-15

申请号：US14383478

申请日：2013-03-07

Applicant: KOREA RESEARCH INSTITUTE OF CHEMICAL TECHNOLOGY

Inventor： Kyoung Su Ha ,  Geun Jae Kwak ,  Jae Hoon Jung ,  Joo Young Cheon ,  Min Hee Woo ,  Yun Jo Lee ,  Ki Won Jun

IPC: B01J23/96 ,  C22B61/00 ,  C22B23/02 ,  C22B11/02 ,  B01J23/89 ,  C07C1/04

CPC classification number: B01J23/96 ,  B01J23/8896 ,  B01J23/8913 ,  B01J23/94 ,  B01J38/04 ,  B01J38/10 ,  C07C1/0435 ,  C07C1/045 ,  C07C2529/068 ,  C10G2/333 ,  C10G2/334 ,  C10G2300/4037 ,  C22B11/02 ,  C22B23/02 ,  C22B61/00

Abstract: The present invention relates to: a catalyst activation method for Fischer-Tropsch synthesis; a catalyst regeneration method for Fischer-Tropsch synthesis; and a method for producing a liquid or solid hydrocarbon by using the Fischer-Tropsch synthesis reaction. The temperatures required for a metal carbide producing and activating reaction is markedly lower than existing catalyst activation temperatures, and the catalyst can be activated under conditions that are the same as Fischer-Tropsch synthesis reaction conditions, and thus there is no need for separate reduction equipment in the reactor, and a Fischer-Tropsch synthesis catalyst which has been used for a long time can be regenerated within the reactor without the catalyst being isolated or extracted from the reactor.

Abstract translation: 本发明涉及：费 - 托合成的催化剂活化方法; 费 - 托合成催化剂再生方法; 以及通过使用费 - 托合成反应来制造液体或固体烃的方法。 金属碳化物生成和活化反应所需的温度明显低于现有的催化剂活化温度，催化剂可以在与费 - 托合成反应条件相同的条件下活化，因此不需要单独的还原装置 在反应器中，长时间使用的费 - 托合成催化剂可以在反应器内再生，而不需要从反应器中分离或提取催化剂。